Results 51 to 60 of about 218,279 (284)

Linker‐Locking Strategy for the Rigidification of Flexible Metal–Organic Framework: Structural Stabilization and Controlled ESIPT for H2O/D2O Sensing

Advanced Science, EarlyView.
A linker‐locking strategy rigidifies the flexible metal–organic framework (MOF) MIL‐53‐(OH)2 via the cooperative encapsulation of ligands and structural water. This network significantly enhances the framework's aqueous stability. Crucially, rigidification suppresses enol emission to yield a single keto tautomer state with an extended lifetime ...
Amitosh Sharma, Seonghwan Lee, Seo I Park, Hak‐Won Nho, Junmo Seong, Eunseo Lee, Oh‐Hoon Kwon, Myoung Soo Lah, Jaewoong Lim   +8 more
wiley   +1 more source

Synthesis of Large‐ and Medium‐Sized Heterobiaryl Atropisomeric Rings and Atropopeptides by Catalytic Intramolecular SNAr

Angewandte Chemie, EarlyView.
Catalytic, intramolecular N‐heterocycle arylation by nucleophilic aromatic substitution (SNAr) is now available for synthesis of highly strained macrocycles and medium‐sized heterobiaryl atropisomeric rings, including atropopeptides. Key to the approach is the ability to generate a strong base catalytically, taking advantage of base‐embedding ...
Alireza Abbasi Kejani, Paritosh Dey, Nicholas H. Stillman, Daniel M. Andrade, Michal Šimek, Martin Dračínský, Daniel Bím, Paulo H. S. Paioti   +7 more
wiley   +2 more sources

Facile Synthesis of Functionalized Phenoxy Quinolines: Antibacterial Activities against ESBL Producing Escherichia coli and MRSA, Docking Studies, and Structural Features Determination through Computational Approach

Molecules, 2022
The synthesis of new 6-Bromoquinolin-4-ol derivatives (3a–3h) by Chan–Lam coupling utilizing different types of solvents (protic, aprotic, and mixed solvents) and bases was studied in the present manuscript.
Mahwish Arshad, Nasir Rasool, Muhammad Usman Qamar, Syed Adnan Ali Shah, Zainul Amiruddin Zakaria   +4 more
doaj   +1 more source

Baylis−Hillman Mechanism:  A New Interpretation in Aprotic Solvents

, 2016
Using reaction rate data collected in aprotic solvents, we have determined that the Baylis−Hillman rate-determining step is second order in aldehyde and first order in DABCO and acrylate.
Hyun M. Jung (2696296), Kristin E. Price (1916002), Steven J. Broadwater (2522134), D. Tyler McQuade (1554988)   +3 more
core   +1 more source

Solvent‐Free Synthesis of Ultrabright Carbon Dots With Near‐Unity Quantum Yield for High‐Performance Light‐Emitting Diodes

Advanced Science, EarlyView.
A rational, solvent‐free synthesis utilizing 2,6‐diaminonaphthalene produces ultrabright green‐emissive carbon dots. Regulated by a self‐limiting oxidative capping mechanism, excitons undergo ultrafast intra‐particle funneling from the nitrogen‐doped carbon core to emissive surface traps.
Hyeonjin Park, Su Hwan Lee, Sejeong Seo, Soye Park, Soo min Ji, Hyunda Jo, Sehyeon Park, Young‐Hoon Kim, Woosung Kwon   +8 more
wiley   +1 more source

Dielectric spectra of some common solvents in the microwave region. Dipolar aprotic solvents and amides

, 1990
Precise complex permittivity spectra of the amides formamide, N-methylformamide (NMF), N,N-dimethylformamide, and N,N-dimethylacetamide and of the dipolar aprotic solvents acetonitrile, propylene carbonate, and DMSO were detd. at 0.95-89 GHz. The dielec.
R. Buchner, M. Kleebauer, Gill, J. B., Barthel, Josef, J. Barthel, K. Bachhuber, Bachhuber, K., Kleebauer, M., Buchner, Richard, J.B. Gill   +9 more
core   +1 more source

N-Butylpyrrolidinone as a dipolar aprotic solvent for organic synthesis [PDF]

, 2016
Dipolar aprotic solvents such as N-methylpyrrolidinone (or 1-methyl-2-pyrrolidone (NMP)) are under increasing pressure from environmental regulation. NMP is a known reproductive toxin and has been placed on the EU “Substances of Very High Concern” list ...
Moonen, Kristof, Hunt, Andrew John, Farmer, Thomas James, Sherwood, James Richard, Parker, Helen Louise   +4 more
core   +1 more source

Toward Rational Design of Aqueous Battery Membranes Beyond the Selectivity‐Conductivity Trade‐Off

Advanced Science, EarlyView.
This review examines sulfonated membranes for redox flow batteries. It focuses on proton transport mechanism, membrane design, performance limits, optimization strategies, and the pathway from molecular design to membrane manufacturing. ABSTRACT Electrochemical energy‐storage systems increasingly require membranes that can simultaneously deliver fast ...
Jinkang Liu, Mingbo Xie, Zhenghao Wang, Huacun Li, Jun Xie, Pan Liu, Qingwei Wang, Xu Yan, Meiqing Shi, Liyuan Chai, Yue Luo, Zining Tang, Rui Tan, Liyuan Zhang   +13 more
wiley   +1 more source

Deciphering Intricacies in Directional CO2 Conversion From Electrolysis to CO2 Batteries

Advanced Energy Materials, EarlyView.
This review will delve into the inherent connections and distinctions of CO2‐directed conversion in ECO2RR and CO2 batteries, in terms of product types, catalyst selection, catalytic mechanisms, and electrochemical performances, while proposing a benchmarking framework for the evaluation of CO2 batteries and innovative CO2 battery configurations for ...
Changfan Xu, Huaping Zhao, Lizhuang Chen, Weidong Shi, Guosheng Shao, Yong Lei   +5 more
wiley   +1 more source

Sensitive Detection of Halides and Nitrate in Organic and Aqueous Solvents through Selective Halogen Bonding on TTF‐SAM‐Modified Platinum Electrodes

ChemElectroChem, 2022
Tetrathiafulvalene derivatives were chemisorbed on platinum electrodes. The electrochemical behavior and the stability of the resulting redox active self‐assembled monolayers in the presence of various anions was studied by cyclic voltammetry.
Dr. Hussein Hijazi, Dr. Eric Levillain, Prof. Dr. Bernd Schöllhorn, Dr. Claire Fave   +3 more
doaj   +1 more source