Metal-free visible-light-enabled vicinal trifluoromethyl dithiolation of unactivated alkenes
Beilstein Journal of Organic Chemistry, 2021 The difunctionalization of alkenes involving a trifluoromethylthio group (SCF3) for the conversion of versatile and readily available olefins into structurally more complex molecules has been successfully studied.
Xiaojuan Li +5 more
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Chemistry Proceedings, 2021 The aim of the research is the development of a one-pot method for the synthesis of lignans, natural compounds that show a wide spectrum of biological activities.
Pavel V. Kovyazin +3 more
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From‐Neutral‐to‐Neutral Reductive Radical Coupling of Non‐Activated Alcohols and Styrenes
ChemistryEurope, 2023 A reductive radical coupling reaction between non‐activated aliphatic alcohols and styrenes has been discovered through the use of low‐valent Ti‐mediated C−O bond homolysis.
Dr. Takuya Suga +2 more
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Alkene-oxo and alkene-alkene coupling on Pt(II) [PDF]
, 2021 Tetranuclear Pt(II) oxo-complex [(COD)4Pt4([mu]3-O)2Cl2](BF4)2 (1) (COD = 1,5- cyclooctadiene) was found to readily react with a variety of alkenes (ethylene, norbornene, propylene and cyclopentene). The most significant discovery resulted from the norbornene reaction, which gave platinaoxetane [(COD)2Pt2(OC7H10)Cl]BF4 (4), the first metallaoxetane ...
openaire +2 more sources
Molecules, 2020 A theoretical analysis of the reaction of oxidative sulfamidation of several alkenes was performed in order to explain the various experimental observations and different reactivity of triflamide and non-fluorinated sulfonamides.
Anton V. Kuzmin +2 more
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Visible-light promoted atom transfer radical addition-elimination (ATRE) reaction for the synthesis of fluoroalkylated alkenes using DMA as electron-donor [PDF]
, 2020 Here, we describe a mild, catalyst-free and operationally-simple strategy for the direct fluoroalkylation of olefins driven by the photochemical activity of an electron donor-acceptor (EDA) complex between DMA and fluoroalkyl iodides.
Gu, Jiwei +5 more
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Frontiers in Chemistry, 2020 Iron(III)-promoted rapid three-component deuteration of quinoxalinones with olefins and NaBD4 is reported for the first time, which provides a novel, economic, and efficient method for the rapid synthesis of deuterated quinoxalinones.
Wanmei Li +6 more
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Glycerol as a cheap, safe and sustainable solvent for the catalytic and regioselective β,β-diarylation of acrylates over palladium nanoparticles [PDF]
, 2010 Herein we show that glycerol can be considered as a promising cheap and green solvent for the regioselective β,β-diarylation of alkenes. Whereas this reaction is generally catalyzed under an inert atmosphere by expensive phosphine or carbene-palladium ...
Barrault, Joel +7 more
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Iodine-Mediated Alkoxyselenylation of Alkenes and Dienes with Elemental Selenium
Molecules, 2022 A one-pot synthesis of linear and cyclic β-alkoxyselenides is developed through the iodine-mediated three-component reaction of elemental selenium with alkenes (dienes) and alcohols.
Evgeny O. Kurkutov, Bagrat A. Shainyan
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Recent Advances in the Synthetic and Mechanistic Aspects of the Ruthenium-catalyzed Carbon-heteroatom Bond Forming Reactions of Alkenes and Alkynes [PDF]
, 2011 The group’s recent advances in catalytic carbon-to-heteroatom bond forming reactions of alkenes and alkynes are described. For the C–O bond formation reaction, a well-defined bifunctional ruthenium-amido catalyst has been successfully employed for the ...
Yi, Chae S.
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