Results 31 to 40 of about 41,367 (166)
, 2018 Density functional theory calculations were performed to investigate the iridium-catalyzed isomerization of 1-alkenes to trans-2-alkenes. The computations show that the originally proposed π-allyl mechanism is kinetically unfeasible.
Lingfei Hu +5 more
core +1 more source
Chemistry of novel fluorinated alkenes [PDF]
, 1986 The work described in this thesis is concerned with three areas relating to nueleophilic reactions of novel-polyfluorinated alkenes-. a) Very highly strained fluorinated epoxides have been synthesised from bicyclic internal alkenes using Ca(OCl)(_2 ...
Bayliff, Andrew E.
core
Effect of terahertz irradiation on DNA damage repair in living cells
FEBS Open Bio, EarlyView.We investigated the effect of terahertz (THz) wave irradiation on DNA double‐strand break (DSB) repair in living cells. We found that THz irradiation enhanced DSB repair at specific frequencies, whereas heat treatment inhibited it, indicating that this effect is nonthermal and frequency‐specific.
Yuya Ueno +3 more
wiley +1 more source
Covalent Functionalization of 2D Semiconductors: A Roadmap to Advanced Electronic Devices
Advanced Functional Materials, EarlyView.This Review presents recent advances in the covalent functionalization strategies for two‐dimensional semiconductors and their implementation in modern technologies. Layered materials are modified through diverse molecular chemistries (e.g., thiols, diazonium salts, alkyl halides, and electron‐deficient species) to tailor their surface properties ...
Ramiro Quirós‐Ovies +2 more
wiley +1 more source
Photocatalytic Hydrogenation of Alkenes Using Water as Both the Reductant and the Proton Source
Advanced ScienceUtilization of clean and low‐cost water as the reductant to enable hydrogenation of alkenes is highly attractive in green chemistry. However, this research subject is considerably challenging due to the sluggish kinetics of the water oxidation half ...
Xinzhe Tian +3 more
doaj +1 more source
Lipase-mediated epoxidation of alkenes in supercritical carbon dioxide
Green Chemistry Letters and Reviews, 2018 In this work, supercritical carbon dioxide was used as reaction media in the lipase-mediated epoxidation of alkenes for the first time. Under the optimal conditions (alkene (1 mmol), novozym 435 (15 mg), H2O2 (50% aqueous solution, 1.4 mmol), n-caprylic ...
Jiaxin Zhang +7 more
doaj +1 more source
Applied Sciences, 2021 The annulation reactions of 8-quinolinesulfenyl halides with natural products and alkenes affording new water-soluble [1,4]thiazino[2,3,4-ij]quinolin-4-ium derivatives in high or quantitative yields are developed in this study. The reactions with styrene
Vladimir A. Potapov +4 more
doaj +1 more source
Advanced Functional Materials, EarlyView.Controlled carbonization of an Al‐MOF partially decomposes its linkers, exposing coordinatively unsaturated Al centers within an oxide/carbon composite. The resulting Lewis acid sites, rather than surface area, govern organochlorine capture: the composite removes chemically diverse organochlorines from waste plastic pyrolysis oil, outperforms a ...
Seong Cheon Kim +6 more
wiley +1 more source
Hydrosilylation Reactions Catalyzed by Rhenium
Molecules, 2021 Hydrosilylation is an important process, not only in the silicon industry to produce silicon polymers, but also in fine chemistry. In this review, the development of rhenium-based catalysts for the hydrosilylation of unsaturated bonds in carbonyl-, cyano-
Duo Wei +3 more
doaj +1 more source
Advancing Human Skin Equivalents: The Crucial Role of Neurovascular Integration
Advanced Healthcare Materials, EarlyView.This review discusses the importance of integrating vascular and peripheral nerve systems into human skin equivalents (HSEs) to better recapitulate native skin physiology. Recent advances in vascularized, innervated, and neurovascularized HSEs are highlighted, together with emerging bioengineering strategies, current challenges, and future ...
Hao Wu +4 more
wiley +1 more source