Results 41 to 50 of about 9,110 (204)
First astronomical detection of the CF+ ion
We report the first astronomical detection of the CF+ (fluoromethylidynium) ion obtained by recent observations of its J = 1 - 0 (102.6 GHz), J = 2 - 1 (205.2 GHz), and J = 3 - 2 (307.7 GHz) pure rotational emissions toward the Orion Bar.
D. A. Neufeld +11 more
core +2 more sources
Valence Threshold Photoionization Spectra of C5$_5$H and C5$_5$H2$_2$ Isomers
Mass‐selected threshold photoelectron spectra (TPES) of l‐C5H, HC5H, and c–C3H‐CCH were recorded using double‐imaging photoelectron‐photoion coincidence spectroscopy. These transient species were generated in situ by hydrogen abstraction from cyclopropylacetylene and 1,3‐pentadiyne.
Ugo Jacovella +9 more
wiley +1 more source
Astrochemistry: Synthesis and Modelling [PDF]
We discuss models that astrochemists have developed to study the chemical composition of the interstellar medium. These models aim at computing the evolution of the chemical composition of a mixture of gas and dust under as- trophysical conditions. These conditions, as well as the geometry and the physical dynamics, have to be adapted to the objects ...
Wakelam, Valentine +2 more
openaire +4 more sources
Ion–Molecule Reaction Products as Probes and Precursors for Preparative Mass Spectrometry
Ion–molecule reactions in the gas phase of mass spectrometers are important for preparative mass spectrometry because they (1) provide knowledge about the intrinsic reactivity of ions, helping to predict and control their reactivity at interfaces, and (2) generate new complex ions that can be mass selected and deposited on surfaces.
Markus Rohdenburg +4 more
wiley +1 more source
ASTROCHEMISTRY OF STAR FORMATION
Star formation is one of the key processes governing the evolution of the Universe. It is accompanied by significant transformations in the chemical composition and the physical state of the interstellar medium. Combining observations in infrared and
D. S. Wiebe, O. V. Kochina
doaj +1 more source
On the Formation of Vinylamine (C2H3NH2) in Interstellar Ice Analogs
Amines—organic molecules carrying the –NH _2 moiety—have been recognized as a vital intermediate in the formation of prebiotic molecules such as amino acids and nucleobases.
Chaojiang Zhang +6 more
doaj +1 more source
Astrochemistry of dust, ice and gas: introduction and overview
A brief introduction and overview of the astrochemistry of dust, ice and gas and their interplay is presented, aimed at non-specialists. The importance of basic chemical physics studies of critical reactions is illustrated through a number of recent ...
van Dishoeck, Ewine F.
core +1 more source
Confined Chemistry in Space: Zeolite‐Supported Fe13 Nanoclusters Modulate CS Reactivity
The study explores how an Fe13 cluster confined in chabazite reshapes the reaction of CS and H2 under astrochemical conditions. Confinement promotes C–S bond cleavage over hydrogenation, directing chemistry toward CH4 and H2S formation. Additional CS enables CS2 and C2 species. Microkinetic analysis identifies protoplanetary environments where zeolites
Gerard Pareras, Albert Rimola
wiley +1 more source
Ice Ic without stacking disorder by evacuating hydrogen from hydrogen hydrate
Metastable cubic ice has been identified in several conditions relevant to geo and astrochemistry, but was always characterized by stacking disorder. Here the authors synthesize a hydrogen hydrate and degas hydrogen, obtaining pure non-defected cubic ice,
Kazuki Komatsu +7 more
doaj +1 more source
A hybrid moment equation approach to gas-grain chemical modeling [PDF]
[Context] The stochasticity of grain chemistry requires special care in modeling. Previously methods based on the modified rate equation, the master equation, the moment equation, and Monte Carlo simulations have been used. [Aims] We attempt to develop a
Awad +38 more
core +2 more sources

