Results 111 to 120 of about 24,650 (254)

Organelle‐Resolved Tetrazine‐trans‐Cyclooctene Click Chemistry for Cargo Delivery and Release

Chemistry – A European Journal, EarlyView.
Bioorthogonal click chemistry tools provide a means for specific intracellular conjugation of molecules. In this study, we used reactive tetrazine (Tz) and TCO moieties for labeling of organelles and organelle‐specific delivery and activation of doxorubicin prodrugs.
Oleh Durydivka, Marek Chovanec, Rastislav Dzijak, Michal Rahm, Jachym Hrusak, Paul E. Reyes‐Gutierrez, Milan Vrabel   +6 more
wiley   +1 more source

Three reversibly interconvertible redox states of boradigermaallyl: syntheses of radical allyl anion and allyl dianion. [PDF]

Chem Sci
Miehe SF, Eichele K, Schubert H, Bettinger HF, Sindlinger CP, Wesemann L.   +5 more
europepmc   +1 more source

Nickel‐Catalyzed Reductive Cross‐Coupling of Xanthate Esters With Aryl and Alkenyl Iodides

Chemistry – A European Journal, EarlyView.
A nickel‐catalyzed reductive cross‐coupling of xanthate esters and aryl/alkenyl iodides is reported without the need for separate activators for the xanthate esters. The reaction utilizes a relatively low catalyst loading. Diarylmethanes with a good functional group variety can thus be synthesized indirectly from the corresponding benzylic alcohols ...
Felix Vöhringer, Kathrin Zwettler, Dmitry I. Sharapa, Felix Studt, Ivana Fleischer   +4 more
wiley   +1 more source

Recent advances in sulfur-containing flavors of garlic (<i>Allium sativum</i> L.): formation mechanisms, controlling factors and innovative processing technologies. [PDF]

Food Chem X
Wu P, Dong T, Sun J, Chen H.
europepmc   +1 more source

FLP Mediated Conversion of Difluorobenzylalkynes to Fluoroallenyl Oniums via an SN1’ Pathway

Chemistry – A European Journal, EarlyView.
Frustrated Lewis pair (FLP) selective C‒F activation of difluorobenzylalkynes allows the formation of fluoroallenic oniums via an SN1’ substitution pathway. The fluoroallenic onium salts are synthetic precursors that allow subsequent functionalization at allenic and onium positions.
Max Coles, Tianhong Wang, Rubi McLennan, Long Kit Kwan, Bivas Mondal, Chakyu Richard Chan, Rowan D. Young   +6 more
wiley   +1 more source

Diastereoselective Copper‐Catalyzed Defluorosilylation of Pentafluoroethyl Alkenes to Access Polyfluorinated Allylsilanes

Chinese Journal of Chemistry, EarlyView.
Under copper(I) catalysis, pentafluoroethylated alkenes can undergo smooth defluorosilylation to generate novel polyfluorinated products. The reaction exhibits high levels of diastereoselectivities for obtaining multisubstituted allylsilanes with control of the double bond geometry.
Yuwei Zong, Yihan Tang, Gavin Chit Tsui
wiley   +1 more source

Synthesis, characterization, and α-glucosidase inhibitory activity of methyl proline derivatives of phenylpropanoid. [PDF]

RSC Adv
Zhang W, Yang H, Yao X, Li R, Yao Y, Ma W, Ma K, Shao L, Zhou P.   +8 more
europepmc   +1 more source

Learning Strategies from Nature's Blueprint to Cyclic Carbonate Synthesis

ChemSusChem, Volume 18, Issue 6, March 15, 2025.
The development of sustainable synthetic methods for cyclic carbonates draws inspiration from nature, focusing on eco‐friendly processes and renewable resources like CO2 and biomass. This review explore various CO2 activation mechanisms, green chemistry principles, and green catalysts.
Erika Saccullo, Vincenzo Patamia, Chiara Zagni, Antonio Rescifina, Giuseppe Floresta   +4 more
wiley   +1 more source

Stereoselective Prenylation of Aryl- and Heteroaryl Halides: γ-Selective Suzuki-Miyaura Coupling as a Tool for Asymmetric Csp²-Csp³ Cross-Coupling. [PDF]

J Org Chem
Pawlowsky C, Leipertz T, Henßen B, Haase M, Pietruszka J.   +4 more
europepmc   +1 more source

Remote Migratory Reductive Arylation of Unactivated Alkenes Enabled by Electrochemical Nickel Catalysis

ChemSusChem, Volume 18, Issue 6, March 15, 2025.
we have developed an electrochemical Ni−H catalyzed arylation coupling method of unactivated alkenes with aryl halides. The method displays broad functional group tolerance and proceeds under very mild conditions. Furthermore, aryl chlorides were also compatible substrates in this catalytic system. This conversion holds significant implications for the
Chao Xu, Ru‐Han A, Xiao‐Feng Wu
wiley   +1 more source