Results 31 to 40 of about 166,984 (347)

Regioselective Alkylation of an Oxonaphthalene-Annelated Pyrrol System

open access: yesMolbank, 2009
The regioselective alkylation of an oxonaphthalene-annelated pyrrole system is reported. The regioselectivity of alkylation can be controlled by the selection of the solvent.
Helmut Spreitzer, Christiane Puschmann
doaj   +1 more source

Formation of Amphiphilic Molecules from the Most Common Marine Polysaccharides, toward a Sustainable Alternative?

open access: yesMolecules, 2021
Marine polysaccharides are part of the huge seaweeds resources and present many applications for several industries. In order to widen their potential as additives or bioactive compounds, some structural modifications have been studied.
Tiphaine Wong   +6 more
doaj   +1 more source

Open-Air Alkylation Reactions in Photoredox-Catalyzed DNA-Encoded Library Synthesis

open access: yesJournal of the American Chemical Society, 2019
DNA-encoded library (DEL) technology is a powerful tool commonly used by the pharmaceutical industry for the identification of compounds with affinity to biomolecular targets. Success in this endeavor lies in sampling diverse chemical libraries. However,
J. Phelan   +7 more
semanticscholar   +1 more source

Dual Catalytic Platform for Enabling sp3 α C–H Arylation and Alkylation of Benzamides

open access: yes, 2020
A dual catalytic sp3 α C–H arylation and alkylation of benzamides with organic halides is described.
A. W. Rand   +7 more
semanticscholar   +1 more source

Nickel-Catalyzed Reductive Alkylation of Heteroaryl Imines

open access: yes, 2022
A Ni-catalyzed reductive cross-coupling of heteroaryl imines with C(sp3) electrophiles for the preparation of heterobenzylic amines is reported. This umpolung-type alkylation proceeds under mild conditions, avoids the pre-generation of organometallic ...
Marco, Brandstätter   +2 more
core   +1 more source

Study on the Alkylation Reactions of N(7)-Unsubstituted 1,3-Diazaoxindoles

open access: yesMolecules, 2017
The chemistry of the 5,7-dihydro-6H-pyrrolo[2,3-d]pyrimidin-6-one (1,3-diazaoxindole) compound family, possessing a drug-like scaffold, is unexplored. In this study, the alkylation reactions of N(7)-unsubstituted 5-isopropyl-1,3-diazaoxindoles bearing ...
Eszter Kókai   +5 more
doaj   +1 more source

Direct C2–H alkylation of indoles driven by the photochemical activity of halogen-bonded complexes

open access: yesBeilstein Journal of Organic Chemistry, 2023
A light-driven metal-free protocol for the synthesis of sulfone-containing indoles under mild conditions is reported. Specifically, the process is driven by the photochemical activity of halogen-bonded complexes formed upon complexation of a sacrificial ...
Martina Mamone   +4 more
doaj   +1 more source

Catalytic Alkylation of Brown Coal and Peat

open access: yesEurasian Chemico-Technological Journal, 2012
The alcohol alkylation of low-grade metamorphic coal and peat in the presence of mineral and organic acids was studied using FTIR, NMR, and GC-MS. The impact of the reaction conditions on the yield of extractable matter was investigated experimentally ...
S. I. Zherebtsov, Z. R. Ismagilov
doaj   +1 more source

Selective sp3 C–H alkylation via polarity-match-based cross-coupling

open access: yesNature, 2017
The functionalization of carbon–hydrogen (C–H) bonds is one of the most attractive strategies for molecular construction in organic chemistry. The hydrogen atom is considered to be an ideal coupling handle, owing to its relative abundance in organic ...
C. Le   +4 more
semanticscholar   +1 more source

Chromium‐Catalyzed Alkylation of Amines by Alcohols

open access: yesAngewandte Chemie, 2020
The alkylation of amines by alcohols is a broadly applicable, sustainable, and selective method for the synthesis of alkyl amines, which are important bulk and fine chemicals, pharmaceuticals, and agrochemicals.
Fabian Kallmeier   +3 more
semanticscholar   +1 more source

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