Results 161 to 170 of about 848,132 (406)

Discovery and enantiocontrol of axially chiral urazoles via organocatalytic tyrosine click reaction

open access: yesNature Communications, 2016
Axially chiral compounds play an important role in areas such as asymmetric catalysis. Here, the authors report an organocatalytic asymmetric tyrosine click-like reaction, giving access to enantio enriched urazoles with restricted rotation around an N-C ...
Ji-Wei Zhang   +5 more
doaj   +1 more source

Carbon Monoxide Adsorption and Carbon Monoxide Oxidation Studies on Thiolate Supported Gold Nanoclusters Dispensed on Metallic Oxides [PDF]

open access: yesarXiv, 2018
Thiolate-protected gold nanoclusters represent atomically well-defined active centers for catalysis with resolved crystal structures, enabling the creation of a homogeneous and defined surface. The correlation of characterization via FT-IR spectroscopy with kinetics studies gives insight into the gold clusters activity and tests their utilization to ...
arxiv  

Defect‐Induced Selectivity Modulation Using Copper Triazole Molecular Frameworks for Electrochemical CO2 Reduction

open access: yesAdvanced Functional Materials, EarlyView.
A Cu‐triazole and D‐Cu‐triazole MOF is studied for eCO2RR. After introducing open metal sites and reducing the particle size through a competitive coordination strategy with N,N‐diethylformamide, the defects significantly enhance and alter the catalytic properties with increased selectivity for C2+ products. Abstract Metal–organic frameworks (MOFs) are
Anirudha Shekhawat   +7 more
wiley   +1 more source

Accelerated Kinetics of Desolvation and Redox Transformation Enabled by MOF Sieving for High‐Loading Mg‐S Battery

open access: yesAdvanced Functional Materials, EarlyView.
A strategy of sieving catalysis based on the MIL‐101(Cr) with multistage pore structure and Lewis acid sites has been proposed as the catalyst to accelerate the kinetics of desolvation and redox conversion of sulfur species, achieving high performance Mg‐S batteries.
Qinghua Guan   +8 more
wiley   +1 more source

Interplay of synthesis and mechanism in asymmetric homogeneous catalysis [PDF]

open access: bronze, 2001
Nicholas J. Adams   +8 more
openalex   +1 more source

Highly Sensitive Electrochemical Biosensor Based on Hairy Particles with Controllable High Enzyme Loading and Activity

open access: yesAdvanced Functional Materials, EarlyView.
For the first time, a highly sensitive electrochemical biosensor based on SiO2‐based hairy particles with a grafted PDMAEMA polymer brush containing a quantifiable and large amount of immobilized Laccase is reported. The fabricated biosensor exhibits a sensitivity of 0.14 A·m⁻¹, a limit of detection (LOD) of 0.1 µm, and a detection range of 0.3–750 µm,
Pavel Milkin   +7 more
wiley   +1 more source

Edge‐Delocalized Electron Effect on Self‐Expediating Desolvation Kinetics for Low‐Temperature Li─S Batteries

open access: yesAdvanced Functional Materials, EarlyView.
The self‐transformed Schottky heterojunction on MXene is developed to facilitate the dissociation of Li (solvent)x+ to achieve fast Li+ desolvation to promote rapid sulfur conversion kinetics by decreasing the related barriers, contributing to high‐performance Li─S batteries under low‐temperatures.
Yongzheng Zhang   +12 more
wiley   +1 more source

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