A cautionary tale of basic azo photoswitching in dichloromethane finally explained
Many studies of azobenzene photoswitches are carried out in polar aprotic solvents as a first principles characterization of thermal isomerization. Among the most convenient polar aprotic solvents are chlorinated hydrocarbons, such as DCM.
Coral Hillel +4 more
doaj +1 more source
Nitrobenzene Hydrogenation to N-phenylhydroxylamine: a New Approach to the Selectivity
A new approach to resolve the problem of selectivity with respect to N-phenylhydroxylamine in nitrobenzene hydrogenation is proposed. N-phenylhydroxylamine only is the final product of nitrobenzene electroreduction in aprotic media.
S.D. Kushch
doaj +1 more source
Condensation of Benzyl Carbamate with Glyoxal in Polar Protic and Aprotic Solvents. [PDF]
Paromov AE.
europepmc +1 more source
Determination of Enantiomeric Excess in Confined Aprotic Solvent
The validation of the stereochemical purity of synthesized compounds is a requisite for the fine-chemical industry, particularly in the production of enantiopure drug compounds. However, most methodologies employed in the determination of enantiopurity require carefully chosen chiral GC or HPLC columns, increasing associated cost, analysis time, and ...
Emer B. Farrell +5 more
openaire +2 more sources
Effect of Aprotic Solvents on the Microtensile Bond Strength of Composite Core and Fiber-Reinforced Composite Posts. [PDF]
Prawatvatchara W +4 more
europepmc +1 more source
Synthesis and fluorosolvatochromism of 3-arylnaphtho[1,2-b]quinolizinium derivatives
Cationic biaryl derivatives were synthesized by Suzuki–Miyaura coupling of 3-bromonaphtho[1,2-b]quinolizinium bromide with arylboronic acids. The resulting cationic biaryl derivatives exhibit pronounced fluorosolvatochromic properties.
Phil M. Pithan +4 more
doaj +1 more source
Universal Trends between Acid Dissociation Constants in Protic and Aprotic Solvents. [PDF]
Busch M, Ahlberg E, Laasonen K.
europepmc +1 more source
Ultrafast fluorescence dynamics of NADH in aprotic solvents: Quasi-static self-quenching unmasked. [PDF]
Li H +5 more
europepmc +1 more source
Scavenging of Superoxide in Aprotic Solvents of Four Isoflavones That Mimic Superoxide Dismutase. [PDF]
Yu S, Caruso F, Belli S, Rossi M.
europepmc +1 more source
Solvation and Ion-Pairing Effects of Choline Acetate Electrolyte in Protic and Aprotic Solvents Studied by NMR Titrations. [PDF]
Veroutis E +3 more
europepmc +1 more source

