Results 41 to 50 of about 13,953 (273)

Invisible Polymer Walls Enhance Reorientational Optical Nonlinearity in Oligothiophene‐Doped Liquid Crystals

open access: yesAdvanced Functional Materials, EarlyView.
The polymer wall stabilized dye‐doped liquid crystals (PWLCs) enhance the sensitivity of photoinduced molecular reorientation in dye‐doped LC systems. The PWLC with an invisible polymer wall successfully reduces the threshold intensity and functions as an optical limiter under the incidence of low intensity light laser source.
Junki Yokota   +6 more
wiley   +1 more source

Dye‐Initiated Chirped Cholesteric Polymer Networks Exhibiting Broadband Dissipative Chiral Photonic Bands

open access: yesAdvanced Functional Materials, EarlyView.
A dye‐based photoinitiator acting as a structure‐directing element, guides the formation of a cholesteric polymer network that behaves as a chirped photonic structure with dissipative chiral coupling. Photopolymerization freezes a depth‐dependent helical pitch, broadening the Bragg resonance spectrum.
Alfredo Mazzulla   +2 more
wiley   +1 more source

Solar‐driven co‐evolution of H2 and H2O2 from pure water splitting over emerging photocatalysts: Detailed mechanism and future outlook

open access: yesPhotoMat, EarlyView., 2023
Photocatalytic water splitting for co‐evolution of H2 and H2O2 is deemed as a sustainable and promising strategy to address energy and environment issues, thus receiving increasing attention and realizing continuous achievements. This review aims to offer a deep understanding of the mechanism for H2 and H2O2 co‐evolution and the design principle of ...
Qiaohong Zhu   +4 more
wiley   +1 more source

Supramolecular Modulation of Photoinduced Charge Transfer: Tuning Between Tunneling and Incoherent Hopping

open access: yesAngewandte Chemie, EarlyView.
Molecular recognition guest binding can comprehensively modulate photoinduced charge‐transfer dynamics in the cyclophane host, including charge separation and recombination, via coherent superexchange and incoherent hopping. Unlike covalent donor–bridge–acceptor systems, this supramolecular approach avoids tedious syntheses and offers precise tuning of
Xueze Zhao   +11 more
wiley   +2 more sources

New Anthraquinones and Anthraquinone Glycosides from Morinda lucida

open access: yesZeitschrift für Naturforschung B, 1981
Abstract From the trank heartwood of Morinda lucida four new anthraquinones, 3-hydroxy-anthraquinone-2-carbaldehyde, morindone-5-methyl ether, munjistin methyl ester, damna-canthol-ѡ-methyl ether and two glycosides, soranjidiol 6-0-β-primveroside and lucidin 3-0-β-primveroside were isolated and identified by spectroscopic and chemical ...
George P. Demagos   +2 more
openaire   +1 more source

Beyond Presumptions: Toward Mechanistic Clarity in Metal‐Free Carbon Catalysts for Electrochemical H2O2 Production via Data Science

open access: yesAdvanced Materials, EarlyView.
Metal‐free carbon catalysts enable the sustainable synthesis of hydrogen peroxide via two‐electron oxygen reduction; however, active site complexity continues to hinder reliable interpretation. This review critiques correlation‐based approaches and highlights the importance of orthogonal experimental designs, standardized catalyst passports ...
Dayu Zhu   +3 more
wiley   +1 more source

Recent advances in photocatalytic hydrogen peroxide production

open access: yesPhotoMat, EarlyView., 2023
We classify the representative photocatalytic materials for photosynthesis of hydrogen peroxide (H2O2) in recent years and discuss the related modification methods in detail, providing inspiration and insights for the future design of photocatalysts for H2O2 production.
Jinyu Yan   +4 more
wiley   +1 more source

Cage‐Type Porous Organic Salts as Ship‐in‐a‐Bottle Nanoreactors for Light‐Transparent and Reusable Molecular Photocatalysts

open access: yesAngewandte Chemie, EarlyView.
Light‐transparent, cage‐type porous organic salts (POSs) function as nanoreactors that heterogenize molecularly defined photocatalysts through size exclusion. Photocatalysts are encapsulated intact during crystallization, providing confined yet accessible reaction fields under visible light without catalyst modification.
Kazuki Shiga   +5 more
wiley   +2 more sources

Promising Inhibitory Effects of Anthraquinones, Naphthopyrone, and Naphthalene Glycosides, from Cassia obtusifolia on α-Glucosidase and Human Protein Tyrosine Phosphatases 1B

open access: yesMolecules, 2016
The present work aims to evaluate the anti-diabetic potentials of 16 anthraquinones, two naphthopyrone glycosides, and one naphthalene glycoside from Cassia obtusifolia via inhibition against the protein tyrosine phosphatases 1B (PTP1B) and α-glucosidase.
Hyun Ah Jung   +2 more
doaj   +1 more source

Selective organocatalytic oxygenation of hydrocarbons by dioxygen using anthraquinones and N-hydroxyphthalimide

open access: yes, 2005
Purely organic and catalytic systems of anthraquinones and N-hydroxyphthalimide efficiently promote oxygenation of hydrocarbons with dioxygen under mild conditions, e.g., fluorene can be converted completely to fluorenone with 85% yield at 80 ...
Xu, J   +5 more
core   +1 more source

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