Results 161 to 170 of about 7,821 (247)

A Comparative Study of the Influence of Water and Temperature on the Racemization of Five‐ and Six‐Membered l‐Alanine‐Derived Imides

open access: yesChirality, Volume 38, Issue 8, August 2026.
Racemization of chiral imides in dimethylformamide is shown to increase with increasing water content and temperature. The six‐membered imide ring system is more stable than the five‐membered analogue, with slower racemization under identical conditions and an absence of competing side reactions.
Diksha U. Sawant   +4 more
wiley   +1 more source

Solvent-dependent reactivity of azo-BF<sub>2</sub> switches. [PDF]

open access: yesChem Sci
Qi Q   +5 more
europepmc   +1 more source

Design, Synthesis, and Biological Evaluation of Chiral Urea and Thiourea Derivatives as Multitarget‐Directed Anti‐Alzheimer Agents

open access: yesDrug Development Research, Volume 87, Issue 5, August 2026.
ABSTRACT A series of novel chiral urea and thiourea compounds were designed as multitarget‐directed ligands for Alzheimer's disease and evaluated against hAChE, hBChE, and hMAO‐B, with exploratory assessment of HSD10. These chiral compounds were synthesized and fully characterized, and their enantiopurity was confirmed via HPLC.
Sule Erol Gunal   +10 more
wiley   +1 more source

Dioxomolybdenum(VI) Complexes Supported by Fluxional Bis(amide)‐Functionalized Aminophenolate Ligands

open access: yesEuropean Journal of Inorganic Chemistry, Volume 29, Issue 22, 1 August 2026.
New bis(amide) aminophenolate ligands form dioxomolybdenum(vi) and dioxotungsten(vi) complexes showing solvent‐dependent nuclearity. Whilst monomeric complexes featuring methoxide ligands are obtained in methanol, water triggers formation of μ‐oxo‐bridged dimers via oxo exchange, verified by 18O labelling.
Pasi Vikberg   +3 more
wiley   +1 more source

A Systematic Study of Auxochrome Effects on Fluorescence Under Conditions of Varying Temperature, pH, or Viscosity: Photo‐induced electron transfer and Twisted Intramolecular Charge Transfer

open access: yesChemistryOpen, Volume 15, Issue 8, August 2026.
The effects of temperature, pH, and viscosity on the fluorescence quenching processes PET and TICT are systematically studied by combining eight amine donors with each of three fluorogenic cores. Fluorescence intensity results from an interplay of structural and environmental factors.
Amina Bibi   +2 more
wiley   +1 more source

Von Richter Cinnolines Synthesis Revisited—Approach to Polysubstituted Cinnoline Derivatives as Important Scaffolds for Kinase Inhibitors

open access: yesChemistrySelect, Volume 11, Issue 29, 3 August 2026.
A revised von Richter cyclization of 2‐aminoalkyne precursors enables the synthesis of polysubstituted 4‐halocinnoline derivatives. By addressing the key challenge of hydrolytic instability, this catalyst‐free approach delivers scaffolds amenable to late‐stage C‐4 functionalization.
Krystof Skach   +3 more
wiley   +1 more source

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