Results 221 to 230 of about 665,789 (291)

Reaction‐Driven Self‐Organization of Nanocrystals by Kinetic Control of Inhomogeneous Photopolymerization

Advanced Science, EarlyView.
Patterned light reorganizes initially uniform CsPbBr3 perovskite quantum dots into well‐defined structures during photopolymerization. Using a digital micromirror device, we show that this reaction‐driven self‐organization is governed by a competition between chemical‐potential‐driven migration and kinetic arrest caused by rapid solidification ...
Kazuto Uchida, Shiryu Kitajima, Koki Ito, Hideyuki Nakanishi   +3 more
wiley   +1 more source

Self‐Healing Pd(II) Cage Metallogels for Iodine Capture in Water and Heterogeneous Photocatalysis

Advanced Science, EarlyView.
Two carbazole‐derived metal‐organic cages hierarchically self‐assemble into supramolecular metallogels that integrate autonomous self‐healing, reversible stimuli responsiveness, high‐capacity aqueous iodine capture, and visible‐light‐driven photocatalytic sulfide oxidation within a single multifunctional platform.
Monotosh Dalapati, Raghunath Singha, Debashree Manna, Dipak Samanta   +3 more
wiley   +1 more source

2D Vermiculite Nanosheets Encapsulated in Hydrogel Electrolyte for Shuttle‐Free and Dendrite‐Inhibited Zinc‐Iodine Batteries

Advanced Science, EarlyView.
A dual‐network hydrogel was prepared via a one‐pot method, incorporating vermiculite nanosheets as an additive. The negatively charged vermiculite nanosheets not only coordinate with zinc ions to facilitate Zn plating/stripping and suppress Zn dendrite growth, but also adsorb polyiodides to inhibit the shuttle effect, which significantly improves the ...
Yunlong Zhou, Chuanliang Wei, Huanyu Yang, Bin Li, Bo Yang, Jie Ren, Cheng Ye, Maofeng Zhang   +7 more
wiley   +1 more source

Holistic prediction of enantioselectivity in asymmetric catalysis. [PDF]

Nature, 2019
Reid JP, Sigman MS.
europepmc   +1 more source

Bridging Chemical Literature and Molecular Graphs: LLM‐Augmented Enantioselectivity Prediction for Iridium‐Catalyzed Asymmetric C–H Borylation

Advanced Science, EarlyView.
A machine‐learning framework for asymmetric C–H borylation bridges multi‐entity 3D molecular graphs and chemical literature. Atom‐resolved mechanistic annotations extracted by large language models augment three‐component graph encoding of catalyst, substrate, and product. The model predicts enantioselectivity with high accuracy on unseen scaffolds and
Zhe Wang, Baohua Zhang, Yi Isaac Yang, Yuan Yao, Yinwu Li   +4 more
wiley   +1 more source

Scaffold-Oriented Asymmetric Catalysis: Conformational Modulation of Transition State Multivalency during a Catalyst-Controlled Assembly of a Pharmaceutically Relevant Atropisomer. [PDF]

Chemistry
Tampellini N, Mercado BQ, Miller SJ.
europepmc   +1 more source

Coordination Chemistry of Single‐Atom Catalysts in Expediating Kinetics for Advanced Lithium‐Sulfur Batteries

Advanced Science, EarlyView.
This review elucidates the catalytic mechanisms of single‐atom catalysts (SACs) in accelerating lithium polysulfides redox kinetics. Subsequently, the modifications brought by asymmetric coordination chemistry and dual‐atom coordination structures in terms of geometric configuration engineering, molecular orbital hybridization, and interfacial charge ...
Peng Chen, Jinyuan Zhao, Jing Zhang, Yidong Miao, Weihao Li, Huihua Li, Jian Wang, Yongzheng Zhang   +7 more
wiley   +1 more source

Consecutive chirality transfer: efficient synthesis of chiral C,O-chelated BINOL/gold(iii) complexes for asymmetric catalysis and chiral resolution of disubstituted BINOLs. [PDF]

Chem Sci
Chan KA, O WY, Jiang JJ, Cui JF, Wong MK.   +4 more
europepmc   +1 more source

Coordination‐Asymmetry‐Regulated Reconstruction of Electron‐Rich Cu Sites for pH‐Dependent Nitrate‐to‐Ammonia Electrocatalysis

Advanced Science, EarlyView.
Distinct initial Cu coordination environments drive different pH‐dependent structural evolution pathways, resulting in divergent nitrate reduction activity and behavior. ABSTRACT Electrocatalytic nitrate reduction reaction (e‐NO3RR) offers a promising route to valorize nitrate‐contaminated wastewater while enabling sustainable ammonia production ...
Shih‐Ching Huang, Yu‐Ru Lin, Hsiang‐Chun Yu, Yi‐Dong Lin, Yu‐Chiao Chang, Chun‐Kuo Peng, Yu‐Chang Lin, Wen‐Wei Wu, Hao Ming Chen, Chi‐Liang Chen, Han‐Yi Chen, Yan‐Gu Lin   +11 more
wiley   +1 more source

Metabolic‐Redox Remodeling of Inflammatory Synovium by Mannose‐Modified Selenium Nanoparticles for Osteoarthritis Therapy

Advanced Science, EarlyView.
Elevated GLUT1‐driven glycolysis and disrupted selenoprotein‐dependent redox homeostasis drive osteoarthritic progression. Intra‐articular mannose‐modified selenium nanoparticles (M‐SeNPs) selectively target hypermetabolic synovial cells to reprogram aberrant glycolysis and restore endogenous antioxidant defenses.
Yu‐Qing Zou, Chen‐Hao Xu, Bo‐Wei Li, Leung Chan, Yi‐Di Xu, Han‐Bo Su, Rui Peng, Fang‐Ji Luo, Ya‐Chen Peng, Zhen‐Yan Li, Vincent Kam Wai Wong, Xiao‐Fei Zheng, Xing Ma, Zhen‐Gang Zha, Tianfeng Chen, Huan‐Tian Zhang   +15 more
wiley   +1 more source