Results 11 to 20 of about 62,467 (179)
Experimental and Computational Study of β-H Transfer between Cobalt(I) Alkyl Complexes and 1-Alkenes
, 2018 Bis(imino)pyridine cobalt(I) alkyl complexes react with 1-alkenes by β-hydrogen transfer, providing a model reaction for the study of a commonly encountered chain transfer process in polymerization and oligomerization catalysis.
Vernon C. Gibson (2329558) +3 more
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Hydroxyl-Diazomethylation of Alkenes via Photoredox Catalysis [PDF]
, 2023 α-Diazoesters belong to significantly important carbenoid precursors in synthetic chemistry, diazomethylation-based difunctionalization of alkenes is highly valuable but remain nontrivial. Herein, we reported a general and modular approach for the direct
Haisheng, Xie +7 more
core +1 more source
Triazenolysis of Alkenes: Aza-version of Ozonolysis [PDF]
, 2023 Numerous applications of alkenes exist due to their abundance and versatility in chemical transformations. In this study, we present a unique and novel chemical transformation of alkenes, the aza-version of canonical ozonolysis reaction, which we termed ...
Alexander, Kaushansky +4 more
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Stereoselective Boron-Masking of polyBorylated-Alkenes: An Access to Stereodefined polyMetalloid Alkenes [PDF]
, 2022 Polyborylated-alkenes are valuable reagents in modern organic synthesis, providing access to a wide array of transformations, including the construction of multiple C–C and C–heteroatom bonds.
Nicole, Hanania +2 more
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Alkene-oxo and alkene-alkene coupling on Pt(II) [PDF]
, 2021 Tetranuclear Pt(II) oxo-complex [(COD)4Pt4([mu]3-O)2Cl2](BF4)2 (1) (COD = 1,5- cyclooctadiene) was found to readily react with a variety of alkenes (ethylene, norbornene, propylene and cyclopentene). The most significant discovery resulted from the norbornene reaction, which gave platinaoxetane [(COD)2Pt2(OC7H10)Cl]BF4 (4), the first metallaoxetane ...
openaire +2 more sources
Iodoaminations of Alkenes [PDF]
Synthesis, 2016 The activation of alkenes and their subsequent functionalization is a frequently used methodology in synthetic chemistry. This review highlights recent iodine-mediated aminations and elaborates on the various strategies to bring about regio- or stereoselective transformations.
Wirth, Thomas, Mizar, Pushpak
openaire +2 more sources
Photocatalytic Hydroalkylation of Aryl-Alkenes
, 2022 Here, we present a visible light-catalyzed hydroalkylation of aryl-alkenes affording C–C bonds using aryl-alkenes and alkyl iodides. We demonstrate the formation of various hydroalkylation products in excellent yields, with primary, secondary, and ...
Michael Schnürch (1281255) +2 more
core +1 more source
Cobalt-catalyzed nucleophilic addition of the allylic C(sp3)–H bond of simple alkenes to ketones
Beilstein Journal of Organic Chemistry, 2018 We herein describe a cobalt/Xantphos-catalyzed regioselective addition of simple alkenes to acetophenone derivatives, affording branched homoallylic alcohols in high yields with perfect branch selectivities.
Tsuyoshi Mita +3 more
doaj +1 more source
Palladium-Catalyzed N-Alkenylation of N-Aryl Phosphoramidates with Alkenes
Molecules, 2023 Versatile and concise Pd-catalyzed oxidative N-alkenylation of N-aryl phosphoramidates with alkenes is described in this study, a reaction that is of great significance but surprisingly unexploited.
Yu-An Li, Ge Wu, Jia Li
doaj +1 more source
Hydrogenations without Hydrogen: Titania Photocatalyzed Reductions of Maleimides and Aldehydes [PDF]
, 2014 A mild procedure for the reduction of electron-deficient alkenes and carbonyl compounds is described. UVA irradiations of substituted maleimides with dispersions of titania (Aeroxide P25) in methanol/acetonitrile (1:9) solvent under dry anoxic conditions
John C. Walton +9 more
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