Results 21 to 30 of about 196,557 (349)

Synthesis and structures of O-anthrylmethyl-substituted hexahomotrioxacalix[3]arenes [PDF]

open access: yes, 2016
O-Alkylation of 7,15,23-tri-tert-butyl-25,26,27-trihydroxy-2,3,10,11,18,19-hexahomo-3,11,19-trioxacalix[3]arene (1H₃) with 9-chloromethylanthracene 5 was carried out under different reaction conditions.
Ikejiri, Yusuke   +5 more
core   +2 more sources

Synthesis and evaluation of a novel ionophore based on a thiacalix[4]arene derivative bearing imidazole units [PDF]

open access: yes, 2014
O-Alkylation of the flexible thiacalix[4]arene 1 with 2-chloromethyl-1-methyl-1H-imidazole 2 in the presence of Na₂CO₃ or K₂CO₃ afforded mono-O-alkylation product 3 in 29–51% yield, along with recovery of the starting compound.
Elsegood, Mark R. J.   +8 more
core   +4 more sources

Carbocation rearrangement, methyl migration, and long-range hydrogen transfer in phenyl fatty acid esters

open access: yesJournal of Chemical Research, 2023
Various isomers can be observed in the Friedel–Crafts alkylation of benzene. However, the mechanism and influence of these isomerization reactions were still unclear. In this work, several methyl phenylundecanoate were analyzed by gas chromatography–mass
Jian-Qiao Lang   +3 more
doaj   +1 more source

Unanticipated differences between α- and γ-diaminobutyric acid-linked hairpin polyamide-alkylator conjugates [PDF]

open access: yes, 2006
Hairpin polyamide–chlorambucil conjugates containing an {alpha}-diaminobutyric acid ({alpha}-DABA) turn moiety are compared to their constitutional isomers containing the well-characterized {gamma}-DABA turn.
Chou, C. James   +4 more
core   +4 more sources

ALKYLATION OF BENZENE WITH LONG CHAIN OLEFINS OVER SOLID-ACID CATALYST

open access: yesJournal of Engineering, 2009
This investigation is concerned with the linear alkylbenzene production reaction by the alkylation of benzene with long chain olefins C10-C13 over various prepared solid acid catalysts.
Abdul Halim A. K. Mohammed   +1 more
doaj   +1 more source

Molecular Tuning of the Magnetic Response in Organic Semiconductors [PDF]

open access: yes, 2017
The tunability of high-mobility organic semi-conductors (OSCs) holds great promise for molecular spintronics. In this study, we show this extreme variability - and therefore potential tunability - of the molecular gyromagnetic coupling ("g-") tensor with
Babak, Vladimir   +6 more
core   +3 more sources

3-(2-Diisopropylaminoethyl)-5-(4-methoxybenzylidene)thiazolidine-2,4-dione

open access: yesMolbank, 2022
Thiazolidine-2,4-dione core is widely used in the medicinal chemistry of different types of potential drug-like small molecules. In the present work, the synthesis of a novel non-condensed thiazolidine-2,4-dione-bearing derivative is reported by the two ...
Serhii Holota   +3 more
doaj   +1 more source

Chemical, Electronic, and Electrical Properties of Alkylated Ge(111) Surfaces [PDF]

open access: yes, 2010
The use of Ge in semiconductor electronics has been constrained by the lack of a simple method of passivating the crystal surface. Toward that end, we have explored the utility of chemically bonded hydrocarbon monolayers.
Brunschwig, Bruce S.   +2 more
core   +2 more sources

Progress of decreasing toxic polycyclic aromatic hydrocarbons content in coal-tar pitch by alkylation method

open access: yesMeitan kexue jishu, 2023
Coal-tar pitch (CTP) is a substance produced by ambient and/or vacuum distillation of high-temperature coal tar, although CTP has a large yield in China, however its wide application is limited due to its high toxicity.
ZHANG Wenshuo   +5 more
doaj   +1 more source

Domino alkylation-cyclization reaction of propargyl bromides with thioureas/thiopyrimidinones: A new facile synthesis of 2-aminothiazoles and 5H-thiazolo[3,2-a]pyrimidin-5-ones [PDF]

open access: yes, 2009
A new synthesis of 2-aminothiazoles and 5H-thiazolo[3,2-a]pyrimidin-5-ones was developed as a domino alkylation-cyclization reaction of propargyl bromides with thioureas and thio¬pyrimidinones, respectively.
Bernardini, Martina   +3 more
core   +1 more source

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