Introducing Diradicaloid Thiele's Hydrocarbon Derivatives as Ligand in Transition Metal Chemistry
Angewandte Chemie, Volume 138, Issue 41, 5 October 2026.N‐doped Thiele's hydrocarbon derivative is introduced as a ligand for the synthesis of mono‐ and bimetallic rhodium complexes as well as cyclometalated iridium complexes. These compounds constitute the first metal complexes based on a Thiele's hydrocarbon (or p‐quinodimethane) derivative and, to the best of our knowledge, the first cyclometalated ...
Alok Mahata +2 more
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Mapping structure-property relationships in a 6-oxo-verdazyl radical by variable pressure crystallography and density functional theory. [PDF]
Acta Crystallogr B Struct Sci Cryst Eng MaterBrookes JR +7 more
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Angewandte Chemie, Volume 138, Issue 41, 5 October 2026.Imine‐linked 2D covalent organic frameworks incorporating delocalized trioxotriangulene (TOT) neutral radicals were synthesized through complementary routes. Direct incorporation of an amine‐functionalized TOT radical yields a highly crystalline, porous framework (TOT‐COF‐H) with intrinsic semiconducting behavior (σRT = 1.2 × 10−4 S cm−1) and a narrow ...
Paula Escamilla +8 more
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Spin and Inversion-Driven Modulation of Structural, Electronic, and Vibrational Properties in ZnMn<sub>2</sub>O<sub>4</sub>: A Hybrid DFT Study. [PDF]
ACS OmegaAlmutairi TS.
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Giant Topological Hall Effect Across a Broad Temperature Window in Co-Doped Mn<sub>3</sub>Sn Noncoplanar Antiferromagnets. [PDF]
Adv Sci (Weinh)Zhang M +6 more
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A high solar cell efficiency of 32%, water-splitting for hydrogen generation, optoelectronics, and super-exchange coupling in Ba<sub>2</sub>MnTiO<sub>6</sub>: a DFT and AIMD study. [PDF]
RSC AdvMalik H +4 more
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Radiation Resilient Synthetic Antiferromagnets-Based Neuromorphic Device for Sea Surface Temperature Reconstruction. [PDF]
Adv Sci (Weinh)Song M +5 more
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