Results 241 to 250 of about 196,557 (349)

Synthesis, Physical and Ion-Conducting Properties of 1,2,3-Triazolium Ionic Liquids. [PDF]

open access: yesMolecules
Abdelhedi Miladi I   +5 more
europepmc   +1 more source

Investigating the Reactivity and Selectivity in Nucleophilic Fluorination of Secondary Alkyl Bromides and Mesylates: Assessment of the Effect of Counterion and Bulky Alcohols

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Hydrogen bonding provided by pinacol or 2‐trifluoromethyl‐2‐propanol enhances the selectivity of nucleophilic fluorination of several secondary alkyl bromides or mesylates. Synthesis of secondary alkyl fluorides via nucleophilic substitution faces the problem of high competition with E2 processes. This competition depends on the chemical environment of
Eloah P. Ávila   +3 more
wiley   +1 more source

Alkylation of Low Eutectic Energy-Containing Carrier Molecules: Design and Synthesis

open access: green
Chaoqi Song   +9 more
openalex   +1 more source

Chan–Lam Cross‐Coupling With Alkylboron Reagents: From Transmetallation to Radical Pathways

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Alkylative Chan–Lam coupling overcomes intrinsic transmetallation limitations of alkylboron reagents by engaging radical pathways. Recent advances reveal how radical and radical–polar crossover mechanisms enable mild C(sp3)—heteroatom bond formation. This minireview highlights key mechanistic insights and emerging strategies that transform alkylboron ...
Nicolas G.‐Simonian   +3 more
wiley   +1 more source

From alkylating to shape-shifting G-quadruplex ligands: the RHAU peptide story. [PDF]

open access: yesNucleic Acids Res
De Paepe L   +6 more
europepmc   +1 more source

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