Results 101 to 110 of about 1,712,246 (296)

Formation of Organomagnesium Compounds via EtMgBr-Mediated Radical Cyclization of Allyl β-Iodoacetals

open access: yes, 2016
Treatment of allyl β-iodoacetals with ethylmagnesium bromide in THF provided tetrahydrofuran derivatives in good yields.
Atsushi Inoue (28383)   +2 more
core   +1 more source

Synthesis and anаlgеsic properties of (3-allyl-4-aryl-3H-thiazol-2-ylidene)-[4-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-yl)phenyl]amine derivatives

open access: yesФармацевтичний журнал, 2018
In recent years, attention to itself attracted by the problem of pain treatment, which is due to a noticeable increase in patients, especially the able-bodied age. The aim of the study was to synthesize substances with potentially analgesic properties in
S. A. Demchenko   +5 more
doaj   +1 more source

Reactions of Some Cyclomanganated Compounds with C-Nitroso Compounds, Allenes, and Ketenimines [PDF]

open access: yes, 2008
eta2-(5-Methoxy-2-acetylphenyl)tetracarbonylmanganese (30) was reacted with 2-methyl-2-nitrosopropane (31) to form 2-acetyl-5-methoxy-N-(tert-butyl)aniline(43) in low yield.
Revell, John Bernard
core  

Enantiomerically Enriched Tetrahydropyridine Allyl Chlorides [PDF]

open access: yes, 2019
Enantiomerically enriched allyl halides are rare due to their configurational lability. Here we report stable piperidine-based allyl chloride enantiomers.
Robert, Paton   +4 more
core   +2 more sources

Synthesis, Properties, and Reactivity with Carbon Dioxide of (allyl)2Ni(L) Complexes

open access: yes, 2016
A family of nickel allyl complexes of the type (allyl)2Ni(L) (L = PMe3 (1), PEt3 (2), PPh3 (3), NHC (4); NHC = 1,3-bis(2,6-diisopropylphenyl)-4,5-dihydro-2H-imidazol-2-ylidene) and (2-methylallyl)2Ni(L) (L = PMe3 (5), PEt3 (6), PPh3 (7), NHC (8)) have ...
Jianguo Wu (30201)   +2 more
core   +2 more sources

Occupational exposure to allyl chloride [PDF]

open access: yes
"The recommended standards include an exposure limit of 1.0 ppm as a time-weighted concentration for up to 10-hour work shift in a 40-hour work week, with a ceiling concentration of 3.0 ppm for 15 minutes. Provisions are included for sampling, collection,

core   +1 more source

Solvent-Controlled Highly Selective Bis- and Monoallylation of Active Methylene Compounds by Allyl Acetate with Palladium(0) Nanoparticle

open access: yes, 2016
Palladium(0) nanoparticle has been used as an efficient catalyst for the allylation of active methylene compounds. Very efficient bisallylation is achieved for a variety of active methylene compounds by allyl acetate and its derivatives in one stroke in ...
Kalicharan Chattopadhyay (2285470)   +2 more
core   +1 more source

Pharmacological and Therapeutic Potential of Garlic (Allium sativum): Integrating Phytochemistry, Molecular Mechanisms, and Clinical and Preclinical Evidence. [PDF]

open access: yesChemistryOpen
Garlic bioactive compounds, including organosulfur compounds (allicin, DADS, DATS, and SAC), phenolic compounds, and quercetin, regulate the Nrf2/HO‐1, NF‐κB, PI3K/Akt, and AMPK/eNOS signaling pathways. These actions enhance antioxidant defenses, suppress inflammation, improve metabolic and cardiovascular function, and contribute to reduced blood ...
Bereda G.
europepmc   +2 more sources

SYNTHESIS, STRUCTURE AND BIOLOGICAL ACTIVITY OF N(4)-ALLYL-3-THIOSEMICARBAZONES AND THEIR COORDINATION COMPOUNDS WITH SOME 3D METALS

open access: yesStudia Universitatis Moldaviae: Stiinte reale si ale naturii, 2016
The paper presents a review of different N(4)-allyl-3-thiosemicarbazones and their coordination compounds described in literature. N(4)-allyl-3-thiosemicarbazide can form corresponding thiosemicarbazones with aliphatic, aromatic and heteroaromatic ...
Vasilii GRAUR
doaj  

A Ruthenium(CAAC‐5) Olefin Metathesis Catalyst for Bioconjugation

open access: yesAngewandte Chemie International Edition, EarlyView.
The aqueous instability of ruthenium catalysts restricts olefin metathesis in biological media. A Ru(CAAC‐5) complex bearing an aniline handle is reported that remains active under biologically relevant conditions and enables bioconjugation to proteins, peptides, and an artificial metalloenzyme, providing a robust platform for olefin metathesis in ...
Damian Alexander Graf   +4 more
wiley   +1 more source

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