Results 51 to 60 of about 104,551 (278)

Anomeric Amide‐Enabled Alkene‐Arene and Alkene‐Alkene Aminative Coupling

Angewandte Chemie International Edition
AbstractDespite the prominence of C−N bond forming cross‐coupling reactions as a strategy to assemble molecular fragments, aminative coupling approaches, in which two fragments are assembled directly at the heteroatom, represents a rarely exploited retrosynthetic strategy. Herein, we report the design, synthesis, and implementation of an anomeric amide
Colin Stein, Jasper L. Tyler, Julius Wiener, Florian Boser, Constantin G. Daniliuc, Frank Glorius   +5 more
openaire   +2 more sources

Enhanced Gamma Radiation Shielding Using Epoxy Quartz Fabric Composites Reinforced With CoCl2 Microparticles

Advanced Engineering Materials, EarlyView.
The growing demand for lightweight, nontoxic, and multifunctional gamma shielding materials has intensified efforts to find alternatives to conventional lead and aluminum‐based protectants. In this work, we develop epoxy quartz fabric composites reinforced with cobalt chloride (CoCl2) microparticles, fabricated via hand lay‐up with varying filler ...
Summan Urooge, Ahsan Irshad, Umar Jamil, Srosh Fazil, Khuram Liaqat, Kashif Shahzad, Fakhar Alam, Mehboob Alam   +7 more
wiley   +1 more source

Iodine-Mediated Alkoxyselenylation of Alkenes and Dienes with Elemental Selenium

Molecules, 2022
A one-pot synthesis of linear and cyclic β-alkoxyselenides is developed through the iodine-mediated three-component reaction of elemental selenium with alkenes (dienes) and alcohols.
Evgeny O. Kurkutov, Bagrat A. Shainyan
doaj   +1 more source

Advancing Electronic Application of Coordination Solids: Enhancing Electron Transport and Device Integration via Surface‐Mounted MOFs (SURMOFs)

Advanced Functional Materials, EarlyView.
The layer‐by‐layer (LbL) assembly of coordination solids, enabled by the surface‐mounted metal‐organic framework (SURMOF) platform, is on the cusp of generating the organic counterpart of the epitaxy of inorganics. The programmable and sequential SURMOF protocol, optimized by machine learning (ML), is suited for accessing high‐quality thin films of ...
Zhengtao Xu, Christof Wöll, Stefan Bräse   +2 more
wiley   +1 more source

Photoredox-catalyzed intramolecular nucleophilic amidation of alkenes with β-lactams

Beilstein Journal of Organic Chemistry
The direct nucleophilic addition of amides to unfunctionalized alkenes via photoredox catalysis represents a facile approach towards functionalized alkylamides.
Valentina Giraldi, Giandomenico Magagnano, Daria Giacomini, Pier Giorgio Cozzi, Andrea Gualandi   +4 more
doaj   +1 more source

Chemical Composition of Essential Oil from Four Sympatric Orchids in NW-Italy

Plants, 2022
Orchidaceae is a flowering plant family worldwide distributed known for producing volatile organic compounds (VOCs) which can act as olfactory signals for pollinators.
Francesco Saverio Robustelli della Cuna, Pierluigi Cortis, Fabiana Esposito, Antonio De Agostini, Cristina Sottani, Cinzia Sanna   +5 more
doaj   +1 more source

Synthetic chemistry and biological activity of pentafluorosulphanyl (SF5) organic molecules [PDF]

, 2012
Acknowledgements We thank the European Commission for financial support (Industry Academia Partnerships and Pathways project “PET BRAIN”, Contract No 251482). S.A.
Altomonte, Stefano, Zanda, Matteo
core   +1 more source

Characterization of the novel ene reductase Ppo-Er1 from paenibacillus polymyxa [PDF]

, 2020
Ene reductases enable the asymmetric hydrogenation of activated alkenes allowing the manufacture of valuable chiral products. The enzymes complement existing metal- and organocatalytic approaches for the stereoselective reduction of activated C=C double ...
Aregger, David, Buller, Rebecca, Peters, Christin   +2 more
core   +1 more source

Photoswitching Conduction in Framework Materials

Advanced Functional Materials, EarlyView.
This mini‐review summarizes recent advances in state‐of‐the‐art proton and electron conduction in framework materials that can be remotely and reversibly switched on and off by light. It discusses the various photoswitching conduction mechanisms and the strategies employed to enhance photoswitched conductivity.
Helmy Pacheco Hernandez, Stefan Hecht, Wolfgang Wenzel, Lars Heinke, Mariana Kozlowska   +4 more
wiley   +1 more source

Copper(I)-Photocatalyzed Addition of Trichloromethanesulfenyl Chloride to Olefinic Compounds

Molecules
Atom transfer radical addition (ATRA) reactions are essential transformations in organic synthetic chemistry that enable the atom-economic difunctionalization of abundant olefin feedstocks.
Nejc Petek, Tilen Zorko, Martin Škrinjar, Uroš Grošelj, Jurij Svete, Drago Kočar, Bogdan Štefane   +6 more
doaj   +1 more source