Results 71 to 80 of about 218,279 (284)
Electron Injection from a Carboxylic Anchoring Dye to TiO2 Nanoparticles in Aprotic Solvents [PDF]
Injection of photoexcited electrons in the para-Ethyl Red dye to TiO2 nanoparticles (Anatase, 40 nm diameter) is characterized by transient absorption on ultrafast time scales.
Fang, Hui +12 more
core +1 more source
The effect of aprotic solvents on the adsorption of phenol by alumina
Abstract The isotherms for the adsorption of phenol onto alumina from cyclohexane, benzene, nitrobenzene, ethyl acetate and 1,4-dioxan solutions have been determined at 25°. The change in solvent in the above order causes a successive decrease in the amount of phenol adsorbed at the ‘saturation level’ and possible explanations of the ...
B, Higgins, J H, Richards
openaire +2 more sources
Pd-catalysed C–C bond formation is an essential tool within the pharmaceutical and agrochemical industries. Many of these reactions rely heavily on polar aprotic solvents; however, despite their utility, these solvents are incompatible with the drive ...
Kirsty L. Wilson +5 more
doaj +1 more source
Solvolytic Reaction Rates of Secondary Aralkyl Chlorides in Dipolar Aprotic Solvents
Activation parameters, p-values, and .a-βeuterium effects of solvolytic reaction of 1-aryl-1-chloroethanes 2a-c were compared with those of 2-aryl-2-chloropropanes la-c in aprotic solvents.
ASAHI, Momoyo, TAKANE, Uchida
core
The electrochemical behavior of three newly synthesized Schiff-base Co(II)-complex with N2SO donor group was investigated. In different non-aqueous media such as acetonitrile (AN) and %50w/w dichlromethane-dimetylsulfoxide (CH2Cl2-DMSO) mixture as ...
Sohrab Ershad +3 more
doaj +1 more source
Determination of Enantiomeric Excess in Confined Aprotic Solvent
The validation of the stereochemical purity of synthesized compounds is a requisite for the fine-chemical industry, particularly in the production of enantiopure drug compounds. However, most methodologies employed in the determination of enantiopurity require carefully chosen chiral GC or HPLC columns, increasing associated cost, analysis time, and ...
Emer B. Farrell +5 more
openaire +2 more sources
Water clustering modulates activity and enables hydrogenated product formation during carbon monoxide electroreduction in aprotic media [PDF]
Water solvation plays a critical role in a wide range of electrochemical transformations, but its role is often convoluted since it is typically used as both solvent and proton source.
Reginaldo, Gomes +7 more
core +1 more source
A cautionary tale of basic azo photoswitching in dichloromethane finally explained
Many studies of azobenzene photoswitches are carried out in polar aprotic solvents as a first principles characterization of thermal isomerization. Among the most convenient polar aprotic solvents are chlorinated hydrocarbons, such as DCM.
Coral Hillel +4 more
doaj +1 more source
Thermodynamics of metal ion cryptates and cryptand 222 in dipolar aprotic solvents. [PDF]
Thermodynamic parameters of transfer of single-ions from water to nitromethane are obtained using the Ph4AsPh4B convention suggested by Parker. Enthalpies of complexing of alkali-metal and silver cations with cryptand 222 in N,N-dimethylformamide ...
Ghousseini, Lily.
core
ABSTRACT Algal proteins from cyanobacteria serve as a natural source of biopolymers. The principal challenge manifests as nonoptimization of unit operations in downstream process accounting for higher costs. This study focuses on process assessment of unit‐operations for selecting suitable recovery strategies not only based on yield, but also considers
Neha Goel +2 more
wiley +1 more source

