Results 41 to 50 of about 166,984 (347)

Enantioselective Synthesis of Skipped Dienes via Iridium-Catalyzed Allylic Alkylation of Phosphonate Carbanions

open access: yes, 2022
An enantioselective synthesis of skipped diene has been developed based on an iridium-catalyzed allylic alkylation of phosphonate carbanions and Horner-Wadsworth-Emmons olefination.
Arko, Seal, Santanu, Mukherjee
core   +1 more source

Room-Temperature, Base-Mediated Selective Synthesis of 2-(Arylamino)ethanols and 2-Aryloxyethanols

open access: yesSynOpen, 2019
A simple and efficient protocol for base-mediated selective synthesis of 2-(arylamino)ethanols from primary aromatic amines and 2-aryloxyethanols from phenols, promoted by K2CO3 has been achieved under mild conditions.
Rahul B. Sonawane   +3 more
doaj   +1 more source

Supported metal catalysts for friedel-crafts alkylation [PDF]

open access: yes, 2013
Doctor EducationisThe research focused on the synthesis, characterisation and activity of zeolite supported metal catalysts for the Friedel-Crafts alkylation of benzene with t-butyl chloride.
Hlatywayo, Tapiwa
core   +1 more source

Alkylation of 2,4-(1H,3H)-Quinazolinediones with Dialkyl Carbonates Under Microwave Irradiations

open access: yesMolecules, 2009
Alkylation is a very important chemical reaction which modifies the biological properties of drugs. Quinazolinedione derivatives are of considerable interest due to their wide array of pharmacological properties.We now report application of a practical ...
Martha Cecilia Meza   +4 more
doaj   +1 more source

Iridium-Catalyzed Asymmetric α-Allylic Alkylation of Amides using Vinyl Azide as Amide Enolate Surrogate

open access: yes, 2020
Among the unstabilized enolates used as nucleophile in iridium-catalyzed asymmetric allylic alkylation reactions, amide enolates are least explored. Vinyl azides are now employed as amide enolate surrogate for the first time in Ir-catalyzed asymmetric ...
Aditya, Chakrabarty, Santanu, Mukherjee
core   +1 more source

Catalytic Photochemical Enantioselective α-Alkylation with Pyridinium Salts

open access: yes, 2022
We have developed a chiral amine catalyzed enantioselective α-alkylation of aldehydes with amino acid derived pyridinium salts as alkylating reagents. The reaction proceeds in the presence of visible light (390 nm) and in the absence of a photocatalyst ...
Santhivardhana Reddy, Yetra   +2 more
core   +1 more source

Effect of zeolites on the alkylation of aromatics with alkanes using a Pd nanoparticle/solid acid cooperative catalytic system

open access: yesGreen Carbon
The direct alkylation of benzene with alkanes is an effective method for alkylbenzene production. Our group previously discovered that a mixture of supported Pd nanoparticles and solid acids effectively promoted the alkylation of benzene with alkanes ...
Satoshi Misaki   +5 more
doaj   +1 more source

Synthesis and structure of novel tripodal ligands based on tetrazol-5-thioles

open access: yesЖурнал Белорусского государственного университета: Химия, 2022
Novel tripodal ligands (R1N4CS)3CH, where R1 = Me, Ph, were synthesised by alkylation of 1-R-tetrazol-5-thioles with iodoform in alkaline media. These ligands were identified based on data of elemental analysis, nuclear magnetic resonance spectroscopy ...
Sergei V. Voitekhovich   +5 more
doaj   +1 more source

Site-selective catalytic deaminative alkylation of unactivated olefins.

open access: yesJournal of the American Chemical Society, 2019
A catalytic deaminative alkylation of unactivated olefins is described. The protocol is characterized by its mild conditions, wide scope - including the use of ethylene as substrate -, and exquisite site-selectivity pattern for both a-olefins and ...
Shang-Zheng Sun   +2 more
semanticscholar   +1 more source

Asymmetric alkylation of diarylmethane derivatives

open access: yes, 2006
Deprotonation–alkylation of prochiral diarylmethane substrates using sec-BuLi and (−)-sparteine has been carried out in excellent yields and up to 94% ee.
Rossington, SB   +4 more
core   +1 more source

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