Chemistry Proceedings, 2022 The data obtained by the authors in the field of chemistry of substituted borolanes and 2,3-dihydro-1H-boroles are summarized. The authors developed a selective method for the synthesis of five-membered boracarbocycles via transmetalation of ...
Liliya I. Tulyabaeva +2 more
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DFT-Assisted Design and Evaluation of Bifunctional Amine/Pyridine-Oxazoline Metal Catalysts for Additions of Ketones to Unactivated Alkenes and Alkynes [PDF]
, 2018 Bifunctional catalyst systems for the direct addition of ketones to unactivated alkenes/alkynes were designed and modeled by density functional theory (DFT).
Dockendorff, Chris +2 more
core +3 more sources
[2+2]-cycloadditions of alkenes with the triphenylallenyl cation [PDF]
, 1984 The triphenylallenyl cation (8), generated from triphenylpropynol (7) and FSO3H, reacts with alkenes to give the allyl cations 12, which may be deprotonated to yield the methyleneccylobutenes 14.
Deno +13 more
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Effect of polarity and steric on the rate addition of free radicals to Alkenes [PDF]
Kirkuk Journal of Science, 2009 In this investigation, the effective factors on the addition rate for hydroxy methyl and cynomethyl free radicals to some alkenes have been studied using quantum mechanics methods. Where in this study, physical properties like the electron density on the
Najla.J. Khalil, Mostafa.R. Aeyd
doaj +1 more source
Radical Fluoroalkylation Reactions [PDF]
, 2018 Recent protocols and reactions for catalytic radical perfluoroalkylations will be described. The production of perfluoroalkyl radicals (RF = CnF2n+1, n ≥ 2), which effect both addition and substitution reactions on organic substrates, can be realized ...
Barata Vallejo, Sebastian +2 more
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Iodoaminations of Alkenes [PDF]
Synthesis, 2016 The activation of alkenes and their subsequent functionalization is a frequently used methodology in synthetic chemistry. This review highlights recent iodine-mediated aminations and elaborates on the various strategies to bring about regio- or stereoselective transformations.
Wirth, Thomas, Mizar, Pushpak
openaire +2 more sources
Power-dependent speciation of volatile organic compounds in aircraft exhaust [PDF]
, 2012 As part of the third NASA Aircraft Particle Emissions Experiment (APEX-3, November 2005), whole air samples were collected to determine the emission rates of volatile organic compounds (VOCs) from aircraft equipped with three different gas-turbine ...
Anderson, BE +6 more
core +1 more source
Experimental and modeling study of the autoignition of 1-hexene/iso-octane mixtures at low temperatures [PDF]
, 2005 Autoignition delay times have been measured in a rapid compression machine at Lille at temperatures after compression from 630 to 840 K, pressures from 8 to 14 bar, \Phi = 1 and for a iso octane/1 hexene mixture containing 82% iso-octane and 18% 1 hexene.
Barbé +33 more
core +3 more sources
Experimental and modeling study of the low-temperature oxidation of large alkanes [PDF]
, 2008 This paper presents an experimental and modeling study of the oxidation of large linear akanes (from C10) representative from diesel fuel from low to intermediate temperature (550-1100 K) including the negative temperature coefficient (NTC) zone.
Battin-Leclerc, Frédérique +4 more
core +3 more sources
Rhodium/phospholane-phosphite catalysts give unusually high regioselectivity in the enantioselective hydroformylation of vinyl arenes [PDF]
, 2014 Using the phospholane-phosphite ligand, BOBPHOS, almost perfect regioselectivities and high enantioselectivities (up to 92% ee) are observed in Rh catalysed enantioselective hydroformylation of vinyl arenes.
Clarke, Matthew L. +3 more
core +1 more source