Results 41 to 50 of about 110,461 (301)

Modeling of Benzene with Ethylene Alkylation

open access: yesMATEC Web of Conferences, 2016
The paper considers the benzene alkylation with ethylene model development with the use of zeolite catalyst. A list of reactions occurring in the alkylation reactor was made and the thermodynamic possibility of determination of these reactions by the ...
Khlebnikova Elena   +3 more
doaj   +1 more source

The performance of HMCM-22 zeolite catalyst on the olefin alkylation thiophenic sulfur in gasoline

open access: yes, 2008
The catalytic performance of the HMCM-22 zeolites with different Si/Al-2 ratios for the olefin alkylation thiophenic sulfur (OATS) process was investigated.
Xu Longya   +6 more
core   +1 more source

Cu-catalyzed Asymmetric Alkylation for Chiral Unnatural α-Substituted α-Amino Acids of Phallotoxins [PDF]

open access: yes, 2023
Asymmetric alkylation is one of the most important methods for synthesizing chiral unnatural α-substituted α-amino acids. Herein, We reported an asymmetric alkylation of tert-butyl glycinate Schiff base catalyzed by copper/(4S,2R)-tBu-Phosferrox ...
Yang, Wang   +6 more
core   +2 more sources

Direct C(sp2)–H alkylation of unactivated arenes enabled by photoinduced Pd catalysis

open access: yesNature Communications, 2020
Direct catalytic C(sp2)–H alkylation of unactivated arenes with alkyl halides remains elusive despite the progress in C-H functionalization. Here, the authors report the catalytic C(sp2)–H alkylation of unactivated arenes with alkyl bromides via visible ...
Daeun Kim   +3 more
doaj   +1 more source

The Shewanella oneidensis Fic enzyme SoFic targets the switch‐I region of EF‐Tu for AMPylation

open access: yesFEBS Letters, EarlyView.
Fic enzymes mediate diverse post‐translational modifications across all domains of life, including AMPylation. Prokaryotic EF‐Tu can be AMPylated and deAMPylated by the conserved Fic enzyme SoFic. Structural and biochemical approaches were used to characterize the effect of AMPylation on EF‐Tu, SoFic's enzymatic activities, and the enzyme‐target ...
Svenja Runge   +6 more
wiley   +1 more source

Acrolein-induced activation of mitogen-activated protein kinase signaling is mediated by alkylation of thioredoxin reductase and thioredoxin 1

open access: yesRedox Biology, 2013
Cigarette smoking remains a major health concern worldwide, and many of the adverse effects of cigarette smoke (CS) can be attributed to its abundant electrophilic aldehydes, such as acrolein (2-propenal).
Matthew J. Randall   +4 more
doaj   +1 more source

Heterogeneous Friedel–Crafts Alkylation

open access: yes, 2023
Heterogeneous alkylation of arene and related catalysis are overviewed from industrial and academic aspects. We first discuss, principally from industrial aspects, the synthesis of ethylbenzene (EB) and cumene (IPB) by the alkylation of benzene using ...
Nishimura, Y   +9 more
core   +1 more source

Tumour‐proximal deep serum proteomics identifies biomarkers associated with ovarian cancer

open access: yesMolecular Oncology, EarlyView.
New biomarkers are needed for early ovarian cancer detection. Ovarian (tumour‐proximal) and peripheral vein serum from healthy women and patients with benign or malignant tumours underwent nanoparticle‐enriched deep proteomics. Ovarian serum yielded more protein identifications and revealed tumour‐reflective signatures.
Darren Lau   +9 more
wiley   +1 more source

Small molecule deoxynyboquinone triggers alkylation and ubiquitination of Keap1 at Cys489 on Kelch domain for Nrf2 activation and inflammatory therapy

open access: yesJournal of Pharmaceutical Analysis
Activation of nuclear factor erythroid 2-related factor 2 (Nrf2) by Kelch-like ECH-associated protein 1 (Keap1) alkylation plays a central role in anti-inflammatory therapy.
Ke-Gang Linghu   +12 more
doaj   +1 more source

Synthesis and structure of novel tripodal ligands based on tetrazol-5-thioles

open access: yesЖурнал Белорусского государственного университета: Химия, 2022
Novel tripodal ligands (R1N4CS)3CH, where R1 = Me, Ph, were synthesised by alkylation of 1-R-tetrazol-5-thioles with iodoform in alkaline media. These ligands were identified based on data of elemental analysis, nuclear magnetic resonance spectroscopy ...
Sergei V. Voitekhovich   +5 more
doaj   +1 more source

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