Results 11 to 20 of about 16,757 (133)
A Short Total Synthesis of the Daucane Sesquiterpenoid Ferutinin
A straightforward total synthesis of the bioactive daucane sesquiterpene ester ferutinin is reported. Starting from 3‐methyl‐2‐cyclopentenone and allyl p ‐tolyl sulfoxide, only nine steps were required to access the target sesquiterpenoid in 22 ...
Christiane Osthaar +3 more
semanticscholar +2 more sources
This work focuses on how to improve the selectivity and activity of electrocatalytic CO2 reduction to C3+ products, by the integration of electrocatalyst and electrolyte co‐design. We summarize key C3+ formation mechanisms and provide a comprehensive reaction network through thermodynamic analysis.
Ling Chen, Damien Voiry, Yan Jiao
wiley +2 more sources
SOLUTION COPOLYMERIZATION OF ACRYLONITRILE WITH 1-ALLYL-3-METHYL-IMIDAZOLIUM
Ionic liquid comonomer 1-allyl-3-methyl-imidazolium(chloride(Cl)) was first used to copolymerize with acrylonitrile(AN) successfully in various conditions.This was achieved by using azobisisobutyronitrile as the initiator and dimethyl sulfoxide as the ...
Bai Yun-gang
semanticscholar +1 more source
Like a shark playing hide‐and‐seek in a coral reef, energy transfer (ET) finds hidden “fish” catalysts in the porous support “reef.” ET allows catalytic species to be precisely mapped, revealing whether they reside near the surface, deep in the pores, or are uniformly distributed. This approach ensures controlled catalyst distribution, highlighting how
Buddhima K. P. Maldeni Kankanamalage +8 more
wiley +2 more sources
Catalytic Functionalization of Unactivated π‐Bonds Enabled by Bidentate Directing Auxiliaries
This review explores how bidentate directing auxiliaries have advanced transition‐metal catalysis for unactivated alkene/alkyne functionalization. By leveraging chelated intermediates, bidentate directing auxiliaries enable precise hydrofunctionalization, difunctionalization, and C─H activation of π‐bonds with unique selectivity and reactivity.
Seunghyeon Cho +4 more
wiley +2 more sources
Borylcyclopropanes: Synthetic Strategies and Applications
Borylcyclopropanes (cyclopropanes bearing a boron substituent) sit at the intersection of two privileged frameworks in synthesis. This review provides the first exhaustive survey of their chemistry, spanning metal–carbene, nucleophilic cyclization, radical, hydroboration, and C─H activation routes, and documenting applications in medicinal chemistry ...
Aiza A. Butt, Joseph M. Ready
wiley +1 more source
Enhanced Degradation of Vinyl Copolymers Based on Lipoic Acid
ABSTRACT The introduction of degradable units into the backbone of commodity vinyl polymers represents a major opportunity to address the societal challenge of plastic waste and polymer recycling. Previously, we reported the facile copolymerization of α‐lipoic acid derivatives containing 1,2‐dithiolane rings with vinyl monomers leading to the ...
Yoichi Okayama +7 more
wiley +1 more source
Porous Organic Polymers: From Molecular Design to Scalable Technologies
This review introduces porous organic polymers (POPs) for a wide range of applications, including energy storage, gas adsorption, catalysts, adsorbents, biomedical applications, sensors, and other exciting fields, and critically analyzes the synthesis and modification, and how structural topology influences the composites' architecture of POPs, along ...
Hossein Mashhadimoslem +12 more
wiley +1 more source
Потенциальные взаимодействия лекарственных средств и чеснока
Every drug may cause central nervous system, gastrointestinal tract or cardiovascular system adverse drugs reactions (ADRs). At the same time, doctors often do not have sufficient information about possible food-drug interactions, in particular, garlic ...
A. P. Pereverzev, O. Ostroumova
semanticscholar +1 more source
This review highlights recent advances in the use of organic carbonates, dimethyl carbonate (DMC), diethyl carbonate (DEC), and propylene carbonate (PC), as solvents in organic synthesis. Based on over seventy studies from the past 6 years, it shows their application in different organic reaction types, emphasizing their role in safer and more ...
Gabriela T. Quadros +5 more
wiley +1 more source

