Shedding Light on Synthetic Autocatalysis: From Conventional Closed‐Shell Chemistries to Overlooked Open‐Shell Occurrences [PDF]
Chemistry – A European Journal, Volume 32, Issue 28, 25 July 2026.Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley +3 more sources
Autocatalysis in Reaction Networks [PDF]
Bulletin of Mathematical Biology, 2014 v4: 29 pages, 1 figure, Theorem 5.3.3 strengthened to all consistent reaction networks; v3: 28 pages, 1 figure, minor revisions; v2: 27 pages, 1 figure, new introduction and related work sections replacing sections in v1; v1:27 pages, 1 ...
Abhishek Deshpande, Manoj Gopalkrishnan
openaire +3 more sources
Autocatalysis in Chemical Networks: Unifications and Extensions [PDF]
, 2020 Autocatalysis is an essential property for theories of abiogenesis and chemical evolution. However, the different formalisms proposed so far seemingly address different forms of autocatalysis and it remains unclear whether all of them have been captured.
Alex, Blokhuis +2 more
core +1 more source
Ni-Catalyzed Arylbenzylation of Alkenylarenes. Kinetic Studies Reveal Autocatalysis by ZnX2 and 3-Fold Catalytic Rate Increase [PDF]
, 2021 We report a Ni-catalyzed regioselective arylbenzylation of alkenylarenes with benzyl halides and arylzinc reagents. The reaction furnishes differently substituted 1,1,3-triarylpropyl structures that are reminiscent of the cores of oligoresveratrol ...
Ramesh, Giri +5 more
core +1 more source
The problem of the autocatalytic origin of culture in Juri Lotman’s cultural philosophy
Sign Systems Studies, 2005 The origin of culture remains in the sphere of hypotheses. Although the hypotheses derive from two presumptions: first, how the structure of culture is envisaged, and secondly, how culture is thought to function.
Linnar Priimägi
doaj +1 more source
Bandgap‐Coupled Template Autocatalysis toward the Growth of High‐Purity sp2 Nanocarbons
Advanced Science, 2021 Extraordinary properties and great application potentials of carbon nanotubes (CNT) and graphene fundamentally rely on their large‐scale perfect sp2 structure.
Jun Gao +5 more
doaj +1 more source
Autocatalysis in Eschenmoser Coupling Reactions [PDF]
Chemistry – A European Journal, 2023 AbstractThe Eschenmoser coupling reaction (ECR) of thioamides with electrophiles is believed to proceed via thiirane intermediates. However, little is known about converting the intermediates into ECR products. Previous mechanistic studies involved external thiophiles to remove the sulfur atom from the intermediates.
DUEZ, Quentin +4 more
openaire +5 more sources
Model of the nonlinear reaction system with autocatalysis and autoinhibition: Stability of dynamic states [PDF]
Hemijska Industrija, 2012 Self-regulation, achieved through positive (autocatalytic) or negative (autoinhibitory) feedback is commonly encountered in natural, technological and economic systems.
Kolar-Anić Ljiljana +2 more
doaj +1 more source
Autocatalysis-Driven Clock Reaction III: Clarifying the Kinetics and Mechanism of the Thiourea Dioxide–Iodate Reaction in an Acidic Medium [PDF]
, 2019 The thiourea dioxide–iodate reaction has been reinvestigated spectrophotometrically under acidic conditions using phosphoric acid–dihydrogen phosphate buffer within the pH range of 1.1–1.8 at 1.0 M ionic strength adjusted by sodium perchlorate and at 25 °
Qingyu Gao (1446913) +3 more
core +1 more source
Mathematical Analysis of a Prototypical Autocatalytic Reaction Network
Life, 2019 Network autocatalysis, which is autocatalysis whereby a catalyst is not directly produced in a catalytic cycle, is likely to be more common in chemistry than direct autocatalysis is.
Ekaterina V. Skorb, Sergey N. Semenov
doaj +1 more source