Results 21 to 30 of about 166,984 (347)

Carbocation rearrangement, methyl migration, and long-range hydrogen transfer in phenyl fatty acid esters

open access: yesJournal of Chemical Research, 2023
Various isomers can be observed in the Friedel–Crafts alkylation of benzene. However, the mechanism and influence of these isomerization reactions were still unclear. In this work, several methyl phenylundecanoate were analyzed by gas chromatography–mass
Jian-Qiao Lang   +3 more
doaj   +1 more source

Visible Light-Enabled Direct Decarboxylative N-Alkylation

open access: yesAngewandte Chemie, 2020
Development of efficient and selective C–N bond-forming reactions from abundant feedstock chemicals remains a central theme in organic chemistry, due to the key roles of amines in synthesis, drug discovery and materials science.
V. Nguyen   +6 more
semanticscholar   +1 more source

ALKYLATION OF BENZENE WITH LONG CHAIN OLEFINS OVER SOLID-ACID CATALYST

open access: yesJournal of Engineering, 2009
This investigation is concerned with the linear alkylbenzene production reaction by the alkylation of benzene with long chain olefins C10-C13 over various prepared solid acid catalysts.
Abdul Halim A. K. Mohammed   +1 more
doaj   +1 more source

3-(2-Diisopropylaminoethyl)-5-(4-methoxybenzylidene)thiazolidine-2,4-dione

open access: yesMolbank, 2022
Thiazolidine-2,4-dione core is widely used in the medicinal chemistry of different types of potential drug-like small molecules. In the present work, the synthesis of a novel non-condensed thiazolidine-2,4-dione-bearing derivative is reported by the two ...
Serhii Holota   +3 more
doaj   +1 more source

Thiol-linked alkylation of RNA to assess expression dynamics

open access: yesNature Methods, 2017
Gene expression profiling by high-throughput sequencing reveals qualitative and quantitative changes in RNA species at steady state but obscures the intracellular dynamics of RNA transcription, processing and decay.
Veronika A. Herzog   +9 more
semanticscholar   +1 more source

Progress of decreasing toxic polycyclic aromatic hydrocarbons content in coal-tar pitch by alkylation method

open access: yesMeitan kexue jishu, 2023
Coal-tar pitch (CTP) is a substance produced by ambient and/or vacuum distillation of high-temperature coal tar, although CTP has a large yield in China, however its wide application is limited due to its high toxicity.
ZHANG Wenshuo   +5 more
doaj   +1 more source

Lead-Halide Perovskites for Photocatalytic α-Alkylation of Aldehydes.

open access: yesJournal of the American Chemical Society, 2019
Cost-effective and efficient photocatalysis are highly desirable in chemical synthesis. Here we demonstrate that readily prepared suspensions of APbBr3 (A = Cs or methylammonium (MA)) type perovskite colloids (ca.
Xiaolin Zhu   +4 more
semanticscholar   +1 more source

Heterogeneous Friedel–Crafts Alkylation

open access: yes, 2023
Heterogeneous alkylation of arene and related catalysis are overviewed from industrial and academic aspects. We first discuss, principally from industrial aspects, the synthesis of ethylbenzene (EB) and cumene (IPB) by the alkylation of benzene using ...
Nishimura, Y   +4 more
core   +1 more source

Merging Photoredox Catalysis with Organocatalysis: The Direct Asymmetric Alkylation of Aldehydes

open access: yesScience, 2008
Photoredox catalysis and organocatalysis represent two powerful fields of molecule activation that have found widespread application in the areas of inorganic and organic chemistry, respectively.
David A. Nicewicz, David W. C. MacMilla
semanticscholar   +1 more source

Synthesis of Secondary Amines via Self-Limiting Alkylation of N-Aminopyridinium Salts

open access: yes, 2023
Partial amine alkylation to prepare secondary amines is challenging due to the enhanced N-nucleophilicity that accompanies alkylation. Here we introduce N-aminopyridinium salts as ammonia surrogates for the synthesis of secondary amines via self-limiting
David, Powers   +4 more
core   +1 more source

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