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Origins and Development of Initiation of Free Radical Polymerization Processes
At present worldwide about 45% of the manufactured plastic materials and 40% of synthetic rubber are obtained by free radical polymerization processes. The first free radically synthesized polymers were produced between 1910 and 1930 by initiation with ...
Dietrich Braun
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Within the scope of this chapter, we provide a quick introduction to a variety of polymerization techniques that transform monomers into copolymers. We also emphasize the distinctive mechanisms that these strategies employ in order to exert control over the structure of polymers.
Bulend Ortaç +3 more
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Atom transfer radical polymerization (ATRP) with dual photoredox/copper catalysis combines the advantages of photo-ATRP and photoredox-mediated ATRP, utilizing visible light and ensuring broad monomer scope and solvent compatibility while minimizing side
Woojin Jeon +2 more
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Applying Dynamic Monte Carlo Simulation for Living Free Radical Polymerization Processes: Emphasis on Atom Transfer Radical Polymerization (ATRP) [PDF]
Modeling is the applications of methods to analyze complex, real-world problems in order to make predictions about what might happen with various actions. When it is too difficult, time consuming, costly or dangerous experiments, the modeler resort to computer simulations, or having a computer program imitate reality, in order to study situations and ...
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This work presents a novel approach for tailoring molecularly imprinted polymers (MIPs) with a preliminary stage of atom transfer radical polymerization (ATRP), for a more precise definition of the imprinted cavity. A well-defined copolymer of acrylamide
Daniela dos Santos Oliveira +5 more
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In the photolithography process of integrated circuits (IC) manufacturing, it is desired that the photoresist resins have both smaller polydispersity index (PDI) and lower trace metal ion concentrations.
Yingchao Liu, Jinshan Wang, Weimin Li
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The atom transfer radical polymerization (ATRP) of phenoxycarbonylmethyl methacrylate (PCMMA) with styrene (St) were performed in bulk at 110°C in the presence of ethyl 2-bromoacetate, cuprous(I)bromide (CuBr), and N,N,N’,N”,N”-pentamethyldiethyltriamine.
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Organocatalytic atom transfer radical polymerization with light and pH dual-gated regulation
To improve the control and precision in polymer synthesis, the development of polymerization with logical control by multiple stimuli has attracted considerable attention in recent years. Herein, we describe the introduction of a dual regulation by light
Yu Jiang +6 more
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Compartmentalization in Atom Transfer Radical Polymerization (ATRP) in Dispersed Systems
Macromolecular Theory and Simulations, 2006AbstractSummary: Compartmentalization in atom transfer radical polymerization (ATRP) in dispersed systems at low conversion (<10%) has been investigated by means of a modified Smith–Ewart equation focusing on the system n‐butyl acrylate/CuBr/4,4′‐dinonyl‐2,2′‐dipyridyl at 110 °C.
Hideto Minami +2 more
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ChemPhysChem, 2012
AbstractAtom transfer radical polymerization (ATRP) was initially developed in the mid‐1990s, and with continued refinement and use has led to significant discoveries in new materials. However, metal contamination of the polymer product is an issue that has proven detrimental to widespread industrial application of ATRP.
Devon Shipp, Qin Lou
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AbstractAtom transfer radical polymerization (ATRP) was initially developed in the mid‐1990s, and with continued refinement and use has led to significant discoveries in new materials. However, metal contamination of the polymer product is an issue that has proven detrimental to widespread industrial application of ATRP.
Devon Shipp, Qin Lou
exaly +3 more sources

