Results 101 to 110 of about 1,621,772 (233)

Synthesis and anаlgеsic properties of (3-allyl-4-aryl-3H-thiazol-2-ylidene)-[4-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-yl)phenyl]amine derivatives

open access: yesФармацевтичний журнал, 2018
In recent years, attention to itself attracted by the problem of pain treatment, which is due to a noticeable increase in patients, especially the able-bodied age. The aim of the study was to synthesize substances with potentially analgesic properties in
S. A. Demchenko   +5 more
doaj   +1 more source

Síntese one-pot de a-arilideno- ð-lactonas a partir de brometos alílicos funcionalizados : estudo das etapas reacionais e caracterização dos intermediários [PDF]

open access: yes, 2014
Dissertação (mestrado) - Universidade Federal de Santa Catarina, Centro de Ciências Físicas e Matemáticas, Programa de Pós-Graduação em Química, Florianópolis, 2014Neste trabalho foi estudada a síntese de a-arilideno-ð-lactonas utilizando alguns dos ...
Conceição, Henrique Pinheiro da
core  

A Modular Synthesis of C5‐Sulfenyl Thiazoles via an Intermolecular Pummerer Rearrangement: An Underexplored Scaffold for Medicinal Chemistry

open access: yesAngewandte Chemie, EarlyView.
Modular access to underexplored C5‐sulfenyl thiazoles via an intermolecular Pummerer rearrangement is reported. The methodology exhibits a broad functional group tolerance enabling the seamless design of trisubstituted thiazole cores bearing a sulfur handle for further elaboration.
Joe L. Smy   +5 more
wiley   +2 more sources

Z‐Retentive Enantioselective Rh‐Catalyzed Hydroarylation of E,Z‐Dienes

open access: yesAngewandte Chemie, EarlyView.
The Rh‐catalyzed hydroarylation of conjugated E,Z‐dienoates is found to proceed with high selectivity for addition to the E‐alkene unit. Mechanistic analysis of this Z‐retentive process points towards preferred binding of the E‐alkene unit to a Rh‐aryl species to give rise to the observed selectivity and that Rh‐enolate protonolysis to be turnover ...
Wesley McNutt   +4 more
wiley   +2 more sources

Oxygen‐Tolerant, Controlled Synthesis of Degradable and Water‐Soluble Poly(Vinyl Amide)s via Radical Ring‐Opening Copolymerization of Cyclic Dithiothreitol

open access: yesAngewandte Chemie, EarlyView.
Oxygen‐tolerant photoinduced electron/energy transfer reversible addition–fragmentation chain transfer (PET‐RAFT) polymerization enables the controlled radical ring‐opening (rROP) copolymerization of cyclic dithiothreitol (cDTT) with less‐activated vinyl monomers, affording degradable polymers with predictable molecular weights, low dispersities, and ...
Alessandro Magro   +5 more
wiley   +2 more sources

SYNTHESIS, STRUCTURE AND BIOLOGICAL ACTIVITY OF N(4)-ALLYL-3-THIOSEMICARBAZONES AND THEIR COORDINATION COMPOUNDS WITH SOME 3D METALS

open access: yesStudia Universitatis Moldaviae: Stiinte reale si ale naturii, 2016
The paper presents a review of different N(4)-allyl-3-thiosemicarbazones and their coordination compounds described in literature. N(4)-allyl-3-thiosemicarbazide can form corresponding thiosemicarbazones with aliphatic, aromatic and heteroaromatic ...
Vasilii GRAUR
doaj  

Some sigmatropic rearrangements of polyfluoroaromatic and heteroaromatic compounds [PDF]

open access: yes, 1986
This Thesis describes some [3,3] and [2,3] -sigmatropic rearrangements that can occur in a variety of polyfluoroaromatic and -heteroaromatic compounds. The presence of fluorine on the aromatic moiety precludes the normal rearomatization process. The
Ferguson, John Alasdair Kerr Jamie
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Antibacterial properties of surface-active synthesized 1-allyl-3-methylimidazolium based ionic liquids: experimental, molecular docking and DFT calculations

open access: yesResults in Chemistry
Ionic liquids are continuously being synthesized and metathesized with their properties being evaluated, particularly the degradation of these compounds for possible industrial applications.
Vuyolwethu Tokoyi   +6 more
doaj   +1 more source

Catalytic Enantioselective Allyl–Allyl Cross-Coupling with a Borylated Allylboronate

open access: yes, 2016
Catalytic enantioselective allyl–allyl cross-coupling of a borylated allylboronate reagent gives versatile borylated chiral 1,5-hexadienes. These compounds may be manipulated in a number of useful ways to give functionalized chiral building blocks for ...
Robert E. Kyne (1616719)   +3 more
core   +1 more source

Highly diastereoselective synthesis of enantioenriched anti-α-allyl-β-fluoroamines

open access: yes, 2019
A highly diastereoselective synthesis ofanti-a-allyl-b-fluoroamineshas been developed involving enantioselectivea-fluorination ofaldehydes followed by a diastereoselective Petasis allyl borono-Mannich reaction.
Thanaphat Thaima (20116911)   +6 more
core  

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