Results 1 to 10 of about 3,278 (226)
Circadian rhythmicity by autocatalysis. [PDF]
PLoS Computational Biology, 2006 The temperature compensated in vitro oscillation of cyanobacterial KaiC phosphorylation, the first example of a thermodynamically closed system showing circadian rhythmicity, only involves the three Kai proteins (KaiA, KaiB, and KaiC) and ATP.
Arun Mehra +5 more
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Angewandte Chemie - International Edition, 2013 AbstractSelf‐replication is a fundamental concept. The idea of an entity that can repeatedly create more of itself has captured the imagination of many thinkers from von Neumann to Vonnegut. Beyond the sciences and science fiction, autocatalysis has found currency in economics and language theory, and has raised ethical fears memorably summed up by the
Andrew J Bissette, Stephen P Fletcher
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Large Solvent‐Dependent Rate Enhancement of Autocatalytic Hydrolysis of Alkyl and Aryl Thiosulfates [PDF]
ChemistryOpenThe hydrolysis of alkyl and aryl thiosulfates (Bunte salts), to produce the corresponding thiol and bisulfate ion, is autocatalytic in the absence of added acid and proceeds at greatly accelerated rates in organic solvents at room temperature relative to
Fatema B. Amin +2 more
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The Origin of Anion−π Autocatalysis
Jacs Au, 2023 The autocatalysis of epoxide-opening ether cyclizations on the aromatic surface of anion-π catalysts stands out as a leading example of emergent properties expected from the integration of unorthodox interactions into catalysis. A working hypothesis was proposed early on, but the mechanism of anion-π autocatalysis has never been elucidated.
, Stefan Matile
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Crystallization-driven template autocatalysis induces mirror symmetry breaking and amplification [PDF]
Nature CommunicationsA plausible hypothesis for the origin of biological homochirality invokes chiral symmetry breaking, transfer, and amplification driven by autocatalysis. Here we experimentally demonstrate that crystallization-driven template autocatalysis (CDTA) induces ...
Huimin Wu +3 more
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Autocatalytic Sets and Assembly Theory: A Toy Model Perspective [PDF]
EntropyAssembly Theory provides a promising framework to explain the complexity of systems such as molecular structures and the origins of life, with broad applicability across various disciplines.
Sebastian Raubitzek +5 more
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Driving forces in the origins of life [PDF]
Open Biology, 2021 What were the physico-chemical forces that drove the origins of life? We discuss four major prebiotic ‘discoveries’: persistent sampling of chemical reaction space; sequence-encodable foldable catalysts; assembly of functional pathways; and encapsulation
K. A. Dill, L. Agozzino
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Martensite’s Logistic Paradigm
Materials Research, 2021 This work introduces a deterministic approach to the martensite transformation curve. Martensite is a nucleation-controlled transformation that has two characteristics: autocatalysis and auto-accommodation.
José Roberto Costa Guimarães +2 more
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Polymer Testing, 2023 Crosslinking reaction behaviors can determine the network morphology and further influence macroscopic properties of polymers, while the current comprehension about crosslinking reaction behaviors of peroxide-induced low-density polyethylene (PLDPE) is ...
Jiacai Li +5 more
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Martensite Transformation Intergrain and Intragrain Autocatalysis in Fe-Ni alloys [PDF]
Materials Research, 2017 This work presents a consolidated view of the autocatalysis, thermal and entropic effects in martensitic transformation of polycrystalline Fe-31wt%Ni-0.02wt%C, which has been a standard material for the investigation of fundamental aspects of the ...
José Roberto Costa Guimarães +1 more
doaj +1 more source