Results 81 to 84 of about 3,282 (84)

Hydrogenation and isomerization of allyl alcohol and 3-cyclohexenol in presence of the chloromethyl methyl sulfoxide complexes of palladium and rhodium

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, 1973
1. The chloromethyl methyl sulfoxide complex of Pd catalyzes the hydrogenation of the C=C bond of allyl alcohol (AA) and 3-cyclohexenol, and also their rearrangement respectively to propionaldehyde and cyclohexanone. 2. The chloromethyl methyl sulfoxide complex of Rh accelerates the hydrogenation of AA and also its rearrangement, either ...
L. Kh. Freidlin, Yu. A. Kopyttsev, N. M. Nazarova   +2 more
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Reactions of 1,2-Epoxy-2-Methyl-3-butene with Lithio Derivatives of Allylic Sulfoxides. Syntheses of 2,6-Dimethylocta-3,7-dien-2,6-diol and of 5,8-Dehydro-4-0xo-nerolidol

Synthetic Communications, 1981
Abstract Our preceding studies have shown that lithio carbanions of protected cyanohydrins can undergo Michael additions to an isoprenic sulfoxide to yield lithio derivatives of allylic sulfoxides1. These results have led us to investigate the utilization of these lithio sulfoxides for new simple syntheses of aliphatic terpenes by head-to-tail linking ...
Eric Guittet, Sylvestre Julia
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ChemInform Abstract: REACTIONS OF 1,2‐EPOXY‐2‐METHYL‐3‐BUTENE WITH LITHIO DERIVATIVES OF ALLYLIC SULFOXIDES. SYNTHESES OF 2,6‐DIMETHYLOCTA‐3,7‐DIENE‐2,6‐DIOL AND OF 5,8‐DEHYDRO‐4‐OXONEROLIDOL

Chemischer Informationsdienst, 1982
AbstractDie aus dem Sulfoxid (I) in THF erzeugte Li‐Verbindung reagiert mit Isoprenoxid (II) zu einem Gemisch der Produkte (III), (IV) und (V).
E. GUITTET, S. JULIA
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The Absolute Configuration of Methyl Allyl Sulfoxide. Stereochemistry of the Grignard Synthesis of Optically Active Sulfoxides

Journal of the American Chemical Society, 1967
Paul. Bickart, Michael. Axelrod, John. Jacobus, Kurt. Mislow   +3 more
openaire   +1 more source