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Observation of SOMO-HOMO Inversion in a Neutral Polycyclic Conjugated Hydrocarbon. [PDF]
Mishra S +5 more
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Hydrogen abstraction from H-donor substrates by the 6-CF3-benzotriazol-N-oxyl radical (TFNO)
Amorati +49 more
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Reversible stimuli responsive radicals and their EPR spectroscopic characterization [PDF]
Wang, D.
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Fundamental Role of N-O Bond-Containing Compounds in Prebiotic Synthesis. [PDF]
Sukhorukov AY.
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Aminoxyl radical addition to arylketenes
Journal of Physical Organic Chemistry, 2006AbstractKinetic studies of the addition of the aminoxyl radical TEMPO (2,2,6,6‐tetramethylpiperidinylaminoxyl, TO·) to the 4‐substituted phenylketenes 8 (4‐RC6H4CHCO, R = NO2, CN, Cl, H, CH3, CH3O) and to 3‐pyridylketene (15) reveal a correlation of logk2(TEMPO) with the Hammett sigma parameters of the substituents (including the aza substituent of ...
Austin Acton +4 more
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Aminoxyl radical substituted uranyl compounds
Inorganica Chimica Acta, 2001Abstract A series of adducts formed by association of the uranyl ion, UO 22+ , with either nitronyl nitroxide substituted pyridine andtriazole ligands or their imino nitroxide counterpart are described. The stability of the radical unit in the vicinity of the U centreappeared to be dependent on whether this unit is directly involved or not in the ...
Nathalie Daro +5 more
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Aminoxyl radicals as crosslinks for macromolecules of polyvinylpyrrolidone
Organic & Biomolecular Chemistry, 2004Using polyvinylpyrrolidone as an example, it has been shown that photolysis of ceric ammonium nitrate at room temperature can result in crosslinking of macromolecules. This process correlates with the formation of stable aminoxyl radicals, which are registered by EPR.
Evgenii Ya, Davydov +3 more
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Aminoxyl radicals bearing a mesogenic core
Tetrahedron Letters, 2001Abstract A series of aminoxyl radicals (nitronyl nitroxide or TEMPO) bearing biphenylcarbonitrile as a mesogenic core ( 2a–2c and 3a–3c ) was prepared. Among them, unusual magnetic transition from the original Curie–Weiss phase to another magnetic phase well expressed by a singlet–triplet model was found in the 4′-undecyloxy-4-biphenylcarbonitrile ...
Hiroshi Ikemoto +3 more
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