Results 141 to 150 of about 2,944,243 (309)

Wavelets for intonation modeling in HMM speech synthesis [PDF]

open access: yes, 2013
The pitch contour in speech contains information about different linguistic units at several distinct temporal scales. At the finest level, the microprosodic cues are purely segmental in nature, whereas in the coarser time scales, lexical tones, word ...
Suni, Antti Santeri   +5 more
core  

Freeze‐Thaw Engineered Dual Conductivity Polymeric Binder Stabilizes Large‐Volume‐Change Lithium–Ion Battery Anodes

open access: yesAdvanced Functional Materials, EarlyView.
This work developed an all‐aqueous freeze‐thaw strategy to create a dual‐conductive PVA/P3KBT binder for high volume‐change lithium–ion battery anodes. The resulting binder system strengthens the electrode structure, supports ion and electron transport, and accommodates repeated volume changes, reducing cracking and improving long‐term cycling ...
Haoze Ren   +17 more
wiley   +1 more source

Recent Advances in π-Stacking Interaction-Controlled Asymmetric Synthesis

open access: yesMolecules
The π-stacking interaction is one of the most important intramolecular and intermolecular noncovalent interactions in organic chemistry. It plays an important role in stabilizing some structures and transition states in certain reactions via both ...
Jiaxi Xu
doaj   +1 more source

Catalytic asymmetric synthesis

open access: yes, 2022
This book covers the preparation of enantiomerically pure or enriched chemical compounds by use of chiral catalyst molecules. While reviewing the most important catalytic methods for asymmetric organic synthesis, this book highlights the most important ...
Akiyama, Takahiko, Ojima, Iwao
core  

High‐Speed Photoresponse of CVD‐Grown Lateral TMD Heterostructures

open access: yesAdvanced Functional Materials, EarlyView.
Internal electric fields generated by p‐n junctions and asymmetric Schottky barriers enhance the photoresponse speed in CVD‐grown monolayer TMD lateral heterostructures. This results in a 1.5‐2 orders of magnitude reduction in rise and fall times for optimized device configurations compared to homogeneous single‐material devices, enabling bandwidths ...
Mario Martin   +9 more
wiley   +1 more source

Catalytic Enantioselective Synthesis of Planar Chiral Pillar[5]arenes via Asymmetric Sonogashira Coupling [PDF]

open access: yes
As a novel type of macrocycles with attractive planar chirality, pillar[5]arenes have gained increasing research interest over the past decades, enabling their widespread applications in diverse fields such as porous materials, molecular machines, and ...
Lin-Tao, Bao   +8 more
core   +2 more sources

Electrochemical Pathways for Nitrate Conversion to Ammonia: From Environmental Challenges to Ammonia Economy

open access: yesAdvanced Functional Materials, EarlyView.
This perspective presents recent advances in electrocatalytic nitrate reduction, focusing on reaction mechanisms, catalyst design, and electrolyzer configurations. Key challenges in selectivity, stability, and practical wastewater treatment are highlighted, while future directions for advancing sustainable ammonia synthesis and nitrate remediation are ...
Xintong Li   +9 more
wiley   +1 more source

Kinetics‐Controlled Architecture of Binder‐Free Organic Electrodes for Enhanced Ion Transport

open access: yesAdvanced Functional Materials, EarlyView.
Pulse reverse electrodeposition controls nucleation and growth to create hierarchically porous Py‐derived oligomeric electrodes with enhanced ionic accessibility and reduced transport resistance. The resulting binder‐free architectures translate these transport advantages into practical sodium‐storage functionality.
Satendra Kumar   +1 more
wiley   +1 more source

Donor‐Engineered Chiral Indium–Salen Complexes for Tunable Circularly Polarized Luminescence

open access: yesAdvanced Functional Materials, EarlyView.
Chiral indium–salen complexes bearing electronically and structurally diverse donor substituents are presented as modular main‐group luminophores exhibiting tunable blue‐to‐green circularly polarized luminescence. Donor engineering systematically controls frontier‐orbital distribution, intraligand charge transfer, and excited‐state relaxation ...
Haein Kim   +14 more
wiley   +1 more source

Programmable Soft Actuator with Multi‐Responsiveness Based on Conductive MOF‐Liquid Crystal Polymer Composite

open access: yesAdvanced Functional Materials, EarlyView.
A sequential dual‐alignment strategy independently programs the orientation of conductive metal‐organic framework (c‐MOF) microrods and liquid crystals within a composite film. This approach creates an asymmetric bilayer structure that enables precise, multi‐responsive actuation.
Taegyun Hong   +5 more
wiley   +1 more source

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