The use of 1,1,3,3‐tetramethyldisiloxane (TMDSO) and potassium tert‐butoxide enables direct alkylation of weakly acidic carbon–hydrogen bonds with alkyl halides. Experimental and computational studies support the formation of a substrate‐associated hydride‐like base, providing a single‐step alternative to the classical deprotonation and electrophile ...
Piers St. Onge +4 more
wiley +2 more sources
Formation mechanism and regulation strategies of off-flavors in meat and meat products - An overall perspective. [PDF]
Pan L +6 more
europepmc +1 more source
Albumin as a dynamic extracellular redox regulator: from Cys34 oxidation biomarkers to polysulfide-mediated homeostatic mechanisms and clinical applications. [PDF]
Ishima Y +6 more
europepmc +1 more source
Metabolism of sulfur amino acids in Saccharomyces cerevisiae
Dominique Thomas, Y. Surdin-Kerjan
semanticscholar +1 more source
Dual modulation of toxic risks and functional benefits: How traditional practices enable safe consumption of toxic <i>Rhododendron decorum</i> Franch. in ethnic cuisine. [PDF]
Gao Y +6 more
europepmc +1 more source
Bottlebrush Polyolefin Sulfones as Triggerable and Degradable Pressure‐Sensitive Adhesives
A grafting‐through alternating copolymerization strategy yields poly(norbornene sulfone) bottlebrush polymers with high molar mass. These materials function as additive‐free pressure‐sensitive adhesives. The incorporation of cleavable sulfone units enables rapid breakdown under mild alkaline conditions, providing a pathway toward sustainable, high ...
Clark Vu +5 more
wiley +1 more source
Comparative impact of white and black garlic on intestinal homeostasis: barrier protection, inflammation and microbiota modulation. [PDF]
Girón-Hernández J +3 more
europepmc +1 more source
Electrocatalytic polarity inversion of azlactones unlocks their coupling with electron‐rich reaction partners. Triarylamine‐mediated oxidation of the azlactone enolate generates an electrophilic radical intermediate that undergoes selective C4 functionalization with diverse SOMOphiles.
Paula Rodríguez +6 more
wiley +1 more source
Investigation on the dynamic change of key odor compounds, free amino acids and chroma during soy sauce fermentation. [PDF]
Zhou Y +6 more
europepmc +1 more source

