Results 41 to 50 of about 166,984 (347)
An enantioselective synthesis of skipped diene has been developed based on an iridium-catalyzed allylic alkylation of phosphonate carbanions and Horner-Wadsworth-Emmons olefination.
Arko, Seal, Santanu, Mukherjee
core +1 more source
Room-Temperature, Base-Mediated Selective Synthesis of 2-(Arylamino)ethanols and 2-Aryloxyethanols
A simple and efficient protocol for base-mediated selective synthesis of 2-(arylamino)ethanols from primary aromatic amines and 2-aryloxyethanols from phenols, promoted by K2CO3 has been achieved under mild conditions.
Rahul B. Sonawane +3 more
doaj +1 more source
Supported metal catalysts for friedel-crafts alkylation [PDF]
Doctor EducationisThe research focused on the synthesis, characterisation and activity of zeolite supported metal catalysts for the Friedel-Crafts alkylation of benzene with t-butyl chloride.
Hlatywayo, Tapiwa
core +1 more source
Alkylation of 2,4-(1H,3H)-Quinazolinediones with Dialkyl Carbonates Under Microwave Irradiations
Alkylation is a very important chemical reaction which modifies the biological properties of drugs. Quinazolinedione derivatives are of considerable interest due to their wide array of pharmacological properties.We now report application of a practical ...
Martha Cecilia Meza +4 more
doaj +1 more source
Among the unstabilized enolates used as nucleophile in iridium-catalyzed asymmetric allylic alkylation reactions, amide enolates are least explored. Vinyl azides are now employed as amide enolate surrogate for the first time in Ir-catalyzed asymmetric ...
Aditya, Chakrabarty, Santanu, Mukherjee
core +1 more source
Catalytic Photochemical Enantioselective α-Alkylation with Pyridinium Salts
We have developed a chiral amine catalyzed enantioselective α-alkylation of aldehydes with amino acid derived pyridinium salts as alkylating reagents. The reaction proceeds in the presence of visible light (390 nm) and in the absence of a photocatalyst ...
Santhivardhana Reddy, Yetra +2 more
core +1 more source
The direct alkylation of benzene with alkanes is an effective method for alkylbenzene production. Our group previously discovered that a mixture of supported Pd nanoparticles and solid acids effectively promoted the alkylation of benzene with alkanes ...
Satoshi Misaki +5 more
doaj +1 more source
Synthesis and structure of novel tripodal ligands based on tetrazol-5-thioles
Novel tripodal ligands (R1N4CS)3CH, where R1 = Me, Ph, were synthesised by alkylation of 1-R-tetrazol-5-thioles with iodoform in alkaline media. These ligands were identified based on data of elemental analysis, nuclear magnetic resonance spectroscopy ...
Sergei V. Voitekhovich +5 more
doaj +1 more source
Site-selective catalytic deaminative alkylation of unactivated olefins.
A catalytic deaminative alkylation of unactivated olefins is described. The protocol is characterized by its mild conditions, wide scope - including the use of ethylene as substrate -, and exquisite site-selectivity pattern for both a-olefins and ...
Shang-Zheng Sun +2 more
semanticscholar +1 more source
Asymmetric alkylation of diarylmethane derivatives
Deprotonation–alkylation of prochiral diarylmethane substrates using sec-BuLi and (−)-sparteine has been carried out in excellent yields and up to 94% ee.
Rossington, SB +4 more
core +1 more source

