Results 81 to 90 of about 195,903 (365)

Metal–Organic Frameworks for Gaseous Pollutant Management: From Capture to Neutralization and Reutilization

open access: yesAdvanced Functional Materials, EarlyView.
This review maps how MOFs can manage hazardous gases by combining adsorption, neutralization, and reutilization, enabling sustainable air‐pollution control. Covering chemical warfare agent simulants, SO2, NOx, NH3, H2S, and volatile organic compounds, it highlights structure‐guided strategies that boost selectivity, water tolerance, and cycling ...
Yuanmeng Tian   +8 more
wiley   +1 more source

Pig Slurry Fertilization Changes the Pyrolytic Signature of Humic Substances in Calcareous Soil

open access: yesAgronomy
The aim of this study was to determine the effect of progressive pig slurry (PS) rates, applied over a 12-year period, on the molecular composition of soil organic matter in a calcareous soil.
Àngela D. Bosch-Serra   +3 more
doaj   +1 more source

[2+2+2] Cycloaddition Reactions of Macrocyclic Systems Catalyzed by Transition Metals. A Review

open access: yesMolecules, 2010
Polyalkyne and enediyne azamacrocycles are prepared from arenesulfonamides and various alkyne and alkene derivatives either under basic or neutral conditions.
Anna Roglans, Anna Pla-Quintana
doaj   +1 more source

On the strong difference in reactivity of acyclic and cyclic diazodiketones with thioketones: experimental results and quantum-chemical interpretation [PDF]

open access: yes, 2015
The 1,3-dipolar cycloaddition of acyclic 2-diazo-1,3-dicarbonyl compounds (DDC) and thioketones preferably occurs with Z,Econformers and leads to the formation of transient thiocarbonyl ylides in two stages.
Holleman   +8 more
core   +4 more sources

Bioprinting Organs—Science or Fiction?—A Review From Students to Students

open access: yesAdvanced Healthcare Materials, EarlyView.
Bioprinting artificial organs has the potential to revolutionize the medical field. This is a comprehensive review of the bioprinting workflow delving into the latest advancements in bioinks, materials and bioprinting techniques, exploring the critical stages of tissue maturation and functionality.
Nicoletta Murenu   +18 more
wiley   +1 more source

Aminothiolation of alkenes with azoles and Bunte salts

open access: yesFrontiers in Chemistry
We have developed an intermolecular aminothiolation of simple olefins using Bunte salt as a thiolating agent. This protocol produces thiyl free radicals under PIDA oxidation conditions, eliminating the need for transition-metal catalysts.
Bingqing Ouyang   +4 more
doaj   +1 more source

Hydrocarbons and polychlorinated biphenyls from the unsaponifiable fraction of anhydrous milk fat

open access: yesJournal of Lipid Research, 1973
Using a combination of gas–liquid chromatography and mass spectrometry, the presence of 39 aliphatic hydrocarbons was firmly established in the unsaponifiable fraction of anhydrous milk fat.
Vincent P. Flanagan, Aldo Ferretti
doaj   +1 more source

Metronidazole‐Loaded Cyclodextrin Nanogels for Antibacterial Therapy and Microbiota Regulation in Periodontitis

open access: yesAdvanced Healthcare Materials, EarlyView.
A methacrylamide β‐cyclodextrin‐based nanogel (MACD nGel) is developed to load the antimicrobial drug Metronidazole (MNZ) for topical delivery for the treatment of periodontitis. It is demonstrated that cyclodextrin nanogel (nGel) loaded with metronidazole provides an efficient drug delivery route but also has potential clinical applications and offers
Yanjing Ji   +8 more
wiley   +1 more source

Unified metal-free intermolecular Heck-type sulfonylation, cyanation, amination, amidation of alkenes by thianthrenation

open access: yesNature Communications
Direct and site-selective C-H functionalization of alkenes under environmentally benign conditions represents a useful and attractive yet challenging transformation to access value-added molecules.
Ming-Shang Liu   +4 more
doaj   +1 more source

Hydrogenation of unactivated enamines to tertiary amines: rhodium complexes of fluorinated phosphines give marked improvements in catalytic activity

open access: yesBeilstein Journal of Organic Chemistry, 2015
In the hydrogenation of sluggish unactivated enamine substrates, Rh complexes of electron-deficient phosphines are demonstrated to be far more reactive catalysts than those derived from triphenylphosphine.
Sergey Tin   +2 more
doaj   +1 more source

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