Results 81 to 90 of about 9,719 (268)

Research Progress on Halide Solid‐State Electrolytes: Synthesis, Mechanism, and Modification

Carbon Energy, EarlyView.
This review comprehensively summarizes the research progress on halide solid‐state electrolytes, including their classifications, synthesis methods, ion conduction mechanisms, and modification strategies. It also proposes effective modification strategies to address critical issues, such as air stability and interface compatibility.
Weifeng Shen, Ping Liu, Long Wang, Haijun Yang, Jiawen Chen, Fengxiang Chen, Shenghui Shen, Guoxiang Pan, Zhong Qiu, Xinqi Liang, Yongqi Zhang, Jiayuan Xiang, Ming Song, Wei Wen, Ruyi Fang, Hui Huang, Jun Zhang, Qi Liu, Yang Xia, Wenkui Zhang, Xinhui Xia   +20 more
wiley   +1 more source

Scavenging of Superoxide in Aprotic Solvents of Four Isoflavones That Mimic Superoxide Dismutase. [PDF]

Int J Mol Sci, 2023
Yu S, Caruso F, Belli S, Rossi M.
europepmc   +1 more source

Shedding Light on Synthetic Autocatalysis: From Conventional Closed‐Shell Chemistries to Overlooked Open‐Shell Occurrences

Chemistry – A European Journal, EarlyView.
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley   +1 more source

Solvation and Ion-Pairing Effects of Choline Acetate Electrolyte in Protic and Aprotic Solvents Studied by NMR Titrations. [PDF]

Chemphyschem, 2022
Veroutis E, Merz S, Eichel RA, Granwehr J.   +3 more
europepmc   +1 more source

A Michaelis‐Arbuzov‐Type Pathway to a Protected 2ʹ‐Deoxy‐2ʹ‐Selenomethyl‐Adenosine‐3ʹ,5ʹ‐Phosphoroselenolate Guanosine Dinucleotide for Use in Modified m7G Cap Synthesis

Chemistry – A European Journal, EarlyView.
Here we report a synthesis of the dinucleotide 4 for a projected future total synthesis of the m7G cap 1. Highlights of the route include: 1) a 3ʹ‐H‐phosphonate/5ʹ‐selenocyanate Michaelis‐Arbuzov coupling to forge the 3ʹ,5ʹ‐phosphoroselenolate; 2) an Amosova reductive selenomethylation to install the 2ʹ‐SeMe; 3) a solid CPR II 5ʹ‐O‐phosphitylation; and
K. Lawrence E. Hale, Helen O. McCarthy, Mark G. McLaughlin   +2 more
wiley   +1 more source

Effect of Selected Organic Solvents on Hydroxyl Radical-Dependent Light Emission in the Fe²⁺-EGTA-H₂O₂ System

Molecules
Numerous compounds that are scavengers of hydroxyl radicals (•OH) in Fenton systems have low solubility in water. Therefore, they are dissolved in organic solvents to reach suitable concentrations in the reaction milieu of the Fenton system.
Krzysztof Sasak, Michał Nowak, Anna Wlodarczyk, Agata Sarniak, Dariusz Nowak   +4 more
doaj   +1 more source

Synthesis of ursodeoxycholic acid by electrochemical stereoselective reduction of 7-ketolithocholic acid in aprotic solvents. [PDF]

Sci Rep, 2021
Shen J, Dong D, Wang Z, Wan J, Cao X.
europepmc   +1 more source

Versatile Palladium‐Catalyzed C‐H Arylation of Fluoroarenes with 2‐Chloropyridine Derivatives

Chemistry – A European Journal, EarlyView.
Direct C─H arylation of fluoroarenes with 2‐chloropyridines is enabled by a simple Pd/SPhos system in isopropyl acetate. The method uses inexpensive reactants and shows broad scope and high yields. DFT computations explain reactivity and selectivity.
Federico Belnome, Péter P. Fehér, András Stirling, Csongor G. Németh, Tamás Hergert, György M. Keserű, Péter Ábrányi‐Balogh   +6 more
wiley   +1 more source

Polymer Chemistry Applications of Cyrene and its Derivative Cygnet 0.0 as Safer Replacements for Polar Aprotic Solvents. [PDF]

ChemSusChem, 2021
Milescu RA, Zhenova A, Vastano M, Gammons R, Lin S, Lau CH, Clark JH, McElroy CR, Pellis A.   +8 more
europepmc   +1 more source

Transitioning Formamide Solvothermal Syntheses of MOFs to Less Toxic Solvents

Chemistry – A European Journal, EarlyView.
Metal‐organic Frameworks (MOFs) are commonly synthesized in toxic formamide solvents. This study investigates the synthetic factors required for effective removal of formamides across various classes of MOFs, providing a foundation for designing new sustainable MOF syntheses.
Julia C. Donovan, Evelyn C. Peterson, Adam J. Matzger   +2 more
wiley   +1 more source