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MOFs as New Catalytic Platform for Covalent Adaptable Networks: Catalysis Meets Reinforcement

open access: yesAngewandte Chemie International Edition, EarlyView.
A novel heterogeneous catalytic platform for covalent adaptable networks (CANs) is introduced by immobilizing bases of low molecular weight on metal‐organic frameworks (MOFs). The obtained catalyst UiO‐TBD benefits from the high loading capacity of the MOF and demonstrates a higher thermal stability relative to free TBD.
Simon Renner   +9 more
wiley   +1 more source

Driving Hydrolysis and Acetolysis of Poly(ethylene terephthalate) (PET) by Microwave and Thermal Energy Inputs: A Comparative Study. [PDF]

open access: yesACS Omega
Pereira P   +7 more
europepmc   +1 more source

RuKY Catalyst-Packed Permeation Membrane for Quantitative Ammonia and d3-Ammonia Dehydrogenation to Ultrapure Hydrogen. [PDF]

open access: yesChemistryOpen
Koch CJ   +7 more
europepmc   +1 more source

Radiative Defects in Chloride-Activated CdSe Thin Films. [PDF]

open access: yesACS Energy Lett
Abudulimu A   +14 more
europepmc   +1 more source

Exploring the Theoretical Foundation with Rupture and Delayed Rupture Experiments. [PDF]

open access: yesMacromolecules
Siavoshani AY   +6 more
europepmc   +1 more source
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The Arrhenius Equation Revisited

Critical Reviews in Food Science and Nutrition, 2012
The Arrhenius equation has been widely used as a model of the temperature effect on the rate of chemical reactions and biological processes in foods. Since the model requires that the rate increase monotonically with temperature, its applicability to enzymatic reactions and microbial growth, which have optimal temperature, is obviously limited. This is
Micha Peleg, Maria G Corradini
exaly   +3 more sources

Extending the compensated Arrhenius formalism to concentrated alcohol electrolytes: Arrhenius vs. non-Arrhenius behavior

Electrochimica Acta, 2011
The compensated Arrhenius formalism is applied to ionic conductivities in alcohol-based electrolytes at concentrations where the salt makes a non-negligible contribution to the static dielectric constant of the solution. The temperature-dependent behavior of the conductivity depends on the amount of added salt.
Allison M. Fleshman   +5 more
openaire   +1 more source

The Arrhenius equation

2022
This chapter discusses how rate constants of most reactions increase with increasing temperature. It introduces the ‘Arrhenius equation’, which captures this temperature dependence by using two parameters that can be determined experimentally. It also reviews the exploration of the dependence of reaction rates on temperature that leads to the ...
Peter Atkins   +2 more
openaire   +1 more source

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