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Decoupling Mechanical and Conductive Dynamics of Polymeric Ionic Liquids via a Trivalent Anion Additive

Macromolecules, 2017
The mechanical and conductive properties of a polymeric ionic liquid (PIL) are decoupled through the addition of a fraction of trivalent anions to a chloride single-ion conductor. Trivalent phosphate ions strongly coordinate with polymer-bound imidazoliums, producing an increase in both the ionic conductivity and the polymer viscosity.
Joshua Bartels   +4 more
openaire   +1 more source

Lipophilic and immobilized anionic additives in solvent polymeric membranes of cation-selective chemical sensors

Analytica Chimica Acta, 1993
Abstract Lipophilic borate salts are frequently used as anionic additives in potentiometric and optical cation-selective sensors based on solvent polymeric membranes. The lifetime of such membranes may be limited owing to chemical decomposition and leaching of the components. Borate salts, in particular, are decomposed in the presence of acids in the
Thomas Rosatzin   +3 more
openaire   +1 more source

Enzymatic Remediation of Bisphenol A from Wastewaters: Effects of Biosurfactant, Anionic, Cationic, Nonionic, and Polymeric Additives

Water, Air, & Soil Pollution, 2020
One of the limitations compromising the utilization of enzymes for the remediation of phenolic wastewaters is enzyme activity loss during the treatment. Some surface active additives have the potential to protect enzymes and, thus, improve their performance. In this study, the removal of bisphenol A from synthetic wastewater samples by laccase has been
Muntathir Alshabib, Sagheer A. Onaizi
openaire   +1 more source

Highly Conductive Anion-Exchange Membranes Based on Cross-Linked Poly(norbornene): Vinyl Addition Polymerization

ACS Applied Energy Materials, 2019
Cross-linked (XL) anion-exchange membranes (AEMs) synthesized by vinyl addition polymerization of norbornene were prepared for use in anion-exchange membrane electrochemical devices, including fuel...
Mrinmay Mandal   +2 more
openaire   +1 more source

Additive Effect of p-Substituted Phenols on the Anionic Polymerization of Acrolein Induced by Imidazole

Journal of Macromolecular Science, Part A, 1986
Abstract Anionic polymerization of acrolein (AL) by imidazole in the presence of several p-substituted phenols such as phenol, p-methyl-phenol, and p-nitrophenol were kinetically carried out in tetra-hydrofuran at 0°C. The initial polymerization rate Rp was estimated from the rate of monomer consumption by means of gas chromatography.
Motoo Horiba   +2 more
openaire   +1 more source

Sequentially bridging anionic addition and ring-opening polymerization by cooperative organocatalysis: well-defined block copolymers from methacrylates and cyclic esters

Polymer Chemistry, 2022
Facile synthesis of well-defined block copolymers from “one-pot” sequential copolymerization of (meth)acrylates and cyclic esters were achieved by the optimalt-BuP4/(thio)ureas cooperative catalyst.
Meng Liu   +4 more
openaire   +1 more source

Multiblock Anion Conducting Copolymers Based on Vinyl Addition and Ring-Opening Metathesis Polymerization of Norbornenes

ECS Meeting Abstracts, 2018
Anion-exchange membranes (AEMs) have widespread applications in electrochemical devices. The development of AEMs with long-term alkaline stability and high hydroxide ion conductivity is currently of interest. The use of non-precious catalysts, facile reaction kinetics and reduced fuel crossover are some of the benefits over proton-exchange membranes
Mrinmay Mandal   +2 more
openaire   +1 more source

Hybrid copolymerization via mechanism interconversion between radical vinyl-addition and anion ring-opening polymerization

Polymer Chemistry, 2019
Here, we report a new hybrid copolymerization via an interconvertible living free radical and anion ring-opening polymerization mechanism, in which the copolymerization of cyclic monomers and vinyl-type monomers can be achieved.
Ze Zhang   +6 more
openaire   +1 more source

Preparation of periodic copolymers by living anionic polymerization mechanism assisted with a versatile programmed monomer addition mode

Polymer, 2018
Abstract Assisted by a versatile programmed monomer addition mode, the well-defined periodic Poly(styrene-per-isoprene) [Poly(St-per-Is)] copolymers are innovatively prepared by living anionic polymerization (LAP) of a general monomer pair of styrene and isoprene.
Zhiwei Zhao   +3 more
openaire   +1 more source

Anionic polymerization of 1,3‐cyclohexadiene: Addition of poly(1,3‐cyclohexadienyl)lithium to fullerene‐C60

Journal of Applied Polymer Science, 2009
AbstractThe addition of poly(1,3‐cyclohexadiene) (PCHD) carbanion to fullerene‐C60 (C60) was examined using poly(1,3‐cyclohexadienyl)lithium (PCHDLi), PCHDLi/1,4‐diazabicyclo[2,2,2]octane (DABCO), and PCHDLi/N,N,N′,N′‐tetramethylethylenediamine (TMEDA).
Itaru Natori, Shizue Natori
openaire   +2 more sources

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