Results 221 to 230 of about 538,570 (408)

Radical‐Polar Crossover Bicyclization Enables a Modular Synthesis of Saturated Bicyclic Amines

open access: yesAdvanced Science, EarlyView.
Herein, we report the successful realization of a radical‐polar crossover bicyclization reaction from easily available cyclopropylamines and substituted alkenes through photoredox catalysis. This approach introduces an innovative methodology for the de novo synthesis of a diverse collection of 4/5‐, 5/5‐, 6/5‐,7/5‐ and 5/6‐fused saturated bicyclic ...
Dewei Feng   +4 more
wiley   +1 more source

Electrochemical Functionalization of Graphene‐on‐Cu(111): Reactivity, Onset Potentials, and Mechanistic Insights

open access: yesAdvanced Science, EarlyView.
The electrochemical reactivity of graphene‐on‐Cu(111) with various phenyl and alkyl iodides showed different onset potentials. Differential pulse voltammetry (DPV) and density functional theory (DFT) calculations are used to elucidate the differences in onset potentials for phenyl iodides with different substituents.
Minhyeok Kim   +4 more
wiley   +1 more source

N-Aryl-glycamine Derivatives. IV

open access: bronze, 1949
Taizo Matsukawa, Kenzo Shirakawa
openalex   +2 more sources

The Behaviour of Lignin in Alkaline Pulping. II. Model Experiments with Arylalkyl-beta-aryl Ethers. [PDF]

open access: bronze, 1964
Erich Adler   +4 more
openalex   +1 more source

An endogenous tumour-promoting ligand of the human aryl hydrocarbon receptor

open access: yesNature, 2011
C. Opitz   +18 more
semanticscholar   +1 more source

Hydrocyclization/Defluorination of CF3‐Substituted Acrylamides: Insights from Kinetics of Hydrogen Atom Transfer

open access: yesAdvanced Science, EarlyView.
The study develops a H•/H– transfer strategy enabling efficient hydrocyclization/defluorination of CF3‐acrylamides to synthesize Seletracetam derivatives with gem‐difluoroalkenes. Mechanistic studies reveal distinct pathways: the NiII‐H/PhSiH3 system operates through a hydrogen atom transfer process, while the 1,4‐Michael addition of H– appears to be ...
Yanjun Wan, Ronghui Shao, Jack R. Norton
wiley   +1 more source

Targeted Dual‐Responsive Liposomes Co‐Deliver Jolkinolide B and Ce6 to Synergistically Enhance the Photodynamic/Immunotherapy Efficacy in Gastric Cancer through the PANoptosis Pathway

open access: yesAdvanced Science, EarlyView.
Schematic model of CJP–TiN liposomes for gastric cancer (GC) treatment. Internalizing RGD peptide (iRGD) targets tumor cells, while Chlorin e6 (Ce6) generates reactive oxygen species (ROS). Jolkinolide B (JB) activates the PANoptosis pathway via caspase‐8, enhancing GC cell death and immune response, transforming “cold tumors” into “hot tumors” by ...
Chenhui Ma   +14 more
wiley   +1 more source

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