Results 61 to 70 of about 9,719 (268)

Self‐Healing Starch‐Based Ionogels with Hydroneutral Dipole–Dipole Interactions

Advanced Science, EarlyView.
This work introduces starch‐based, conductive, underwater‐healable, and transparent ionogels for soft electronics (SCUTEs). Starch macromolecules are partially substituted with cyanoethyl groups and incorporated with hydrophobic ionic liquid. The polar yet hydroneutral cyanoethyl groups facilitate strong dynamic dipole–dipole interactions that remain ...
J. Justin Koh, Jiayi Liu, Xue Qi Koh, Binting Huang, Szu Cheng Lai, Jayce Jian Wei Cheng, Gwendolyn J. H. Lim, Warintorn Thitsartarn, Yong‐Wei Zhang, Zhigen Yu, Chaobin He   +10 more
wiley   +1 more source

Electro‐Chemo‐Mechanical Coupling in Composite Cathodes of Sulfide‐Based All‐Solid‐State Batteries: Pathways, Degradation, and Design Rules

Advanced Science, EarlyView.
This review provides an integrated framework for achieving superior electrochemical performance in sulfide‐based all‐solid‐state batteries. It first delineates mechano‐electrochemical failure modes of cathode active materials and solid electrolytes, then outlines engineering principles for particle morphology, electronic and ionic conduction, and ...
Gawon Song, Seonghyun Lee, Minseon Lee, Junsung Park, Kyu Tae Lee   +4 more
wiley   +1 more source

Aqueous Lithium Hydroxide Chemistry Based on Hierarchically Assembled Hydrogenated Borophene/Cobalt‐Nickel Compounds for Rechargeable High‐Performance Supercapattery

Advanced Energy Materials, EarlyView.
Aqueous lithium‐ion storage has been demonstrated using a hierarchically assembled hydrogenated borophene/cobalt‐nickel compound as a supercapattery electrode. Reducible hydrogenated borophene generates undercoordinated oxygen, which is redox‐active for lithiation and hydrogenation during the discharging process following the lithium hydroxide ...
Seunghwan Jo, Ozden Gunes Yildiz, Hyun‐Sik Kim, Liting Zhang, Ki Hoon Shin, Seong Hyeok Kwon, Keon Beom Lee, Paul Simon, Umut Aydemir, Ghim Wei Ho, Jung Inn Sohn   +10 more
wiley   +1 more source

Scope and limitations of a DMF bio-alternative within Sonogashira cross-coupling and Cacchi-type annulation

Beilstein Journal of Organic Chemistry, 2016
Pd-catalysed C–C bond formation is an essential tool within the pharmaceutical and agrochemical industries. Many of these reactions rely heavily on polar aprotic solvents; however, despite their utility, these solvents are incompatible with the drive ...
Kirsty L. Wilson, Alan R. Kennedy, Jane Murray, Ben Greatrex, Craig Jamieson, Allan J. B. Watson   +5 more
doaj   +1 more source

Hybridization of Homogeneous and Heterogeneous Catalysis to Develop a Novel Biocatalyst via Immobilization of Lipase on Surface Modified Mesoporous Silica Towards Biodiesel Synthesis Application

Advanced Energy and Sustainability Research, EarlyView.
The 3‐(methacryloyloxy)propyltrimethoxysilane surface functionalized SBA‐15 (MP‐SBA‐15) is used for the first time as a lipase carrier. The immobilized CAL‐B exhibits high thermal stability and superior catalytic activity. CAL‐B/SBA‐15 suggests that optimum hydrophobicity gives better catalytic activity.
Murugappan N., Ayumi Sato, Jiachen Ge, Arisa Yamada, Makoto Onaka, Yuki Nakamura, Masaru Ogura   +6 more
wiley   +1 more source

Electrochemical Behavior of N2SO Schiff-Base Co(II) Complexes in Non-Aqueous Media at the Surface of Solid Electrodes

International Journal of Electrochemical Science, 2009
The electrochemical behavior of three newly synthesized Schiff-base Co(II)-complex with N2SO donor group was investigated. In different non-aqueous media such as acetonitrile (AN) and %50w/w dichlromethane-dimetylsulfoxide (CH2Cl2-DMSO) mixture as ...
Sohrab Ershad, Lotf-Ali Sagathforoush, Ghasem Karim-nezhad, Sahar Kangari   +3 more
doaj   +1 more source

Interpretable Machine Learning for Solvent‐Dependent Carrier Mobility in Solution‐Processed Organic Thin Films

Advanced Intelligent Discovery, EarlyView.
This work establishes a correlation between solvent properties and the charge transport performance of solution‐processed organic thin films through interpretable machine learning. Strong dispersion interactions (δD), moderate hydrogen bonding (δH), closely matching and compatible with the solute (quadruple thiophene), and a small molar volume (MolVol)
Tianhao Tan, Lian Duan, Dong Wang
wiley   +1 more source

A cautionary tale of basic azo photoswitching in dichloromethane finally explained

Communications Chemistry
Many studies of azobenzene photoswitches are carried out in polar aprotic solvents as a first principles characterization of thermal isomerization. Among the most convenient polar aprotic solvents are chlorinated hydrocarbons, such as DCM.
Coral Hillel, Sara Rough, Christopher J. Barrett, William J. Pietro, Ozzy Mermut   +4 more
doaj   +1 more source

Nitrobenzene Hydrogenation to N-phenylhydroxylamine: a New Approach to the Selectivity

Eurasian Chemico-Technological Journal, 2002
A new approach to resolve the problem of selectivity with respect to N-phenylhydroxylamine in nitrobenzene hydrogenation is proposed. N-phenylhydroxylamine only is the final product of nitrobenzene electroreduction in aprotic media.
S.D. Kushch
doaj   +1 more source

Combination of a UPO-Based Epoxidation With a Subsequent Ring-Opening Reaction for the Synthesis of Amino Alcohols. [PDF]

Chembiochem
The synthesis of aromatic amino alcohols via a combination of an unspecific peroxygenase‐catalysed reaction, oxyfunctionalization, and addition of selected nucleophiles and electrophiles in a highly atom‐efficient manner was investigated. This study presents the design to aim for an atom‐efficient chemo‐enzymatic synthesis route towards aromatic amino ...
Last S, Dietz N, Weissenborn MJ, von Langermann J.   +3 more
europepmc   +2 more sources