Reactions of t-BuOK and Dibenzyl, Benzyl Allyl, and Allyl β-Keto Sulfide Complexes of the Chiral Rhenium Lewis Acid [(η5-C5H5)Re(NO)(PPh3)]+: Highly Diastereoselective or Chemoselective [2,3]-Sigmatropic Rearrangements [PDF]
, 2016 Reaction of the dibenzyl sulfide complex [(η5-C5H5)Re(NO)(PPh3)(S(CH2Ph)2)]+TfO- (4a+TfO-) and t-BuOK (THF, −80 °C) gives the thiolate (η5-C5H5)Re(NO)(PPh3)(SCH(o-C6H4CH3)Ph) (5a; 99%) as a 96:4 mixture of SR,RS/SS,RR Re:C diastereomers.
Konrad Weickhardt (3082194) +5 more
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Quantification of volatile metabolites derived from garlic in human breast milk [PDF]
, 2022 S.603-610Maternal garlic intake during pregnancy and the breastfeeding period has been reported to be associated with the potential of modulating later garlic acceptance in infants.
Sharapa, Constanze +2 more
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Metabolites of diallyl disulfide and diallyl sulfide in primary rat hepatocytes [PDF]
, 2014 The objectives of this study were to analyse and identify the metabolites of diallyl disulfide (DADS) and diallyl sulfide (DAS) in primary rat hepatocytes prepared by collagenase perfusion.
Sheen, L.Y. +3 more
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Chinese onion (Allium chinense), an evergreen vegetable: A brief review [PDF]
, 2020 The history of using medicinal herbs and plant dates back to the ancient times. Chinese onion (Allium chinense) is famous as a plant for both food and medicinal purposes. It is widely cultivated as a vegetable and native to China. Its bulbs are commonly
Sun, Wenli +2 more
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Kinetic characterizations of diallyl sulfide analogs for their novel role as CYP2E1 enzyme inhibitors [PDF]
, 2017 Diallyl sulfide (DAS), a selective inhibitor of CYP2E1, has shown protective effects against alcohol- and acetaminophen-induced hepatotoxicity in many studies.
Santosh Kumar +9 more
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Toward absolute asymmetric synthesis of coordination polymers with bidentate sulfide ligands [PDF]
, 2013 In search for sulfide-containing coordination polymers that crystallize as conglomerates, five new copper(I) complexes with prochiral sulfide ligands have been prepared and characterized by single crystal Xray structure determination. Three unsymmetrical
Björemark, Per Martin, +4 more
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Product ion distributions for the reactions of NO(+) with some physiologically significant volatile organosulfur and organoselenium compounds obtained using a selective reagent ionization time-of-flight mass spectrometer [PDF]
, 2014 RATIONALE: The reactions of NO(+) with volatile organic compounds (VOCs) in Selective Reagent Ionization Time-of-Flight Mass Spectrometry (SRI-TOF-MS) reactors are relatively poorly known, inhibiting their use for trace gas analysis.
Amann, A +4 more
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Mechanochemistry Meets Catalysis: Metal Complexes for Greener Organic Transformations
Angewandte Chemie, Volume 138, Issue 29, 13 July 2026.Mechanochemistry is redefining metal catalysis by controlling catalyst formulation, speciation, and deployment. This Review shows how milling, LAG, RAM, and TSE enable rapid metal‐complex assembly, distinctive catalytic manifolds, and scalable synthesis beyond solution chemistry.
Sourav Behera +2 more
wiley +2 more sources
Nickel‐Catalyzed Reductive Cross‐Coupling of Xanthate Esters With Aryl and Alkenyl Iodides
Chemistry – A European Journal, EarlyView.A nickel‐catalyzed reductive cross‐coupling of xanthate esters and aryl/alkenyl iodides is reported without the need for separate activators for the xanthate esters. The reaction utilizes a relatively low catalyst loading. Diarylmethanes with a good functional group variety can thus be synthesized indirectly from the corresponding benzylic alcohols ...
Felix Vöhringer +4 more
wiley +1 more source
Reactions of Some Cyclomanganated Compounds with C-Nitroso Compounds, Allenes, and Ketenimines [PDF]
, 2008 eta2-(5-Methoxy-2-acetylphenyl)tetracarbonylmanganese (30) was reacted with 2-methyl-2-nitrosopropane (31) to form 2-acetyl-5-methoxy-N-(tert-butyl)aniline(43) in low yield.
Revell, John Bernard
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