Results 331 to 340 of about 538,570 (408)
THE CHROMIC ACID OXIDATION OF ARYL TRIFLUOROMETHYL ALCOHOLS: ISOTOPE AND SUBSTITUENT EFFECTS
Ross Stewart, Donald G. Lee
openalex +1 more source
The structure and biosynthetic origin of the enigmatic “yellow affinity substance” (YAS) from the anaerobe thermophile Clostridium thermocellum (now: Acetivibrio thermocellus) were elucidated. YAS is a complex of unusual antibacterial arylpolyene alkaloids (celluxanthenes) that are produced by various cellulolytic anaerobes.
Keishi Ishida+9 more
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Using Triazabutadienes as a Protected Source of Diazonium Cations to Facilitate Electrografting to a Variety of Conductive Surfaces. [PDF]
Yates NDJ+3 more
europepmc +1 more source
A Bayesian meta‐learning framework is proposed for reaction outcome prediction in low‐data settings. It utilizes a literature‐mined dataset on asymmetric hydrogenation of olefins to build a pre‐trained model. This meta‐model is shown to return better predictions as compared to single‐tasks methods, such as random forest and graph neural networks, given
Sukriti Singh+1 more
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Organocatalytic Asymmetric Synthesis of Azabicyclo[2.1.1]hexanes. [PDF]
Alama L+4 more
europepmc +1 more source
Nitrate Reduction for Deaminative Suzuki–Miyaura Coupling of Anilines
We present a one‐step deaminative Suzuki–Miyaura‐type coupling of anilines via fleeting diazonium intermediate with nitrate and bisulfite as the reagents. This represents the first application of the nitrate reduction strategy in transition metal catalysis of diazonium chemistry.
Chen‐Chen Li+6 more
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N,N- and N,O-Bidentate-Chelation-Assisted Alkenyl C-H Functionalization. [PDF]
Zhang Y+6 more
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Titan‐vermittelte Umlagerung von Bis(alkinyl)boranen: B–C‐Aktivierung vs. C–H‐Aktivierung
Bis(alkinyl)borane mit verschiedenen B‐Substituenten reagierten mit Cp*2Ti(Me3SiCCSiMe3), was zur Bildung von B–C‐Aktivierungsprodukten (oben rechts) bzw. C–H‐Aktivierungsprodukten (unten rechts) führte. Kurzzusammenfassung Es wurden Reaktionen zwischen Rosenthal‐Titanocen‐ (Cp2Ti) und Decamethyltitanocen‐ (Cp*2Ti) Synthonen mit verschiedenen Bis ...
Chenchang Ma+5 more
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Direct vicinal sulfonyloximation of alkenes: an efficient and straightforward approach towards the synthesis of α-sulfonyl ketoximes. [PDF]
Hossaini Z+8 more
europepmc +1 more source
Ein zweidimensionales Poly(Arylenvinylene) vom Donor‐Akzeptor‐Typ wurde entwickelt, das eine schmale optische Bandlücke und einen einzigartigen, elektronen‐dominierten Ladungstransport mit hoher Ladungsträgermobilität für ultrasensitive Chemiresistoren aufweist.
Ruyan Zhao+16 more
wiley +1 more source