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Anodic Oxidation of Pentaphenylcyclopentadienes [PDF]
Cyclic voltammetric oxidation of 1,2,3,4,5-pentaphenylcyclopentadiene has been studied in non-polar chloroalkane solvents (CH2Cl2 and CH2ClCH2Cl). The oxidation is reversible if tetra-n-butylammonium hexafluorophosphate (TBA^+PF6^-) is used as supporting electrolyte, but irreversible when tetra-n-butylammonium perchlorate (TBA^+ClO4^-) or tetra-n ...
Sanga, Jackson K.
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Oxide anodes in electro-organic oxidation. Oxidation of maleic addon tungsten oxide anodes
Journal of Applied Electrochemistry, 1982The electrochemical oxidation of maleic acid on tungsten anodes has been investigated. Glyoxal and carbon dioxide were the main products together with tartaric acid and acetaldehyde. Glyoxal is also obtained as the main product from the oxidation ofd-tartaric acid.
G. Filardo +3 more
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Formic Acid Electro-synthesis by Concurrent Cathodic CO2 Reduction and Anodic CH3OH Oxidation.
Angewandte Chemie, 2020Electrochemical conversion of carbon dioxide into energy carrying compounds or value-added chemicals is of great significance for diminishing the greenhouse effect and the efficient utilization of carbon dioxide emissions, which, however, suffers from ...
Xinfa Wei +3 more
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Anodic Oxidation of Organics on Oxide Anodes
1998The electrochemical oxidation (or combustion) of organics with simultaneous oxygen evolution has been investigated using different oxide electrodes. A simplified mechanism for the electrochemical oxidation of organics is presented, according to which selective oxidation occurs with oxide anodes (MOx) for which the formation of higher oxides (e.g.: MOX ...
Olivier Simond +2 more
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Organocatalyzed Anodic Oxidation of Aldehydes
Journal of the American Chemical Society, 2012A method for the catalytic formation of electroauxiliaries and subsequent anodic oxidation has been developed. The process interfaces N-heterocyclic carbene-based organocatalysis with electro-organic synthesis to achieve direct oxidation of catalytically generated electroactive intermediates. We demonstrate the applicability of this method as a one-pot
Eric E, Finney +2 more
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Anodic Oxidation for the Stereoselective Synthesis of Heterocycles.
Accounts of Chemical Research, 2019Stereodefined aliphatic heterocycles are one of the fundamental structural motifs observed in natural products and biologically active compounds.
Kosuke Yamamoto, M. Kuriyama, O. Onomura
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The Oxide TFT By Anodic Oxidation
ECS Meeting Abstracts, 2016Oxide-TFTs (thin film transistors) have been studied and are being applied to the AMLCD and AMOLED. One advantage of the oxide TFT is higher mobility than amorphous silicon TFT. The oxide material such as IGZO (indium gallium zinc oxide) is sputtered for the active layer.
Seong Min Shin +4 more
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Philosophical Magazine B, 1987
Abstract Key aspects of anodic film growth on aluminium at ambient temperatures in aqueous electrolytes, encompassing barrier- and porous-type films, are described. By direct observation of film sections, incorporating inert marker layers and tracers, in the transmission electron microscope and appropriate analysis, the locations of solid-film growth ...
G. E. Thompson +5 more
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Abstract Key aspects of anodic film growth on aluminium at ambient temperatures in aqueous electrolytes, encompassing barrier- and porous-type films, are described. By direct observation of film sections, incorporating inert marker layers and tracers, in the transmission electron microscope and appropriate analysis, the locations of solid-film growth ...
G. E. Thompson +5 more
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Canadian Journal of Physics, 1971
Anodization current efficiency measurements were used to determine the oxygen content of sputtered tantalum films. Films consisting mainly of b.c.c. Ta had less than 5 at.% oxygen while 'normal' β-Ta contained 10–15 at.% oxygen. Films with a more negative temperature coefficient of resistance had a higher oxygen content.The field strength required to ...
P. S. Wilcox, W. D. Westwood
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Anodization current efficiency measurements were used to determine the oxygen content of sputtered tantalum films. Films consisting mainly of b.c.c. Ta had less than 5 at.% oxygen while 'normal' β-Ta contained 10–15 at.% oxygen. Films with a more negative temperature coefficient of resistance had a higher oxygen content.The field strength required to ...
P. S. Wilcox, W. D. Westwood
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Boosting Hydrogen Production by Anodic Oxidation of Primary Amines over a NiSe Nanorod Electrode.
Angewandte Chemie, 2018For electrocatalytic water splitting, the sluggish anodic oxygen evolution reaction (OER) restricts the cathodic hydrogen evolution reaction (HER). Therefore, developing an alternative anodic reaction with accelerating kinetics to produce value-added ...
Yi Huang +4 more
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