Efficient Microwave‐Assisted Hydrolytic Recycling of Poly(L‐Lactic Acid)
Microwave‐assisted hydrolysis of poly(lactic acid) promoted by a zinc catalyst. A highly efficient procedure performed under mild reaction conditions and in the absence of solvents aligning with green chemistry principles. Poly(L‐Lactic acid) (PLLA) is a bio‐based and biodegradable thermoplastic polymer widely recognized as a leading sustainable ...
Federica Santulli +6 more
wiley +1 more source
The Formation of Covalent Linkages in Lignocellulosic Biomass via the Oxocarbenium Intermediate
Density functional theory models show that the hydrated and acidic hemicellulose matrix in lignocellulosic biomass can generate oxocarbenium ions. These reactive intermediates can participate in the stable formation of glycosidic lignin‐carbohydrate covalent linkages, promoting recalcitrance in plant biomass.
Eduardo Romero‐Montalvo +1 more
wiley +1 more source
Autoxidation of 1-Isopropylazulene in Aprotic Polar Solvents
Yoshiharu MATSUBARA +4 more
openalex +2 more sources
Determination of the Equilibrium Constant for the Tautomeric 9-Hydroxyanthracene/9-Anthrone System in Aprotic Solvents by a Novel Application of Cyclic Voltammetry. [PDF]
Kristoffer Almdal +6 more
openalex +1 more source
Structure-Selective Recognition by Voltammetry: Enantiomeric Determination of Amines Using Azophenolic Crowns in Aprotic Solvent [PDF]
Kyungmin Chun +6 more
openalex +1 more source
Unorthodox Thermodynamic Enolate Coupled with a Radical Pathway A transition‐metal‐free oxidation of biomass‐derived levulinic acid to citramalic acid is achieved through an unorthodox enolate in combination with a radical pathway using potassium tert‐butoxide (KOtBu) and molecular oxygen (O2).
Geun Ho Kim +4 more
wiley +1 more source
Controlled Polymer Synthesis Toward Green Chemistry: Deep Insights into Atom Transfer Radical Polymerization in Biobased Substitutes for Polar Aprotic Solvents. [PDF]
Zaborniak I +8 more
europepmc +1 more source
Dehydration of cellulose to levoglucosenone using polar aprotic solvents
Fei Cao +5 more
openalex +2 more sources
Dispersion‐Enhanced Nitrogen‐Centered Photocatalysis of the Direct Hydrogen Atom Transfer
Nitrogen‐centered acridine photocatalysts for direct hydrogen atom transfer have been developed, leveraging dispersion interactions to enhance photocatalytic activity. This approach enables diverse functionalization reactions of strong C─H bonds even under cryogenic conditions and provides a new strategy for boosting the efficiency of direct HAT ...
Jiasong Zhang +16 more
wiley +2 more sources

