Ligand assisted Co(ii) catalyzed direct C-H alkylation of aryl ketones with diverse alkyl halides.
Nigade A, Parmar SV, Avasare V.
europepmc +1 more source
Benzyl methyl morpholinium hydroxide (BMMorph)OH: a new basic ionic liquid for <i>N</i>-alkylation of bioactive N-heterocycles. [PDF]
Soltani Rad MN +2 more
europepmc +1 more source
Divergent Synthesis of Polycyclic Derivatives via Gold Catalysis
Gold(I)‐catalyzed cycloisomerization enables the formation of complex 3D structures from simple enyne precursors. This study presents a divergent strategy to synthesize functionalized bicyclic and tricyclic scaffolds from a common alkynyl ketone.
Emilie Gentilini +4 more
wiley +1 more source
Late-stage adenine N6-alkylation of nucleos(t)ides and oligonucleotides via photoredox and copper co-catalytic decarboxylative C(sp3)-N coupling. [PDF]
Xie R +9 more
europepmc +1 more source
Chemical Syntheses of 3′ and 5′ Phosphorylated Oligonucleotides: An Overview
This review provides an overview of the various chemical methods employed in the synthesis of oligonucleotides bearing a phosphate group at their 3′ or 5′ end. Notably, it presents modified phosphoramidites and supports developed for this purpose. Oligonucleotides (ON) with a phosphate monoester group at their 3′ or 5′ end have applications in many ...
Rémy Lartia
wiley +1 more source
Enantioselective Intramolecular C-H Alkylation Catalyzed by a Nonsymmetric Chiral Cobalt Porphyrin. [PDF]
Buchelt C +4 more
europepmc +1 more source
Beyond Alkylation – Cyclophosphamide's Expanding Role in Cancer Therapy and Immunomodulation
Mohalkar Krushna*, Dahatonde Abhijit, Munfan Sumit, Dr. Tarde Vijay
openalex +1 more source
Bridging the gap. Beyond deck functionalization, the ethylene bridges of [2.2]paracyclophanes offer a largely unexploited reactivity landscape. This review showcases strategies to functionalize these bridges and leverage them to build novel cyclophane architectures.
Rongyu Sun +3 more
wiley +1 more source
"On-water" photosensitization enables redox neutral acylation and alkylation of quinones. [PDF]
Mandal T +4 more
europepmc +1 more source

