Results 21 to 30 of about 24,493 (253)

Intrinsic Photoactive Star ZnPc–Poly(glutamate) Nanoplatforms for Multimodal Glioblastoma Therapy and Brain‐Targeted Delivery

Advanced Functional Materials, EarlyView.
An intrinsic photoactive star‐shaped zinc phtalocyanine‐poly(L‐glutamic acid) (ZnPc‐PGA) nanoplatform for multimodal glioblastoma (GBM) therapy and brain‐targeted elivery. A ZnPc‐PGA‐based multifunctional theranostic nanocarrier platform enables image‐guided, multimodal GBM therapy. ZnPc‐PGA nanocarriers support the integration of fluorescence imaging,
Amina Benaicha‐Fernández, Teodora Ranđelović, Ana Armiñán, Víctor Sebastián, Manuel Fuentes, Cristián Huck‐Iriart, Esther Masiá, Paula Carrascosa‐Marco, Pablo Juanes‐Velasco, Snežana Đorđević, Clara Bayona, Ignacio Ochoa, Maria Medel, Inmaculada Conejos‐Sánchez, María J. Vicent   +14 more
wiley   +1 more source

Anomeric Amide‐Enabled Alkene‐Arene and Alkene‐Alkene Aminative Coupling

Angewandte Chemie International Edition
AbstractDespite the prominence of C−N bond forming cross‐coupling reactions as a strategy to assemble molecular fragments, aminative coupling approaches, in which two fragments are assembled directly at the heteroatom, represents a rarely exploited retrosynthetic strategy. Herein, we report the design, synthesis, and implementation of an anomeric amide
Colin Stein, Jasper L. Tyler, Julius Wiener, Florian Boser, Constantin G. Daniliuc, Frank Glorius   +5 more
openaire   +2 more sources

Water‐Compatible SuFEx‐Active Diazonium Linchpin Platform for Rapid Modular Diversification and On‐DNA Functionalization

Advanced Functional Materials, EarlyView.
Sulfur fluoride exchange (SuFEx) is a powerful click platform, yet water‐compatible multifunctional linchpins remain elusive. Here, we report decagram‐scalable diazonium linchpins that enable rapid Pd‐catalyzed diversification and direct, catalyst‐free on‐DNA ligation in aqueous media.
Seok Ju Hong, Dong Hyeon Kim, Yujin Lim, Yongseok Kwon, Sangkyu Lee, Han Yong Bae   +5 more
wiley   +1 more source

Photocatalytic Hydrogenation of Alkenes Using Water as Both the Reductant and the Proton Source

Advanced Science
Utilization of clean and low‐cost water as the reductant to enable hydrogenation of alkenes is highly attractive in green chemistry. However, this research subject is considerably challenging due to the sluggish kinetics of the water oxidation half ...
Xinzhe Tian, Ming Qiu, Wankai An, Yun‐Lai Ren   +3 more
doaj   +1 more source

Stereodefined polymetalloid alkenes synthesis via stereoselective boron-masking of polyborylated alkenes

Nature Communications, 2023
Polyborylated-alkenes are valuable polymetalloid reagents in modern organic synthesis, providing access to a wide array of transformations, including the construction of multiple C–C and C–heteroatom bonds.
Nadim Eghbarieh, Nicole Hanania, Ahmad Masarwa   +2 more
doaj   +1 more source

Single‐Step Recovery of Water from Stable Crude Oil‐Water Emulsion Using Surface Engineered Hybrid Inorganic‐Polymer Membranes

Advanced Functional Materials, EarlyView.
Atomic layer deposition is used to conformally surface engineer polymeric membranes to fabricate inorganic–organic hybrid membranes. These membranes have exceptionally strong attraction toward water even in high oil containing emulsions, which leads to an extremely strong hydration layer at the interface.
Bratin Sengupta, Yining Liu, Gaurab Sarkar, Rouke Cai, Katrina Sparks, Chi Thang Nguyen, Tamar Segal‐Peretz, Seth B. Darling, Jeffrey W. Elam   +8 more
wiley   +1 more source

Enhanced Tantalum Superconducting Resonator Performance via All‐Surface Organic Monolayer Passivation

Advanced Functional Materials, EarlyView.
The internal quality factor of tantalum superconducting resonators is significantly increased by ∼140% in the low photon regime by passivating their surfaces with a high‐quality alkene self‐assembled monolayer. Our methodology promises to enhance the performance of superconducting quantum circuits.
Harsh Gupta, Moritz Singer, Benedikt Schoof, Anna Cattani‐Scholz, Shreya Sharma, Luca Rommeis, Marc Tornow   +6 more
wiley   +1 more source

Photoredox-catalyzed intramolecular nucleophilic amidation of alkenes with β-lactams

Beilstein Journal of Organic Chemistry
The direct nucleophilic addition of amides to unfunctionalized alkenes via photoredox catalysis represents a facile approach towards functionalized alkylamides.
Valentina Giraldi, Giandomenico Magagnano, Daria Giacomini, Pier Giorgio Cozzi, Andrea Gualandi   +4 more
doaj   +1 more source

Metal-Free Direct C–H Functionalization of Quinoxalin-2(1H)-Ones to Produce 3-Vinylated Quinoxalin-2(1H)-Ones in the Presence of Alkenes

Frontiers in Chemistry, 2021
A novel and efficient C3-H vinylation reaction with quinoxalin-2(1H)-one as the substrate, in the presence of alkenes, under metal-free conditions, is reported herein.
Rongcai Ding, Yingxue Li, Yaoyao Chang, Yue Liu, Jie Yu, Yanna Lv, Jinxing Hu   +6 more
doaj   +1 more source

Chemically Fueled Systems Chemistry Across Length Scales

Advanced Functional Materials, EarlyView.
Chemically fueled reaction cycles regulate processes through single and multiple catalytic sites on the molecular and assembly scale. This gives rise to unique kinetically controlled properties/functions like spatio‐temporal catalysis, oscillations, optical properties, and perform work.
Brigitte A. K. Kriebisch, Job Boekhoven
wiley   +1 more source