Triflic acid catalyzed isobutane alkylation with trifluoroethanol as a promoter
Hailing Ren +4 more
openalex +2 more sources
Dearomatization with Axial‐to‐Central Chirality Conversion
Atropisomers are exciting synthetic targets with unique properties, which find applications in many fields of chemistry. However, considering them as substrates is not very frequent, notably in the context of dearomatization reaction. We wish to discuss the different strategies for the dearomatization of aromatic atropisomers with axial‐to‐central ...
Morgane Mando +3 more
wiley +1 more source
DNA-Protein Cross-Link Formation and Cellular Toxicity by Chimeric Bis-Electrophiles. [PDF]
Yu H, Jiang X, Greenberg MM.
europepmc +1 more source
A Direct Method to Prepare Zwitterionic Organotrifluoroborates: Ammonium and Sulfonium Derivatives
Organotrifluoroborates find applications in synthesis, diagnostics, and theranostics. This study outlines a one‐step reaction for producing ammonium and sulfonium trifluoroborate zwitterion derivatives. This method achieves satisfactory yields without the need for expensive reagents.
Vanessa Re +6 more
wiley +1 more source
Application of Proteomic Workflows for the Identification of Biomarkers for the Retrospective Verification of Sulfur Mustard Intoxication. [PDF]
Thomann G +3 more
europepmc +1 more source
1,2‐Diazetidines − Structure, Synthesis, and Functionalization
1,2‐Diazetidines are saturated four‐membered heterocycles featuring two adjacent nitrogen atoms. Despite recent advances in their synthesis and promising potential in medicinal chemistry, the chemistry of these cyclic hydrazines remains underexplored.
Stefan Roesner
wiley +1 more source
General Light-Induced Pd-Catalyzed Allylic C-H Alkylation of Internal Alkenes: Direct Access to Tertiary and Quaternary Carbon Centers. [PDF]
Pradhan S, Prakash G, Gevorgyan V.
europepmc +1 more source
The one‐pot synthesis of 3‐benzylidenbenzo[c]thiophen‐1‐amines was achieved through the nickel‐catalyzed three‐component coupling reaction of 1‐ethynyl‐2‐iodobenzenes, tert‐butyl isocyanide, and hexamethyldisilathiane. This procedure is applicable to the preparation of secondary thioamides using aryl iodides.
Norio Sakai +4 more
wiley +1 more source
Acridinium amidate as a hydrogen-bonding photocatalyst for direct decarboxylative alkylation of native carboxylic acids. [PDF]
Truong DA +8 more
europepmc +1 more source
A cascade reaction under phase‐transfer conditions between 3‐nitro indoles and isocyanomethylene dibenzenes affords the construction of pyrrolo[3,4‐b]indole cores. Control experiments provide insight into moderate product yields and clarify why the reaction is not amenable to asymmetric induction. A cascade reaction enabling the construction of pyrrolo[
Ana Mikleušević +4 more
wiley +1 more source

