Results 21 to 30 of about 504,742 (339)

Antibacterial activity of alkyl gallates is a combination of direct targeting of FtsZ and permeabilization of bacterial membranes

open access: yesFrontiers in Microbiology, 2015
Alkyl gallates are compounds with reported antibacterial activity. One of the modes of action is binding of the alkyl gallates to the bacterial membrane and interference with membrane integrity.
Ewa eKról   +6 more
doaj   +1 more source

Alkylating Agents Stronger than Alkyl Triflates [PDF]

open access: yesJournal of the American Chemical Society, 2004
A new class of potent electrophilic "R(+)" alkylating agents has been developed using weakly nucleophilic carborane anions as leaving groups. These reagents, R(CHB(11)Me(5)X(6)) (R = Me, Et, and i-Pr; X = Cl, Br), are prepared via metathesis reactions with conventional alkylating agents such as alkyl triflates, using the high oxophilicity of silylium ...
Kato, Tsuyoshi   +4 more
openaire   +4 more sources

Multiple Beneficial Health Effects of Natural Alkylglycerols from Shark Liver Oil

open access: yesMarine Drugs, 2010
Alkylglycerols (alkyl-Gro) are ether lipids abundant in the liver of some elasmobranch fish species such as ratfishes and some sharks. Shark liver oil from Centrophorus squamosus (SLO), or alkyl-Gro mix from this source, have several in vivo biological ...
Alain B. Legrand   +5 more
doaj   +1 more source

New insight into the spatiotemporal variability and source apportionments of C1–C4 alkyl nitrates in Hong Kong [PDF]

open access: yesAtmospheric Chemistry and Physics, 2016
C1–C4 alkyl nitrates (RONO2) were measured concurrently at a mountain site, Tai Mo Shan (TMS), and an urban site, Tsuen Wan (TW), at the base of the same mountain in Hong Kong from September to November 2010. Although the levels of parent hydrocarbons
Z. Ling   +8 more
doaj   +1 more source

Fragment Coupling and the Construction of Quaternary Carbons Using Tertiary Radicals Generated From tert-Alkyl N-Phthalimidoyl Oxalates By Visible-Light Photocatalysis. [PDF]

open access: yes, 2015
The coupling of tertiary carbon radicals with alkene acceptors is an underdeveloped strategy for uniting complex carbon fragments and forming new quaternary carbons.
Lackner, Gregory L   +3 more
core   +3 more sources

Alkylation of Dihydrofullerenes [PDF]

open access: yesThe Journal of Organic Chemistry, 2002
The fulleride dianions C(60)(2-) and C(70)(2-) were generated by deprotonation of the corresponding hydrogenated fullerenes, 1,2-C(60)H(2) and 1,2-C(70)H(2). These anions were prepared in the presence of a variety of alkylating agents, and mono- or dialkylated products were obtained. Alkylation was not successful with sulfonate ester alkylating agents.
Mark S, Meier   +4 more
openaire   +2 more sources

Preparation of New 2,3-Diphenylpropenoic Acid Esters – Good Yields Even for the More Hindered Z Isomers [PDF]

open access: yes, 2004
The potassium salt of E- and Z-2,3-diphenylpropenoic acids prepared in situ could be esterified efficiently in DMSO with the appropriate alkyl halides at room temperature.
Barry   +7 more
core   +2 more sources

Ketones from aldehydes via alkyl C(sp3)−H functionalization under photoredox cooperative NHC/palladium catalysis

open access: yesNature Communications, 2023
Direct synthesis of ketones from aldehydes features high atom- and step-economy. Yet, the coupling of aldehydes with unactivated alkyl C(sp3)-H remains challenging.
Hai-Ying Wang   +4 more
doaj   +1 more source

Alkyl and Aromatic Amines as Digestive Ripening/Size Focusing Agents for Gold Nanoparticles

open access: yesNanomaterials, 2013
Both long chain alkyl thiols and alkyl amines behave as size focusing agents for gold nanoparticles, a process that is under thermodynamic control. However, amines do not oxidize surface gold atoms while thiols do oxidize surface gold to gold(I) with ...
Christopher Sorensen   +3 more
doaj   +1 more source

Copper(I)-catalyzed tandem reaction: synthesis of 1,4-disubstituted 1,2,3-triazoles from alkyl diacyl peroxides, azidotrimethylsilane, and alkynes

open access: yesBeilstein Journal of Organic Chemistry, 2018
A copper-catalyzed azide–alkyne cycloaddition (CuAAC) reaction for the synthesis of 1,4-disubstituted 1,2,3-triazoles from alkyl diacyl peroxides, azidotrimethylsilane, and terminal alkynes is reported.
Muhammad Israr   +4 more
doaj   +1 more source

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