Results 141 to 150 of about 22,861 (258)

Bismuth-mediated arylation [PDF]

open access: yes
Initial efforts were focused on the development of a catalytic protocol for the arylation of hydroxyarenes using Ar3BiX2 reagents. The individual steps oxidation, arylation and transmetallation were investigated separately to be combined in the final ...
Jurrat, Mark
core   +2 more sources

From Sourcing to End‐of‐Life: Sustainability Challenges and Opportunities in Organic Bioelectronics

open access: yesAdvanced Science, Volume 13, Issue 51, 14 September 2026.
Organic bioelectronics bridges biology and electronics using organic mixed ionic/electronic conductors. This Perspective addresses sustainability across the full lifecycle of organic bioelectronic materials and devices, offering a framework to guide material sourcing, synthesis, fabrication, application, and end‐of‐life strategies toward bioelectronic ...
Gwennaël Dufil   +3 more
wiley   +1 more source

Molecular Engineering of Polytriphenylamine: A Fluorinated Cathode for High‐Voltage, Ultrafast, and Stable Sodium‐Ion Batteries

open access: yesAdvanced Energy Materials, Volume 16, Issue 34, 9 September 2026.
Fluorination of polytriphenylamine lowers the HOMO energy, enabling high‐voltage operation of the PFTPA cathode. Electron‐withdrawing F substituents stabilize the nitrogen redox center and suppress polarization, leading to fast kinetics. The optimized polymer delivers ∼3.75 V vs.
Natalia Voronina   +6 more
wiley   +1 more source

Nickel catalysis enables chemoselectivity in radiation chemistry. [PDF]

open access: yesNat Commun
Liang W   +8 more
europepmc   +1 more source

Machine Learning for Synthetic Organic Chemistry: Methods, Applications, and Best Practices

open access: yesAngewandte Chemie Novit, Volume 2, Issue 3, September 2026.
Artificial intelligence (AI) and machine learning (ML) are increasingly reshaping experimental chemistry. This review maps the challenges of synthetic organic chemistry to modern digital tools that can help address them. While focusing on the practical application of ML tools in real‐world laboratory settings, we outline prerequisites, emerging ...
Niklas Hölter   +3 more
wiley   +1 more source

Temperature‐Controlled Diene Cyclization Toward Trifluoromethyl Biphenyl Derivatives: Synthetic and Computational Study

open access: yesChemCatChem, Volume 18, Issue 18, 28 September 2026.
Synthesis of functionalized polyfluorinated biphenyl moieties via one‐pot Heck coupling followed by temperature‐controlled cyclization reaction of polyfluoro diene intermediate. The cyclization reaction proceeds via a palladium‐catalyzed β‐fluoro elimination step.
Bálint Varga   +7 more
wiley   +1 more source

Copper-catalysed site-selective arylation of pyrazoles. [PDF]

open access: yesNat Chem
Wang M   +5 more
europepmc   +1 more source

Excited‐State Antiaromaticity Relief‐Guided Discovery of 7‐Hydroxycoumarins as Photoacid Catalysts

open access: yesChemCatChem, Volume 18, Issue 17, 14 September 2026.
DFT and NICS studies are presented, in order to elucidate the relation of photoacidity with antiaromaticity relief of the excited state of 4‐substituted umbelliferone derivatives, leading to the experimentally optimum selection of photoacid catalysts for the acetalization reaction.
E. Alexandros Routsi   +5 more
wiley   +1 more source

Redox-active photocatalytic N^C cyclometalated gold(III) catecholate complexes. [PDF]

open access: yesBeilstein J Org Chem
Gonzálvez MA   +5 more
europepmc   +1 more source

Hydrazone‐Type Ligands for Asymmetric Catalysis

open access: yesChemistryEurope, Volume 4, Issue 9, September 2026.
The introduction of trans 2,5‐disubstituted pyrrolidines is the key design element enabling the excellent stereocontrol exerted by hydrazone‐based N‐ligands in a variety of transition metal‐catalyzed transformations, including Diels–Alder cycloadditions, Suzuki/Hiyama/Negishi cross‐couplings, 1,2‐additions to a variety of imines and hydrazones, and ...
Esteban Matador   +4 more
wiley   +1 more source

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