A Dual Catalytic Platform for Enabling sp3 α C–H Arylation & Alkylation of Benzamides [PDF]
, 2019 A dual catalytic sp3 a C–H arylation & alkylation of benzamides with organic halides is described. This protocol exhibits excellent chemoselectivity and exquisite site-selectivity, offering a complementary reactivity mode to existing sp3 arylation or ...
Jessica, Giacoboni +5 more
core +2 more sources
Study on the Alkylation Reactions of N(7)-Unsubstituted 1,3-Diazaoxindoles
Molecules, 2017 The chemistry of the 5,7-dihydro-6H-pyrrolo[2,3-d]pyrimidin-6-one (1,3-diazaoxindole) compound family, possessing a drug-like scaffold, is unexplored. In this study, the alkylation reactions of N(7)-unsubstituted 5-isopropyl-1,3-diazaoxindoles bearing ...
Eszter Kókai +5 more
doaj +1 more source
Synthesis of tetrahydrokhusitone: Annulation of the cyclohexane ring by free radical and carbanionic sequence of reactions [PDF]
Journal of the Serbian Chemical Society, 2003 The synthesis of norcadinane sesquiterpene tetrahydrokhusitone 1 has been achieved by a new method for annulation of cyclohexane ring involving a sequence of free radical δ-alkylation of the non-activated carbon atom and intramolecular carbanionic ...
Petrović Goran, Čeković Živorad
doaj +1 more source
Catalytic Alkylation of Brown Coal and Peat
Eurasian Chemico-Technological Journal, 2012 The alcohol alkylation of low-grade metamorphic coal and peat in the presence of mineral and organic acids was studied using FTIR, NMR, and GC-MS. The impact of the reaction conditions on the yield of extractable matter was investigated experimentally ...
S. I. Zherebtsov, Z. R. Ismagilov
doaj +1 more source
Molecules, 2021 Marine polysaccharides are part of the huge seaweeds resources and present many applications for several industries. In order to widen their potential as additives or bioactive compounds, some structural modifications have been studied.
Tiphaine Wong +6 more
doaj +1 more source
Room-Temperature, Base-Mediated Selective Synthesis of 2-(Arylamino)ethanols and 2-Aryloxyethanols
SynOpen, 2019 A simple and efficient protocol for base-mediated selective synthesis of 2-(arylamino)ethanols from primary aromatic amines and 2-aryloxyethanols from phenols, promoted by K2CO3 has been achieved under mild conditions.
Rahul B. Sonawane +3 more
doaj +1 more source
Alkylation of 2,4-(1H,3H)-Quinazolinediones with Dialkyl Carbonates Under Microwave Irradiations
Molecules, 2009 Alkylation is a very important chemical reaction which modifies the biological properties of drugs. Quinazolinedione derivatives are of considerable interest due to their wide array of pharmacological properties.We now report application of a practical ...
Martha Cecilia Meza +4 more
doaj +1 more source
Green CarbonThe direct alkylation of benzene with alkanes is an effective method for alkylbenzene production. Our group previously discovered that a mixture of supported Pd nanoparticles and solid acids effectively promoted the alkylation of benzene with alkanes ...
Satoshi Misaki +5 more
doaj +1 more source
Direct C2–H alkylation of indoles driven by the photochemical activity of halogen-bonded complexes
Beilstein Journal of Organic Chemistry, 2023 A light-driven metal-free protocol for the synthesis of sulfone-containing indoles under mild conditions is reported. Specifically, the process is driven by the photochemical activity of halogen-bonded complexes formed upon complexation of a sacrificial ...
Martina Mamone +4 more
doaj +1 more source
Synthesis of Multisubstituted 1,4-Dihydrobenzoxazin-2-ones through a One-Pot Nucleophilic N-Alkylation/C-Alkylation of Cyclic α-Imino Esters [PDF]
, 2020 A nucleophilic N-alkylation of 2-oxobenzoxazine-2-carboxylates with organozinc reagents with good selectivities and in moderate to good yields is described.
Pons, Carolina +3 more
core +2 more sources