Polarizability matters in enantio-selection
The prevalence of chirality, or, handedness in biological world is a fundamental phenomenon and a characteristic hallmark of life. Thus, understanding the origin of enantio-selection, i.e., the sense and magnitude of asymmetric induction, has been a long-
Fumin Chen+8 more
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SymmCD: Symmetry-Preserving Crystal Generation with Diffusion Models [PDF]
Generating novel crystalline materials has the potential to lead to advancements in fields such as electronics, energy storage, and catalysis. The defining characteristic of crystals is their symmetry, which plays a central role in determining their physical properties. However, existing crystal generation methods either fail to generate materials that
arxiv
Recent Advances in Asymmetric Catalysis Associated with B(C6F5)3. [PDF]
Zhan Z, Yan J, Yu Z, Shi L.
europepmc +1 more source
TitaniumLewis Acids for Asymmetric Catalysis: Synthesis and Structural Characterization of Dichloro[diolato(2−)-κO,κO′]bis(solvent)titanium ([TiCl2(diolato)(solvent)2]) Complexes [PDF]
Lukas Hintermann+2 more
openalex +1 more source
Circularly Polarized Luminescence (CPL) emitters based on Tröger's base analogues bearing two peripheral fluorophores (anthracene, pyrene or 9,9‐dimethylfluorene) are prepared following a straightforward and versatile synthetic approach from common precursors.
Pablo García‐Cerezo+11 more
wiley +1 more source
Recent Developments in Asymmetric Catalysis
Asymmetric catalysis has long been dominated by C2-symmetric bidentate ligands. More recently, sterically and electronically unsymmetrical ligands have found increasing attention.
Andreas Pfaltz
doaj
Synthesis of P-stereogenic 1-phosphanorbornane-derived phosphine-phosphite ligands and application in asymmetric catalysis. [PDF]
Ramazanova K+5 more
europepmc +1 more source
New Applications of Bis(oxazoline) Ligands in Catalysis: Asymmetric 1,2- and 1,4- Addition of ZnR2 to Carbonyl Compounds [PDF]
Marina Schinnerl+3 more
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A multifunctional memristor is demonstrated for in‐memory sensing and computing, leveraging a MoWS₂/VOx heterojunction to enable high ON/OFF ratio up to 10⁸ with ultralow operating voltages of ±0.2 V. This bio‐inspired multimodal design exhibits tunable synaptic behavior across electrical, optical, and humidity stimuli, enabling in situ modulation of ...
Abdul Momin Syed+8 more
wiley +1 more source
Chirality Transfer and Asymmetric Catalysis: Two Strategies toward the Enantioselective Formal Total Synthesis of (+)-Gelsenicine. [PDF]
Knutson PC+4 more
europepmc +1 more source