A facile and efficient synthetic protocol for the synthesis of α-amino amidines has been developed using a molecular iodine-catalyzed three-component coupling reaction of isocyanides, amines, and aldehydes. The presented strategy offers the advantages of
Praveen Reddy Adiyala +4 more
doaj +1 more source
Acrylamide Production Using Encapsulated Nitrile Hydratase from \u3cem\u3ePseudonocardia thermophila\u3c/em\u3e in a Sol–gel Matrix [PDF]
The cobalt-type nitrile hydratase from Pseudonocardia thermophila JCM 3095 (PtNHase) was successfully encapsulated in tetramethyl orthosilicate sol–gel matrices to produce a PtNHase:sol–gel biomaterial.
Elgren, Timothy E. +4 more
core +1 more source
Synthesis and In vitro Activity of N-sulfonylamidine-derived Pyrimidine Analogues [PDF]
Two novel series of N-sulfonylamidino pyrimidine derivatives were synthesized via Cu-catalyzed three-component reaction of propargylated nucleobases with different benzenesulfonyl azides and amines.
Bajić, Miroslav +5 more
core +2 more sources
Electrochemical Dehydration of Carboxamides to Their Nitriles
Electrochemical dehydration of carboxamides to nitriles is achieved using thiocyanate‐mediated activation, avoiding stoichiometric reagents. In an undivided cell at ambient conditions, 18 aromatic and aliphatic substrates give good‐to‐excellent yields (up to 84%) with functional‐group tolerance. Cyclic voltammetry supports an EC‐type‐mediated oxidation.
Enrico Lunghi +2 more
wiley +1 more source
Pathways to Meteoritic Glycine and Methylamine [PDF]
Glycine and methylamine are meteoritic water-soluble organic compounds that provide insights into the processes that occurred before, during, and after the formation of the Solar System.
Aponte, Jose C. +5 more
core +1 more source
Prevalence of Resistant Strains of Rhipicephalus microplus to Acaricides in Cattle Ranch in the Tropical Region of Tecpan of Galeana, Guerrero, Mexico [PDF]
Tick and tick borne diseases cause many problems to the cattle industry worldwide. The prevalence of resistant strains of Rhipicephalus microplus to different acaricides on cattle farms in the tropical region of Tecpan of Galeana, Guerrero, Mexico, and ...
J. Olivares-Pérez*, S. Rojas-Hernández, M.T. Valencia-Almazan, I. Gutiérrez-Segura and E.J. Míreles-Martínez
core
Strategies for the control of Rhipicephalus microplus ticks in a world of conventional acaricide and macrocyclic lactone resistance [PDF]
Infestations with the cattle tick, Rhipicephalus microplus, constitute the most important ectoparasite problem for cattle production in tropical and subtropical regions worldwide, resulting in major economic losses. The control of R.
Bhushan, Chandra +2 more
core +1 more source
An Amidinate‐Stabilized Germatrisilacyclobutadiene Ylide
AbstractThe synthesis and characterization of new amidinate‐stabilized germatrisilacyclobutadiene ylides [L3Si3GeL′] (L=PhC(NtBu)2; L′=ËL; Ë=Ge (3), Si (7)) are described. Compound 3 was prepared by the reaction of [LSiSiL] (1) with one equivalent of [LGeGeL] (2) in THF. Compound 7 was synthesized by the reaction of 2 with excess 1 in THF.
Yeong, Hui-Xian +6 more
openaire +3 more sources
In this study, we find CD55+ neutrophils show activated NETosis within bone marrow, induce BMSC senescence and osteogenesis inhibition, finally leading to bone aging initiation. Mechanistically, ROS synergizes with the CD55‐driven HIF1α‐PADI4 pathway to promote NETosis.
Yutong Guo +6 more
wiley +1 more source
A four-step synthesis of novel (S)-1-(heteroaryl)ethan-1-amines from (S)-Boc-alanine
A series of (S)-1-(pyrimidin-4-yl)-, and regioisomeric (S)-1-(pyrazolo[1,5-a]pyrimidin-7-yl)-, and (S)-1-(pyrazolo[1,5-a]pyrimidin-5-yl)ethan-1-amines were prepared by cyclisation of (S)-N-Boc-alanine-derived ynone with N,N-1,3-dinucleophiles, such as ...
Jurij Svete +3 more
doaj +1 more source

