Results 221 to 230 of about 538,570 (408)
Radical‐Polar Crossover Bicyclization Enables a Modular Synthesis of Saturated Bicyclic Amines
Herein, we report the successful realization of a radical‐polar crossover bicyclization reaction from easily available cyclopropylamines and substituted alkenes through photoredox catalysis. This approach introduces an innovative methodology for the de novo synthesis of a diverse collection of 4/5‐, 5/5‐, 6/5‐,7/5‐ and 5/6‐fused saturated bicyclic ...
Dewei Feng+4 more
wiley +1 more source
The electrochemical reactivity of graphene‐on‐Cu(111) with various phenyl and alkyl iodides showed different onset potentials. Differential pulse voltammetry (DPV) and density functional theory (DFT) calculations are used to elucidate the differences in onset potentials for phenyl iodides with different substituents.
Minhyeok Kim+4 more
wiley +1 more source
The Behaviour of Lignin in Alkaline Pulping. II. Model Experiments with Arylalkyl-beta-aryl Ethers. [PDF]
Erich Adler+4 more
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An endogenous tumour-promoting ligand of the human aryl hydrocarbon receptor
C. Opitz+18 more
semanticscholar +1 more source
The study develops a H•/H– transfer strategy enabling efficient hydrocyclization/defluorination of CF3‐acrylamides to synthesize Seletracetam derivatives with gem‐difluoroalkenes. Mechanistic studies reveal distinct pathways: the NiII‐H/PhSiH3 system operates through a hydrogen atom transfer process, while the 1,4‐Michael addition of H– appears to be ...
Yanjun Wan, Ronghui Shao, Jack R. Norton
wiley +1 more source
Studies on Bis (Alkyl-, Bis (Aryl-, and Bis (Aralkyl-mercuric) Sulfides I
Tenmin Kaku, Yoshihide Hagiwara
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An improved synthesis of β-hydroxysulfones via α-sulfonylcarbanions in liquid ammonia. The direct metalation of dialkyl and aryl alkyl sulfones [PDF]
Donald F. Tavares, Peter Vogt
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Schematic model of CJP–TiN liposomes for gastric cancer (GC) treatment. Internalizing RGD peptide (iRGD) targets tumor cells, while Chlorin e6 (Ce6) generates reactive oxygen species (ROS). Jolkinolide B (JB) activates the PANoptosis pathway via caspase‐8, enhancing GC cell death and immune response, transforming “cold tumors” into “hot tumors” by ...
Chenhui Ma+14 more
wiley +1 more source
Fungal Cellulases XI. The Nature of the Inductive Process for Aryl ?-Glucosidase in Stachybotrys Atra [PDF]
MAJ Ermyn
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