Results 51 to 60 of about 62,467 (179)

[2+2+2] Cycloaddition Reactions of Macrocyclic Systems Catalyzed by Transition Metals. A Review

open access: yesMolecules, 2010
Polyalkyne and enediyne azamacrocycles are prepared from arenesulfonamides and various alkyne and alkene derivatives either under basic or neutral conditions.
Anna Roglans, Anna Pla-Quintana
doaj   +1 more source

Hydrocarbons and polychlorinated biphenyls from the unsaponifiable fraction of anhydrous milk fat

open access: yesJournal of Lipid Research, 1973
Using a combination of gas–liquid chromatography and mass spectrometry, the presence of 39 aliphatic hydrocarbons was firmly established in the unsaponifiable fraction of anhydrous milk fat.
Vincent P. Flanagan, Aldo Ferretti
doaj   +1 more source

Hydrogenation of unactivated enamines to tertiary amines: rhodium complexes of fluorinated phosphines give marked improvements in catalytic activity

open access: yesBeilstein Journal of Organic Chemistry, 2015
In the hydrogenation of sluggish unactivated enamine substrates, Rh complexes of electron-deficient phosphines are demonstrated to be far more reactive catalysts than those derived from triphenylphosphine.
Sergey Tin   +2 more
doaj   +1 more source

High Ethylene and Propylene in an Area Dominated by Oil Production

open access: yesAtmosphere, 2020
We measured the spatial distribution and composition of ozone-forming hydrocarbons, alcohols, and carbonyls in Utah’s Uinta Basin during the winter months of 2019 and 2020. The Uinta Basin contains about 10,000 producing oil and gas wells. Snow cover and
Seth N. Lyman   +4 more
doaj   +1 more source

Visible-light photoredox catalysis enabled bromination of phenols and alkenes

open access: yesBeilstein Journal of Organic Chemistry, 2014
A mild and efficient methodology for the bromination of phenols and alkenes has been developed utilizing visible light-induced photoredox catalysis. The bromine was generated in situ from the oxidation of Br− by Ru(bpy)33+, both of which resulted from ...
Yating Zhao   +4 more
doaj   +1 more source

Rewriting Alkene Frameworks: A Practical Strategy for Nitrogen Incorporation

open access: yesChemistryEurope
Expanding the reach of skeletal editing to unactivated hydrocarbons presents a formidable challenge in nitrogen incorporation chemistry. In a recent advance, Morandi and coworkers have developed a direct, metal‐free strategy to insert nitrogen into ...
Ranjini Laskar, Frank Glorius
doaj   +1 more source

Palladium-catalyzed Heck-type reaction of secondary trifluoromethylated alkyl bromides

open access: yesBeilstein Journal of Organic Chemistry, 2017
An efficient palladium-catalyzed Heck-type reaction of secondary trifluoromethylated alkyl bromides has been developed. The reaction proceeds under mild reaction conditions with high efficiency and excellent functional group tolerance, even towards ...
Tao Fan, Wei-Dong Meng, Xingang Zhang
doaj   +1 more source

Room Temperature Ni(II) Catalyzed Hydrophosphination and Cyclotrimerization of Alkynes

open access: yesInorganics, 2018
The catalytic activity of nickel complexes in hydrophosphination involving secondary phosphines is not a commonly studied transformation. Beyond a small number of stand-out examples, many reports in the literature focus on the use of simple nickel salts.
Ruth L. Webster
doaj   +1 more source

Cuticular wax profiling of Populus trichocarpa and P. balsamifera reveals surface similarities with underlying differences

open access: yesFrontiers in Plant Science
Cuticular waxes are a mixture of hydrophobic components protecting plant tissues from the environment. Populus trichocarpa and P. balsamifera are closely-related tree species with broad North American distribution; however, variation in their cuticular ...
Mahbobeh Zamani-Babgohari   +11 more
doaj   +1 more source

Lipase-mediated epoxidation of alkenes in supercritical carbon dioxide

open access: yesGreen Chemistry Letters and Reviews, 2018
In this work, supercritical carbon dioxide was used as reaction media in the lipase-mediated epoxidation of alkenes for the first time. Under the optimal conditions (alkene (1 mmol), novozym 435 (15 mg), H2O2 (50% aqueous solution, 1.4 mmol), n-caprylic ...
Jiaxin Zhang   +7 more
doaj   +1 more source

Home - About - Disclaimer - Privacy