Copper(I)-catalyzed asymmetric alkylation of α-imino-esters
Nature Communications, 2023 Asymmetric alkylation of enolates is one of the most direct and important reactions to prepare α-chiral carbonyl compounds. Except for the classical methods that rely on the use of chiral auxiliaries, asymmetric catalysis emerged as a powerful tool ...
Zong-Ci Liu +3 more
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Nickel-catalyzed C-alkylation of nitroalkanes with alkyl halides
, 2022 Watson, Donald A.This dissertation focuses on the development of novel methods for nickel-catalyzed C-alkylation of nitroalkanes and mechanistic studies of them.
Rezazadeh, Sina
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Kinetic modeling of liquid phase catalytic alkylation of guaiacol with cyclohexene
Chemical Engineering Journal Advances, 2021 The kinetics of the liquid-phase alkylation of guaiacol (G) with cyclohexene (CH) over Amberlyst 36 resin was studied using Langmuir–Hinshelwood–Hougen–Watson (LHHW) heterogeneous kinetic models.
Mardelly Kateryne Montañez-Valencia +3 more
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Alkyl–Alkyl Suzuki Cross‐Coupling of Unactivated Secondary Alkyl Chlorides [PDF]
Angewandte Chemie, 2010 The first method for achieving alkyl–alkyl Suzuki reactions of unactivated secondary alkyl chlorides has been developed. Carbon–carbon bond formation occurs under mild conditions (at room temperature) with the aid of commercially available catalyst components.
Lu, Zhe, Fu, Gregory C.
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Alkylation of Magnesium Enamide with Alkyl Chlorides and Fluorides. [PDF]
ChemInform, 2005 AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access the actual ChemInform Abstract, please click on HTML or PDF.
Takuji, Hatakeyama +3 more
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Itaconate is an anti-inflammatory metabolite that activates Nrf2 via alkylation of KEAP1
Nature, 2018 The endogenous metabolite itaconate has recently emerged as a regulator of macrophage function, but its precise mechanism of action remains poorly understood.
E. Mills +34 more
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DNA polymerase α (swi7) and the flap endonuclease fen1 (rad2) act together in the s-phase alkylation damage response in S. pombe [PDF]
, 2012 Polymerase α is an essential enzyme mainly mediating Okazaki fragment synthesis during lagging strand replication. A specific point mutation in Schizosaccharomyces pombe polymerase α named swi7-1, abolishes imprinting required for mating-type switching ...
Koulintchenko Milana +20 more
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New catalytic strategies for DNA and RNA alkylation using rhodium (II) and copper (I) carbenes - a versatile tool for applications in chemical biology [PDF]
, 2015 A variety of nucleic acid substrates were catalytically alkylated with rhodium(II) and copper(I)-carbenoids generated from diazocarbonyl compounds. The alkylation took place via an N-H insertion reaction selectively targeting the nucleobases in single ...
Tishinov, Kiril
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Iridium-Catalyzed Enantioselective Formal α-Allylic Alkylation of Acrylonitrile
, 2023 A highly enantioselective formal α-allylic alkylation of acrylonitrile is developed using 4-cyano-3-oxotetrahydrothiophene (c-THT) as a safe and easy-to-handle surrogate of acrylonitrile.
Pankaj, Roy, Santanu, Mukherjee
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Homogeneous Friedel–Crafts Alkylation
, 2023 Since its discovery in 1877, Friedel–Crafts alkylation has been one of the most significant reactions in organic chemistry. The breadth of this reaction has increased over 130 years, and it is now moving toward a more environmental friendly and ...
Dasireddy, VDBC +4 more
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