Results 141 to 150 of about 22,861 (258)
Bismuth-mediated arylation [PDF]
Initial efforts were focused on the development of a catalytic protocol for the arylation of hydroxyarenes using Ar3BiX2 reagents. The individual steps oxidation, arylation and transmetallation were investigated separately to be combined in the final ...
Jurrat, Mark
core +2 more sources
From Sourcing to End‐of‐Life: Sustainability Challenges and Opportunities in Organic Bioelectronics
Organic bioelectronics bridges biology and electronics using organic mixed ionic/electronic conductors. This Perspective addresses sustainability across the full lifecycle of organic bioelectronic materials and devices, offering a framework to guide material sourcing, synthesis, fabrication, application, and end‐of‐life strategies toward bioelectronic ...
Gwennaël Dufil +3 more
wiley +1 more source
Fluorination of polytriphenylamine lowers the HOMO energy, enabling high‐voltage operation of the PFTPA cathode. Electron‐withdrawing F substituents stabilize the nitrogen redox center and suppress polarization, leading to fast kinetics. The optimized polymer delivers ∼3.75 V vs.
Natalia Voronina +6 more
wiley +1 more source
Nickel catalysis enables chemoselectivity in radiation chemistry. [PDF]
Liang W +8 more
europepmc +1 more source
Machine Learning for Synthetic Organic Chemistry: Methods, Applications, and Best Practices
Artificial intelligence (AI) and machine learning (ML) are increasingly reshaping experimental chemistry. This review maps the challenges of synthetic organic chemistry to modern digital tools that can help address them. While focusing on the practical application of ML tools in real‐world laboratory settings, we outline prerequisites, emerging ...
Niklas Hölter +3 more
wiley +1 more source
Synthesis of functionalized polyfluorinated biphenyl moieties via one‐pot Heck coupling followed by temperature‐controlled cyclization reaction of polyfluoro diene intermediate. The cyclization reaction proceeds via a palladium‐catalyzed β‐fluoro elimination step.
Bálint Varga +7 more
wiley +1 more source
Copper-catalysed site-selective arylation of pyrazoles. [PDF]
Wang M +5 more
europepmc +1 more source
Excited‐State Antiaromaticity Relief‐Guided Discovery of 7‐Hydroxycoumarins as Photoacid Catalysts
DFT and NICS studies are presented, in order to elucidate the relation of photoacidity with antiaromaticity relief of the excited state of 4‐substituted umbelliferone derivatives, leading to the experimentally optimum selection of photoacid catalysts for the acetalization reaction.
E. Alexandros Routsi +5 more
wiley +1 more source
Redox-active photocatalytic N^C cyclometalated gold(III) catecholate complexes. [PDF]
Gonzálvez MA +5 more
europepmc +1 more source
Hydrazone‐Type Ligands for Asymmetric Catalysis
The introduction of trans 2,5‐disubstituted pyrrolidines is the key design element enabling the excellent stereocontrol exerted by hydrazone‐based N‐ligands in a variety of transition metal‐catalyzed transformations, including Diels–Alder cycloadditions, Suzuki/Hiyama/Negishi cross‐couplings, 1,2‐additions to a variety of imines and hydrazones, and ...
Esteban Matador +4 more
wiley +1 more source

