Results 171 to 180 of about 11,464 (289)

Pd‐Catalyzed Cyclotrimerization and Cycloaddition of 5,6‐Didehydrobenzo[8]annulenes (BenzoCOTynes): Formation of Nonplanar Tri[8]annulenes and Diels–Alder Cycloadducts

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 23, 16 June 2026.
A Pd(0)‐catalyzed cyclotrimerization of benzoCOTynes to form tri(benzo[8]annulenes) was developed. Three distinct isomers were isolated and structurally characterized by single‐crystal X‐ray diffraction. Ligand modulation proved crucial for enhancing regioselectivity: P(4‐OMePh), and (S)‐tBu‐Phox promoted the formation of the symmetric isomers.
Jesús Bello‐García   +2 more
wiley   +1 more source

Real‐Time Monitoring of Excited‐State Ring‐Puckering Process in BODIPY Molecule Using Ultrafast Spectroscopy

open access: yesChemPhysChem, Volume 27, Issue 11, 15 June 2026.
Pyrromethene 597 (PM597), a commercial laser dye, shows a lower fluorescence yield than its analogues. Ultrafast dynamics studies using femtosecond fluorescence upconversion and transient absorption revealed that a non‐radiative ring‐puckering process in the excited state of PM597, occurring with a time constant of 1.3 ps, is primarily responsible for ...
Ayentika Sen   +2 more
wiley   +1 more source

Once Upon a Time Without DMF: Greener Paths in Peptide and Organic Synthesis. [PDF]

open access: yesMolecules
Scognamiglio A   +5 more
europepmc   +1 more source

Defined Nylon Oligomers Enable Mechanistic Insight Into Enzymatic Polyamide Depolymerization

open access: yesChemSusChem, Volume 19, Issue 11, 15 June 2026.
The remarkable progress in enzymatic polyester depolymerization has demonstrated the potential of biocatalysis for sustainable polymer recycling. In contrast, enzymatic polyamide (PA) degradation remains poorly understood, largely due to the lack of defined and accessible model substrates.
Sukmanita Dewi   +3 more
wiley   +1 more source

Solvation-mediated isomerization of surface motifs tunes emissions and electron transfer dynamics in gold nanoclusters. [PDF]

open access: yesNat Commun
Wang X   +14 more
europepmc   +1 more source

Innovating Electrosynthesis From Metal Electrodeposition to Organic Chemistry: Deep Eutectic Solvents as Efficient and Sustainable Media

open access: yesChemSusChem, Volume 19, Issue 11, 15 June 2026.
This review analyzes deep eutectic solvents (DESs) as efficient media for both organic and inorganic electrosynthesis. The improvements in terms of synthetic opportunities and sustainability are discussed, by exploring the multiple roles of DESs as solvents, electrolytes, and promoters, enabling effective and selective electrosynthesis under mild and ...
Cristiana Margarita   +6 more
wiley   +1 more source

Mechanochemical SNAr on Phthalonitriles: Distinct Reactivity and Selectivity in One‐Pot Synthesis for Greener Phthalocyanines

open access: yesChemSusChem, Volume 19, Issue 11, 15 June 2026.
Mechanochemical nucleophilic aromatic substitution enables efficient, reproducible functionalization of phthalonitriles under minimal solvent conditions with high versatility. Integrating this process with solid‐state cyclotetramerization affords metalated and metal‐free phthalocyanines in a streamlined sustainable one‐pot workflow.
Obed Rodriguez‐Perez   +3 more
wiley   +1 more source

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