Results 181 to 190 of about 1,338,850 (289)

Deprotonation and Alkylation of Weakly Acidic C(sp3)─H Bonds Through In Situ Generation of a Strong Hydride Base From 1,1,3,3‐Tetramethyldisiloxane and Potassium tert‐Butoxide

open access: yesAngewandte Chemie, EarlyView.
The use of 1,1,3,3‐tetramethyldisiloxane (TMDSO) and potassium tert‐butoxide enables direct alkylation of weakly acidic carbon–hydrogen bonds with alkyl halides. Experimental and computational studies support the formation of a substrate‐associated hydride‐like base, providing a single‐step alternative to the classical deprotonation and electrophile ...
Piers St. Onge   +4 more
wiley   +2 more sources

Metabolism of sulfur amino acids in Saccharomyces cerevisiae

open access: yesMicrobiology and Molecular Biology Reviews, 1997
Dominique Thomas, Y. Surdin-Kerjan
semanticscholar   +1 more source

Therapeutic paracetamol treatment in older persons induces dietary and metabolic modifications related to sulfur amino acids

open access: yesAGE, 2011
E. Pujos-Guillot   +8 more
semanticscholar   +1 more source

Bottlebrush Polyolefin Sulfones as Triggerable and Degradable Pressure‐Sensitive Adhesives

open access: yesAngewandte Chemie, EarlyView.
A grafting‐through alternating copolymerization strategy yields poly(norbornene sulfone) bottlebrush polymers with high molar mass. These materials function as additive‐free pressure‐sensitive adhesives. The incorporation of cleavable sulfone units enables rapid breakdown under mild alkaline conditions, providing a pathway toward sustainable, high ...
Clark Vu   +5 more
wiley   +1 more source

Electrocatalytic Polarity Inversion of Azlactones: Access to α‐Quaternary Amino Acids with Electron‐Rich SOMOphiles

open access: yesAngewandte Chemie, EarlyView.
Electrocatalytic polarity inversion of azlactones unlocks their coupling with electron‐rich reaction partners. Triarylamine‐mediated oxidation of the azlactone enolate generates an electrophilic radical intermediate that undergoes selective C4 functionalization with diverse SOMOphiles.
Paula Rodríguez   +6 more
wiley   +1 more source

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