OH Radical Trapping with Benzoxazine nitrones: a combined computational and spectroscopic study. [PDF]
none1The hydroxyl radical addition onto 3-aryl-2H-benzo[1,4]oxazin-4-oxides spin traps yielded very persistent nitroxides. Their EPR spectra showed unusually large splitting due to the trapped OH proton, whose assignment has been possible by means of the
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Photochemical Transformations with Iodine Azide after Release from an Ion-Exchange Resin [PDF]
This report discloses the photochemical homolytic cleavage of iodine azide after its formation following release from polymer-bound bisazido iodate(I) anions.
Dräger, Gerald +3 more
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Degradation of Plastics - A Brief Review [PDF]
Plastics have been indispensable to humans because of their widespread applications due to their favorable mechanical and physical properties. Hence, the increasing demand for their production, coupled with their non-biodegradability, has drawn public ...
Jeffrey Ken B. Balangao
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Liquid Chromatography Analysis of Reactive Oxoammonium Cations [PDF]
This study presents the first liquid chromatography method for the quantitative and qualitative analysis of highly reactive oxoammonium cations based on a simple derivatization reaction.
Burges, Rene +5 more
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Ab Initio Study of Some Persistent Nitroxide Radicals [PDF]
Stable free radicals have a variety of applications. Particularly, the aminoxyl group is frequently used in spin-labeling experiments. Nitroxides may also exhibit intriguing chiral and magnetic properties, and can be of interest for studies of molecular ...
Horný, L'uboš +2 more
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Electron transfer reactions of piperidine aminoxyl radicals
This review article summarizes the electron transfer reactions of piperidine aminoxyl radicals. Electrochemical studies revealed the single electron transfer nature of piperidine aminoxyl radicals. In solution, piperidine aminoxyl radicals serve as single electron transfer oxidation reagent to react with various biologically interesting molecules such ...
Fa Zhang, YouCheng Liu
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Direct introduction of nitrogen and oxygen functionality with spatial control using copper catalysis. [PDF]
Synthetic chemists have spent considerable effort optimizing the synthesis of nitrogen and oxygen containing compounds through a number of methods; however, direct introduction of N- and O-functionality remains challenging.
Fisher, David J +4 more
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Detecting In Vivo Free Radicals in Various Disease Models [PDF]
In vivo free radical imaging in pre-clinical models of disease is now possible. Free radicals have traditionally been characterized by ESR or EPR spin trapping spectroscopy.
Smith, Nataliya, Towner, Rheal A.
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Electrosynthesis of Bioactive Chemicals, From Ions to Pharmaceuticals
This review discusses recent advances in electrosynthesis for biomedical and pharmaceutical applications. It covers key electrochemical materials enabling precise delivery of ions and small molecules for cellular modulation and disease treatment, alongside catalytic systems for pharmaceutical synthesis.
Gwangbin Lee +4 more
wiley +1 more source
Synthesis And Characterization Of (pyNO−)2GaCl: A Redox-Active Gallium Complex [PDF]
We report the synthesis of a gallium complex incorporating redox-active pyridyl nitroxide ligands. The (pyNO−)2GaCl complex was prepared in 85% yield via a salt metathesis route and was characterized by 1H and 13C NMR spectroscopies, X-ray diffraction ...
Carroll, P. J. +5 more
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