Biological Potential and Physicochemical Properties of Ionic Liquids Bioinspired by Carboxylic Acids: A Review. [PDF]
Terán C, Mato MM, Besada P.
europepmc +1 more source
A Proposed Complete‐Cycle Mechanism for Conversion of N2 to NH3 by Mo‐Nitrogenase
How does the enzyme nitrogenase convert N2 to NH3 under ambient conditions? Here I describe a proposed complete cycle of the chemical mechanism, with computed energy profiles and kinetic barriers for a sequence of 31 reaction steps, encompassing 40 intermediates. How does the enzyme nitrogenase convert N2 to NH3 under ambient conditions?
Ian Dance
wiley +1 more source
Cyrene Dimethyl Acetal: Potential Alternative Solvent for Pd-Catalyzed Homogeneous Aminocarbonylation of Iodo(hetero)arene Compounds. [PDF]
Takács A +6 more
europepmc +1 more source
An in situ NMR method using isotopically enriched 13CO2 reveals regioisomeric cation‐CO2 adducts in asymmetric phosphonium‐based aprotic N‐heterocyclic anion ionic liquids. Two distinct carboxylate species, formed at chemically nonequivalent α‐carbons, are unambiguously identified and quantified.
Pranav J. Thacker +3 more
wiley +1 more source
A Promising Strategy for Solvent-Regulated Selective Hydrogenation of 5-Hydroxymethylfurfural over Porous Carbon-Supported Ni-ZnO Nanoparticles. [PDF]
Huang R +6 more
europepmc +1 more source
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley +1 more source
Synthesis of Polyimides, Polyamides, and Poly(Amide-Imides) in the "Green" Solvent N-Butyl-2-Pyrrolidone (TamiSolve NxG): Features, Optimization, and Versatility. [PDF]
Zabegaeva ON +4 more
europepmc +1 more source
Versatile Palladium‐Catalyzed C‐H Arylation of Fluoroarenes with 2‐Chloropyridine Derivatives
Direct C─H arylation of fluoroarenes with 2‐chloropyridines is enabled by a simple Pd/SPhos system in isopropyl acetate. The method uses inexpensive reactants and shows broad scope and high yields. DFT computations explain reactivity and selectivity.
Federico Belnome +6 more
wiley +1 more source
Linear Actuation of Dielectrophoretic Formed Multi-Walled Carbon Nanotube Fiber with Carbide-Derived Carbon in Polar Aprotic and Polar Protic Solvents. [PDF]
Tran CB, Le QB, Kiefer R.
europepmc +1 more source
We report the synthesis, structural characterization, and photophysical investigation of a series of Excited‐State Intramolecular Proton Transfer‐active HBO and HDMI derivatives. By varying heterocyclic cores, substituents, and ethynyl planarization, we establish structure–property relationships governing fluorescence behavior.
Mathieu Gervais +7 more
wiley +1 more source

