Results 181 to 190 of about 665,789 (291)

Recent Advances in Carbon-Based Catalysts for Heterogeneous Asymmetric Catalysis. [PDF]

Molecules
Zheng Y, Liu T, Tai J, Ma N.
europepmc   +1 more source

Hybrid Metal–Organic Framework‐Derived Dual Active Site Catalysts Enabling Surface‐Enriched Cathode and Modified Zinc Anode for Long‐Life Zinc–Air Batteries

Advanced Science, EarlyView.
This work demonstrates the implementation of MOF‐assisted anode and cathode materials for prolonged cycling of zinc‐air batteries with strong redox capability and structural stability. ABSTRACT The surface modification of zinc anodes and the development of effective cathode dual‐functional oxygen electrocatalysts remain of paramount interest for ...
Ramasamy Santhosh Kumar, Duraisami Kaviyarasu, Dilmurod Sayfiddinov, Murugavel Kathiresan, Pandian Mannu, Chung‐Li Dong, Arul Manuel Stephan, Dong Jin Yoo   +7 more
wiley   +1 more source

Application of Asymmetric Catalysis in the <i>E</i>/<i>Z</i>-Stereodivergent Synthesis of Alkenes. [PDF]

J Am Chem Soc
Liu M, Kanale VV, Uyeda C.
europepmc   +1 more source

High‐Current‐Density Acidic CO2 Electroreduction to Formic Acid Enabled by Multiscale Microenvironment Regulation Over Defect‐Rich Sn/SnOx

Advanced Science, EarlyView.
Acidic CO2 electroreduction to formic acid is enabled by integrating mixed Sn/SnOx nanoclusters, K+‐regulated interfacial solvation, and Janus wettability. Coordinated control of active sites, interfacial water, and gas‐liquid transport suppresses hydrogen evolution and delivers approximately 85% HCOOH Faradaic efficiency at 400 mA cm−2.
Qiaoqi Guo, Bowen Jiang, Le Huang, Kunyu Jiang, Rongrong Tang, Qinong Zhu, Huajun Feng, Mengyang Fan, Yijing Xia   +8 more
wiley   +1 more source

Performance-Enhancing Asymmetric Catalysis Driven by Achiral Counterion Design. [PDF]

J Am Chem Soc
Deng Z, Payne JL, Vishe M, Jan JEL, Funk CM, Johnston JN.   +5 more
europepmc   +1 more source

Rigidified Bis(sulfonyl)ethylenes as Effective Michael Acceptors for Asymmetric Catalysis: Application to the Enantioselective Synthesis of Quaternary Hydantoins. [PDF]

J Org Chem, 2023
Villaescusa L, Hernández I, Azcune L, Rudi A, Mercero JM, Landa A, Oiarbide M, Palomo C.   +7 more
europepmc   +1 more source

Mixed‐Valence Atomic‐Layer Iridium Patches Enhance Alkaline Hydrogen Evolution

Advanced Science, EarlyView.
Engineering iridium architectures on Cu3P nanowires reveals that atomic‐layer Ir patches form a mixed‐valence interfacial motif with an anisotropic electronic structure. This configuration balances water dissociation and hydrogen adsorption/desorption, delivering superior alkaline hydrogen evolution with a 27 mV overpotential and 1 A cm−2 operation in ...
Payam Ahmadian Koudakan, Xiaobin Hao, Rui Guo, Omid Mazaheri, Matthias Pichler, Qinjian Luo, Bufeng Zhang, Shuaijun Pan   +7 more
wiley   +1 more source

A meta-learning approach for selectivity prediction in asymmetric catalysis. [PDF]

Nat Commun
Singh S, Hernández-Lobato JM.
europepmc   +1 more source

Silver thiolate nanoclusters as support for chiral ligands: application in heterogeneous phase asymmetric catalysis. [PDF]

Nanoscale Adv, 2023
Primitivo L, De Angelis M, Necci A, Di Pietro F, Ricelli A, Caschera D, Pilloni L, Suber L, Righi G.   +8 more
europepmc   +1 more source

Permanent Oxidative Dipole Engineering in Quinoline COFs for Boosting Exciton Dissociation and Oxygen Activation in H2O2 Photosynthesis

Advanced Science, EarlyView.
Permanent oxidative dipole (POD) engineering overcomes the electronic uniformity of quinoline‐linked COFs. By enhancing the dipole moment to 2.08 D and lowering exciton binding energy to 20.3 meV, it constructs a robust built‐in electric field and spatially decoupled redox centers. This bypasses inherent kinetic bottlenecks, achieving a 4569 µmol g−1 h−
Yong‐Quan Wu, Zhi‐Bo Zuo, Wei‐Rong Cui   +2 more
wiley   +1 more source