(S)-Allyl-l-cysteine is the major bioactive compound in garlic. (S)-Allyl-l-cysteine is metabolized to (S)-allyl-l-cysteine sulfoxide, N-acetyl-(S)-allyl-l-cysteine, and N-acetyl-(S)-allyl-l-cysteine sulfoxide after oral administration. An accurate LC-MS/
Taehoon Park +5 more
core +1 more source
Pincer-Nickel-Catalyzed Allyl-Aryl Coupling between Allyl Methyl Ethers and Arylzinc Chlorides
The P,N,N-pincer nickel complex [Ni(Cl){N(2-Ph2PC6H4)(2′-Me2NC6H4)}]-catalyzed allyl-aryl coupling was studied. The reaction of allyl methyl ethers, including (1-methoxyallyl)arenes and (3-methoxyprop-1-en-1-yl)arenes, with arylzinc chlorides ...
Jian-Long Tao (1456900) +2 more
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The ionization potentials of methyl, allyl, and benzyl radicals have been measured directly by electron impact. The values found were methyl 9.95\ub10.03 ev, allyl 8,16\ub10.03 ev, and benzyl 7.73\ub10.08 ev.
Henderson, I.H.S. +2 more
core +1 more source
Application of sub-stoichiometric amounts of Grubbs' second generation catalyst to the substrate N-allyl-N-[2-(allylsulfanyl)phenyl]-4- methylbenzenesulfonamide afforded the ring-closed compound 6-[(4-methylphenyl) sulfonyl]-5,6-dihydro-2H-1,6 ...
Yadav D.B. +5 more
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Highly diastereoselective synthesis of enantioenriched anti-α-allyl-β-fluoroamines
A highly diastereoselective synthesis ofanti-a-allyl-b-fluoroamineshas been developed involving enantioselectivea-fluorination ofaldehydes followed by a diastereoselective Petasis allyl borono-Mannich reaction.
Thanaphat Thaima (20116911) +6 more
core
Hypoglycemic and hypolipidemic effect of S-allyl-cysteine sulfoxide (alliin) in DIO mice
Alliin (S-allyl cysteine sulfoxide) is a bioactive sulfoxide compound derived from garlic. To evaluate the preventive effect of alliin against metabolic risk factors in diet induced obese (DIO) mice, we treated the C57BL/6J DIO mice with drinking water ...
Kunlun Huang +7 more
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3-Allyl-1-methyl-1H-benzotriazol-3-ium iodide
In the crystal structure of 1-methyl-3-allyl benzotriazolium iodide, C10H12N3+·I−, centrosymmetric dimers of coplanar cations are π-stacked with an interplanar distance of 3.453 (6) Å.
Nabeel H. Buttrus +7 more
core +1 more source
Stable Carbocations. 198. Formation of Allyl Cations via Protonation of Alkynes in Magic Acid Solution. Evidence for 1,2-Hydrogen and Alkyl Shifts in the Intermediate Vinyl Cations [PDF]
Mayr, Herbert, Olah, George A.
core +1 more source
Onion (<i>Allium cepa L</i>.) Organosulfur Compounds: From Traditional Use to Modern Pharmacological Insights. [PDF]
Tang Y, Lv, Tao Y.
europepmc +1 more source
Harnessing Li-Ion Binding Energy for Solvation-Guided Electrolyte Additive Design and Robust Solid Electrolyte Interphase Reinforcement. [PDF]
Byun J +6 more
europepmc +1 more source

