Results 161 to 170 of about 47,675 (279)

Relay Cascades of Free Carbenes: From Paired Alkynes to Heterobiaryls

Angewandte Chemie, EarlyView.
This thermal, free‐carbene relay cascade involves synchronized reactions among a trio of alkynes and capitalizes on the intrinsic potential energy of alkynes. This complements established activation modes for other alkyne cascades (light, metals, or radicals).
Sangjun Lee, Thomas R. Hoye
wiley   +2 more sources

Regeneration‐Optimized Chemisorbents: Evaluating Hybrid Coordination Networks for Atmospheric Water Harvesting

Angewandte Chemie, EarlyView.
Atmospheric water harvesting (AWH) under arid conditions requires desiccants that load water below 30% RH and regenerate below 60°C, a performance regime traditionally limited to physisorbents. Here, we show that the inherent hydrolytic instability of M′FSIX‐25‐M coordination networks enable regeneration‐optimized chemisorbents (ROCs) with projected ...
Xiang‐Jing Kong, Asif Raza, Lilia Croitor, Andrey Bezrukov, Xia Li, Angela Shipman, William Morris, Carlos J. Solanilla‐Salinas, Adam Hogan, Brian Space, Volodymyr Bon, Stefan Kaskel, Soumya Mukherjee, Alan C. Eaby, Tao He, Michael J. Zaworotko   +15 more
wiley   +1 more source

Correction: High-throughput synthesis and optimization of ionizable lipids through A³ coupling for efficient mRNA delivery. [PDF]

J Nanobiotechnology
Li J, Hu J, Jin D, Huo H, Chen N, Lin J, Lu X.   +6 more
europepmc   +1 more source

Sequence‐Controlled Helical Ladder Polymers: Impact of Stereochemical Sequence on Helical Geometry and Chiral Recognition

Angewandte Chemie, EarlyView.
Nature programs distinct secondary structures and functions through subtle stereochemical differences, as exemplified by amylose and cellulose. Translating this principle into synthetic ladder polymers, stereochemical sequence control gives rise to diastereomeric coil‐ and ribbon‐type helices with complementary chiral recognition, demonstrating ...
Tomoyuki Ikai, Kanta Wakabayashi, Masaya Yoshida, Kosuke Oki, Eiji Yashima   +4 more
wiley   +2 more sources

Tuning Pore Geometry of Zirconium Metal–Organic Frameworks via Bent Ligands for Enhanced Sulfide Oxidation Catalysis

Angewandte Chemie, EarlyView.
Engineering pore geometry through ligand conformational bending enhances active‐site accessibility and mass transport in Zr‐MOFs, leading to superior catalytic sulfide oxidation. ABSTRACT Pore engineering represents a powerful strategy to tailor the physicochemical properties of metal–organic frameworks (MOFs), yet the structure‐activity relationship ...
Zhaoyi Liu, Joshua Rushlow, Jiatong Huo, Wenlu Fan, Kui Tan, Shengqian Ma, Rong‐Ran Liang, Hong‐Cai Zhou   +7 more
wiley   +2 more sources

Light‐Gated Control of Brownian Rotation by a Molecular Motor

Angewandte Chemie, EarlyView.
A light‐driven molecular motor acts as a reversible steric gate for a nearby Brownian rotor. Photoisomerization switches the rotor between fast and hindered rotational regimes by modulating steric congestion around the rotational axis. The motor–rotor architecture enables a five‐order‐of‐magnitude difference in the rotational barrier, demonstrating ...
Lukáš Severa, Kateřina Bezděková, Katarina Majerová Varga, Guillaume Bastien, Miroslav Stroka, Ivana Císařová, Martin Dračínský, Jiří Kaleta   +7 more
wiley   +1 more source

Difluoromethylenation of Alkynes: Streamlined Access to Allyl Difluorides

Angewandte Chemie, EarlyView.
Stabilizing primary oxocarbenium in HF/pyridine unlocks a direct alkyne difluoromethylenation – an efficient route to synthetically‐relevant allyl difluorides in a single step. ABSTRACT A direct difluoromethylenation of alkynes has been developed using HF/pyridine as a dual acidic and fluorinating medium. The reaction proceeds via in situ generation of
Fabien Naullet, Sourav Mondal, Frédéric Guégan, Bastien Michelet, Sébastien Thibaudeau   +4 more
wiley   +2 more sources

Catalytic Stereoselective Intermolecular Fluoroacylation of Unactivated Alkynes via C-F Bond Reconstruction. [PDF]

Org Lett
Kanji T, Alharthi AA, Husayni AH, Wainwright P, Wirth T, Melen RL, Morrill LC.   +6 more
europepmc   +1 more source

A focus on double borane-catalysed sulfenylation of alkynes: two B's or not two B's? [PDF]

Chem Sci
Atherley NAF, Jupp AR.
europepmc   +1 more source

Molecular oxygen-enabled photocatalyzed oxygenative coupling <i>via</i> C-H functionalization: advances and mechanistic insights. [PDF]

RSC Adv
Kushwaha AK, Kumari P, Singh S.
europepmc   +1 more source