Results 181 to 190 of about 195,903 (365)

Photoinduced Ring‐Opening Polymerization of N‐Carboxyanhydrides for the Preparation of Cross‐Linked Polypeptide Gels

open access: yesAngewandte Chemie, EarlyView.
We employ a photochemical approach for ring‐opening polymerization (ROP) of α‐amino acid N‐carboxyanhydride (NCA) monomers to prepare covalently cross‐linked synthetic polypeptide gels using a photobase and light, which offers significant advantages in the synthesis of polypeptides and holds great potential for applications requiring spatial and ...
Ana Kočman   +3 more
wiley   +2 more sources

Dispersion‐Enhanced Nitrogen‐Centered Photocatalysis of the Direct Hydrogen Atom Transfer

open access: yesAngewandte Chemie, EarlyView.
Nitrogen‐centered acridine photocatalysts for direct hydrogen atom transfer have been developed, leveraging dispersion interactions to enhance photocatalytic activity. This approach enables diverse functionalization reactions of strong C─H bonds even under cryogenic conditions and provides a new strategy for boosting the efficiency of direct HAT ...
Jiasong Zhang   +16 more
wiley   +2 more sources

Dual Circularly Polarized Luminescence from Chiral Boron‐Embedded Polycyclic Aromatic Hydrocarbons

open access: yesAngewandte Chemie, EarlyView.
Boron‐embedded polycyclic aromatic hydrocarbons featuring an asymmetric boron center coordinated by a proximal P═O group were synthesized. Anthracene‐fused boracyclic derivatives show dual circularly polarized luminescence (CPL) arising from excited‐state P═O⋯B dissociation, which converts point chirality into C−B axial chirality.
Tatsuya Mori   +6 more
wiley   +2 more sources

Alkinyltriazene in photochemischen metallfreien Doyle‐Kirmse‐Umlagerungen

open access: yesAngewandte Chemie, EarlyView.
Es wird eine metall‐ und additivfreie photokatalytische Doyle‐Kirmse‐Reaktion von Alkinyltriazenen beschrieben, die über Cyancarbenzwischenstufen verläuft. Diese Strategie ermöglicht den effizienten Aufbau hochsubstituierter asymmetrischer Kohlenstoffzentren mit breitem Substratspektrum und liefert synthetisch wertvolle Nitrile.
Ningning Liu   +7 more
wiley   +1 more source

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