Results 11 to 20 of about 16,757 (133)

A Short Total Synthesis of the Daucane Sesquiterpenoid Ferutinin

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 24, 23 June 2026.
A straightforward total synthesis of the bioactive daucane sesquiterpene ester ferutinin is reported. Starting from 3‐methyl‐2‐cyclopentenone and allyl p ‐tolyl sulfoxide, only nine steps were required to access the target sesquiterpenoid in 22 ...
Christiane Osthaar   +3 more
semanticscholar   +2 more sources

Reaction Environment Engineering for Selective C3+ Formation in CO2 Electroreduction: Progress and Perspectives

open access: yesAngewandte Chemie, EarlyView.
This work focuses on how to improve the selectivity and activity of electrocatalytic CO2 reduction to C3+ products, by the integration of electrocatalyst and electrolyte co‐design. We summarize key C3+ formation mechanisms and provide a comprehensive reaction network through thermodynamic analysis.
Ling Chen, Damien Voiry, Yan Jiao
wiley   +2 more sources

SOLUTION COPOLYMERIZATION OF ACRYLONITRILE WITH 1-ALLYL-3-METHYL-IMIDAZOLIUM

open access: yes, 2009
Ionic liquid comonomer 1-allyl-3-methyl-imidazolium(chloride(Cl)) was first used to copolymerize with acrylonitrile(AN) successfully in various conditions.This was achieved by using azobisisobutyronitrile as the initiator and dimethyl sulfoxide as the ...
Bai Yun-gang
semanticscholar   +1 more source

Catalyst Hide‐and‐Seek Beneath Porous Support Surfaces: Pinpointing Active Site Distribution Through Resonance Energy Transfer

open access: yesAngewandte Chemie, Volume 138, Issue 30, 20 July 2026.
Like a shark playing hide‐and‐seek in a coral reef, energy transfer (ET) finds hidden “fish” catalysts in the porous support “reef.” ET allows catalytic species to be precisely mapped, revealing whether they reside near the surface, deep in the pores, or are uniformly distributed. This approach ensures controlled catalyst distribution, highlighting how
Buddhima K. P. Maldeni Kankanamalage   +8 more
wiley   +2 more sources

Catalytic Functionalization of Unactivated π‐Bonds Enabled by Bidentate Directing Auxiliaries

open access: yesAngewandte Chemie, Volume 138, Issue 28, 6 July 2026.
This review explores how bidentate directing auxiliaries have advanced transition‐metal catalysis for unactivated alkene/alkyne functionalization. By leveraging chelated intermediates, bidentate directing auxiliaries enable precise hydrofunctionalization, difunctionalization, and C─H activation of π‐bonds with unique selectivity and reactivity.
Seunghyeon Cho   +4 more
wiley   +2 more sources

Borylcyclopropanes: Synthetic Strategies and Applications

open access: yesAngewandte Chemie International Edition, EarlyView.
Borylcyclopropanes (cyclopropanes bearing a boron substituent) sit at the intersection of two privileged frameworks in synthesis. This review provides the first exhaustive survey of their chemistry, spanning metal–carbene, nucleophilic cyclization, radical, hydroboration, and C─H activation routes, and documenting applications in medicinal chemistry ...
Aiza A. Butt, Joseph M. Ready
wiley   +1 more source

Enhanced Degradation of Vinyl Copolymers Based on Lipoic Acid

open access: yesJournal of Polymer Science, Volume 63, Issue 6, Page 1345-1351, 15 March 2025.
ABSTRACT The introduction of degradable units into the backbone of commodity vinyl polymers represents a major opportunity to address the societal challenge of plastic waste and polymer recycling. Previously, we reported the facile copolymerization of α‐lipoic acid derivatives containing 1,2‐dithiolane rings with vinyl monomers leading to the ...
Yoichi Okayama   +7 more
wiley   +1 more source

Porous Organic Polymers: From Molecular Design to Scalable Technologies

open access: yesSmall, EarlyView.
This review introduces porous organic polymers (POPs) for a wide range of applications, including energy storage, gas adsorption, catalysts, adsorbents, biomedical applications, sensors, and other exciting fields, and critically analyzes the synthesis and modification, and how structural topology influences the composites' architecture of POPs, along ...
Hossein Mashhadimoslem   +12 more
wiley   +1 more source

Потенциальные взаимодействия лекарственных средств и чеснока

open access: yes, 2021
Every drug may cause central nervous system, gastrointestinal tract or cardiovascular system adverse drugs reactions (ADRs). At the same time, doctors often do not have sufficient information about possible food-drug interactions, in particular, garlic ...
A. P. Pereverzev, O. Ostroumova
semanticscholar   +1 more source

Dimethyl‐, Diethyl‐, and Propylene Carbonates: An Emerging Class of Green Solvents for Organic Synthesis

open access: yesThe Chemical Record, EarlyView.
This review highlights recent advances in the use of organic carbonates, dimethyl carbonate (DMC), diethyl carbonate (DEC), and propylene carbonate (PC), as solvents in organic synthesis. Based on over seventy studies from the past 6 years, it shows their application in different organic reaction types, emphasizing their role in safer and more ...
Gabriela T. Quadros   +5 more
wiley   +1 more source

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